This chapter provides an overview of the production and use of titanium and its significance as an engineering material. It begins by identifying important deposits and ores and assessing current and future production capacities and how they align with global consumption trends. It then describes the physical and mechanical properties of pure titanium and numerous grades of wrought titanium alloys and explains how they compare with other aerospace materials in terms of processing complexity and cost. The chapter also includes information on extractive metallurgy, current and emerging processes, product forms, and related costs.

This chapter provides a general overview of titanium and its versatility as an engineering material.

Titanium castings are used in a wide range of aerospace, chemical process, marine, biomedical, and automotive applications. This chapter provides an overview of titanium casting and associated processes and how they compare with other manufacturing methods. It also discusses the role heat treating and its effect on the tensile properties of different titanium alloys.

This chapter discusses the advantages and disadvantages of producing titanium parts using powder metallurgy (PM) techniques. It compares the typical properties of wrought, cast, and PM titanium alloy products, addresses various manufacturing challenges, and describes several consolidation and shaping processes along with associated property data.

This chapter examines the process, structure, and property relationships in titanium alloys. It provides information on microstructures and strengthening mechanisms, the role of alloy and interstitial elements, and the effect of composition, processing, and surface treatments on tensile and yield strength, fracture toughness, hardness, ductility, and creep and fatigue behaviors. The chapter covers wrought, cast, and powder metal titanium alloys and contains an extensive amount of property data.

Titanium is a lightweight metal with a density approximately 60% that of steel and, through alloying and deformation processing, it can be just as strong. It is readily available in many grades and forms and can be further processed using standard methods and techniques. This chapter provides a concise review of the capabilities of titanium and its design advantages over other materials. It includes information on properties and selection factors as well as applications.

This chapter discusses the processes of isothermal and hot-die forging and their use in producing aerospace components. It explains how isothermal forging was developed to provide a near-net shape component geometry and well-controlled microstructures and properties with accurate control of the working temperature and strain rate. It describes the materials typically used as well as equipment and tooling, die heating procedures, part separation techniques, and postforging heat treatment.

Titanium alloys are classified according to the amount of alpha and beta phase material retained in their structures at room temperature. This chapter discusses the metallurgy, composition, processing, and properties of titanium and its alloys. It provides information on melting, forging, casting, heat treating, and secondary fabrication. It also discusses the advantages and disadvantages of titanium and its alloys in various applications.

This chapter contains tables listing room-temperature tensile yield strength comparisons of metals and plastics and room-temperature tensile modulus of elasticity comparisons of various materials.

This chapter describes the metallurgy of superalloys and the extent to which it can be controlled. It discusses the alloying elements, crystal structures, and processing sequences associated with more than a dozen phases that largely determine the characteristics of superalloys, including their properties, behaviors, and microstructure. It examines the role of more than 20 alloying elements, including phosphorus (promotes carbide precipitation), boron (improves creep properties), lanthanum (increases hot corrosion resistance), and carbon and tungsten which serve as matrix stabilizers. It explains how precipitates provide strength by impeding deformation under load. It also discusses the factors that influence grain size, shape, and orientation and how they can be controlled to optimize mechanical and physical properties.

Superalloys are nickel, iron-nickel, and cobalt-base alloys designed for high-temperature applications, generally above 540 deg C. This chapter covers the metallurgy, composition, and properties of cast and wrought superalloys. It provides information on melting, heat treating, and secondary fabrication processes. It also covers coating technology, including aluminide diffusion and overlay coatings, and addresses the advantages and disadvantages of superalloys in various applications.

This appendix is a collection of tables listing coefficients of linear thermal expansion for carbon and low-alloy steels, presenting a summary of thermal expansion, thermal conductivity, and heat capacity; and listing thermal conductivities and specific heats of carbon and low-alloy steels.

Titanium is a lightweight metal used in a growing number of applications for its strength, toughness, stiffness, corrosion resistance, biocompatibility, and high-temperature operating characteristics. This chapter discusses the applications, metallurgy, properties, compositions, and grades of commercially pure titanium and alpha and near-alpha, alpha-beta, and beta titanium alloys. It describes primary and secondary fabrication processes, including melting, forging, forming, heat treating, casting, machining, and joining as well as powder metallurgy and direct metal deposition. It also compares and contrasts the properties of wrought, cast, and powder metal titanium products and discusses corrosion behaviors.

This article discusses the composition, structure, and properties of iron-nickel-, nickel-, and cobalt-base superalloys and the effect of major alloying and trace elements. It describes the primary and secondary roles of each alloying element, the amounts typically used, and the corresponding effect on properties and microstructure. It also covers mechanical alloying and weldability and includes nominal composition data on many wrought and cast superalloys.

This chapter provides a brief overview of nickel-iron-base, cobalt-base, and nickel-base superalloys, discussing their basic metallurgy and defining characteristics.

Casting is the most economical processing route for producing titanium parts, and unlike most metals, the properties of cast titanium are on par with those of wrought. This chapter covers titanium melting and casting practices -- including vacuum arc remelting, consumable electrode arc melting, electron beam hearth melting, rammed graphite mold casting, sand casting, investment casting, hot isostatic pressing, weld repair, and heat treatment -- along with related equipment, process challenges, and achievable properties and microstructures. It also explains how titanium parts are produced from powders and how the different methods compare with each other and with conventional production techniques. The methods covered include powder injection molding, spray forming, additive manufacturing, blended elemental processing, and rapid solidification.

This article discusses the composition, properties, and behaviors of zinc and its alloys. It explains where cast and wrought zinc alloys are used, describes commercial designations and grades, and discusses the effect of various alloying elements on properties and performance.

Nonferrous alloys are heat treated for a variety of reasons. Heat treating can reduce internal stresses, redistribute alloying elements, promote grain formation and growth, produce new phases, and alter surface chemistry. This chapter describes heat treatment processes and how nonferrous alloys respond to them. It provides information on aluminum, cobalt, copper, magnesium, nickel, and titanium alloys and their composition, microstructure, properties, and processing characteristics.

This article discusses the composition, structures, properties, and behaviors of aluminum alloys and explains how they correspond to specific alloying elements. It begins with an overview of the general characteristics of wrought and cast aluminum alloys, the four-digit classification system by which they are defined, and the applications for which they are suited. It then explains how primary alloying elements, second-phase constituents, and impurities affect yield strength, phase formation, and grain size and how they induce structural changes that help refine certain alloys. The article also explains how primary alloying elements affect corrosion and wear behaviors and how they influence fabrication processes such as forming, forging, welding, brazing, and soldering.