Copper is often used in the unalloyed form because pure copper is more conductive than copper alloys. Alloying elements are added to optimize strength, ductility, and thermal stability, with little negative effect on other properties such as conductivity, fabricability, and corrosion resistance. This chapter covers the classification, composition, properties, and applications of copper alloys, including brasses, bronzes, copper-nickel, beryllium-copper, and casting alloys. It also examines wrought copper alloys and pure coppers. The chapter begins with an overview of the copper production process and concludes with a discussion on corrosion resistance.

This article discusses the composition, properties, and behaviors of copper and its alloys. It begins with an overview of the characteristics, applications, and commercial grades of wrought and cast copper. It then discusses the role of alloying, explaining how zinc, tin, aluminum, silicon, and nickel affect the physical and mechanical properties of coppers and high-copper alloys as well as brasses, bronzes, copper-nickels, and nickel silvers. It also explains how alloying affects electrical conductivity, corrosion resistance, stress-corrosion cracking, and processing characteristics.

The discovery and use of materials have shaped civilization since ancient times. This chapter traces the history of the use of metals from hammered copper estimated to be 11,000 years old to the development of electrolytically refined aluminum in 1884. The discussion covers the advent of the Bronze Age, extraction of metals from their respective ores, and the discovery of modern metals such as chromium, vanadium, platinum, and titanium.

This chapter covers the friction and wear behaviors of copper alloys. It describes the compositions and forms of copper available and their suitability for applications involving friction, different types of erosion, and adhesive and abrasive wear.

Nonferrous alloys are heat treated for a variety of reasons. Heat treating can reduce internal stresses, redistribute alloying elements, promote grain formation and growth, produce new phases, and alter surface chemistry. This chapter describes heat treatment processes and how nonferrous alloys respond to them. It provides information on aluminum, cobalt, copper, magnesium, nickel, and titanium alloys and their composition, microstructure, properties, and processing characteristics.

The term heat treatable alloys is used in reference to alloys that can be hardened by heat treatment, and this chapter briefly describes the major types of heat treatable nonferrous alloys. The discussion provides a general description of annealing cold-worked metals and describes some of the common nonferrous alloys that can be hardened through heat treatment. The nonferrous alloys covered include aluminum alloys, cobalt alloys, copper alloys, magnesium alloys, nickel alloys, and titanium alloys.

This appendix is a collection of tables listing coefficients of linear thermal expansion for carbon and low-alloy steels, presenting a summary of thermal expansion, thermal conductivity, and heat capacity; and listing thermal conductivities and specific heats of carbon and low-alloy steels.

This chapter contains tables listing room-temperature tensile yield strength comparisons of metals and plastics and room-temperature tensile modulus of elasticity comparisons of various materials.

This chapter describes the processes involved in alloy production, including melting, casting, solidification, and fabrication. It discusses the effects of alloying on solidification, the formation of solidification structures, supercooling, nucleation, and grain growth. It describes the design and operation of melting furnaces as well as melting practices and the role of fluxing. It also discusses casting methods, nonferrous casting alloys, and atomization processes used to make metal powders.

This chapter describes important requirements for ferrous and nonferrous alloys used for gears. Wrought surface-hardening and through-hardening carbon and alloy steels are the most widely used of all gear materials and are emphasized in this chapter. The processing characteristics of gear steels and the bending fatigue strength and properties of carburized steels are reviewed. In addition to wrought steels, the chapter provides information on the other iron-base alloys that are used for gears, namely cast carbon and alloy steels, gray and ductile cast irons, powder metallurgy irons and steels, stainless steels, and tool steels. In terms of nonferrous alloys, the chapter addresses copper-base alloys, die cast aluminum alloys, zinc alloys, and magnesium alloys.

Aluminum generally has excellent resistance to corrosion and gives years of maintenance-free service in natural atmospheres, fresh waters, seawater, many soils and chemicals, and most foods. This chapter explains why aluminum and aluminum alloys are naturally resistant to corrosion and describes the conditions and circumstances under which their natural defenses break down. It discusses the causes and forms of corrosion observed in aluminum alloys and the effect of composition, microstructure, processing history, and environmental variables such as impurities, fluid flow, surface area, pressure, and temperature.

Nonferrous metals are of commercial interest both as engineering materials and as alloying agents. This chapter addresses both roles, discussing the properties, processing characteristics, and applications of several categories of nonferrous metals, including light metals, corrosion-resistance alloys, superalloys, refractory metals, low-melting-point metals, reactive metals, precious metals, rare earth metals, and metalloids or semimetals. It also provides a brief summary on special-purpose materials, including uranium, vanadium, magnetic alloys, and thermocouple materials.

Tool steels are the ferrous alloys used to manufacture tools, dies, and molds that shape, form, and cut other materials, including steels, nonferrous metals, and plastics. This chapter explores the considerations that make tool steels a very special class of steels, the long historical evolution of iron and steel manufacture, including steels for tools, and the development of tool steels as they emerged from the general class of iron and steel products.

This chapter provides a brief account of galvanic corrosion, which occurs when a metal or alloy is electrically coupled to another metal or conducting nonmetal in the same electrolyte. It begins by describing the galvanic series of metals and alloys useful for predicting galvanic relationships, followed by a brief section on polarization of metals or alloys. The effects of area, distance, and geometric shapes on galvanic-corrosion behavior are then discussed. Various alloys susceptible to galvanic corrosion are briefly reviewed. The chapter also discusses various modes of attack that lead to galvanic corrosion, along with methods for predicting and controlling galvanic corrosion.

Aluminum casting alloy compositions parallel those of wrought alloys in many respects. However, because work hardening plays no significant role in the development of casting properties, the use and purposes of some alloying elements differ in casting alloys versus wrought alloys. This chapter provides information on specifications and widely used designation systems and alloy nomenclature for aluminum casting alloys. It describes the composition of seven basic families of aluminum casting alloys: aluminum-copper, aluminum-silicon-copper, aluminum-silicon, aluminum-silicon-magnesium, aluminum-magnesium, aluminum-zinc-magnesium, and aluminum-tin. The chapter discusses the effects of alloying elements on the properties of cast aluminum. It provides information on various alloys that are grouped with respect to their applications or major performance characteristics.

This chapter traces the history of steelmaking over three millennia, from the discovery of martensite in a mining tool dating from the twelfth century B.C. to the nineteenth century development of the Bessemer and Siemens processes. It also describes the work of early metallographers who discovered many phases and microstructures associated with steel and gave them their now familiar names. The chapter concludes with a brief discussion on the emergence of continuous casting and the subsequent development of strip casting production techniques.

All materials are susceptible to corrosion or some form of environmental degradation. Although no single material is suitable for all applications, usually there are a variety of materials that will perform satisfactorily in a given environment. The intent of this chapter is to review the corrosion behavior of the major classes of metals and alloys as well as some nonmetallic materials, describe typical corrosion applications, and present some unique weaknesses of various types of materials. It also aims to point out some unique material characteristics that may be important in material selection, and discuss, where appropriate, the characteristic forms of corrosion that attack specific materials. The materials addressed in this chapter include carbon steels, weathering steels, and alloy steels; nickel, copper, aluminum, titanium, lead, magnesium, tin, zirconium, tantalum, niobium, and cobalt and their alloys; polymers; and other nonmetallic materials, including rubber, carbon and graphite, and woods.

This chapter discusses the foundational principles of materials science. It begins with a review of the periodic table and the fundamental particles, including atoms, ions, and molecules, that constitute matter. It also reviews the types of bonds that form between atoms and the relative levels of force they produce. It describes the difference between crystalline and noncrystalline or amorphous materials and discusses common crystal structures, including face-centered cubic, body-centered cubic, hexagonal close packed, and diamond cubic. It also describes the structure of sodium chloride and includes a list of structurally similar compounds.