Elastomers comprise a subclass of polymers that display the ability to stretch and recover that is typical of a rubber band. This chapter describes the properties determined by tensile testing of elastomers and the factors influencing them, namely, structuring of the molecular matrix, compounding, specimen preparation, specimen type, vulcanization parameters, and temperature. The chapter also provides information on ASTM D 412, the most widely referenced standard for determining the tensile properties of elastomers.

This chapter discusses the structural classifications, molecular configuration, degradation, properties, and uses of polymers. It describes thermoplastic and thermosetting polymers, degree of polymerization, branching, cross-linking, and copolymers. It also discusses glass transition temperatures, additives, and the effect of stretching on thermoplastics.

This chapter discusses recycling processes used for metals, plastics, rubber, glass, and paper. Is also describes the advantages of recycled materials.

The increased use of advanced high-strength steels to achieve weight reduction in automobiles has led to the development of innovative tool designs and manufacturing processes. Among these technologies and processes are: real-time process control, active drawbeads, active binders, flexible binders, and flexible rolling. This chapter presents the implementation, advantages, disadvantages, and applications of these processes and technologies.

This chapter reviews the tests and procedures used for measuring hardness of plastics and elastomers. The conventional testing methods (Rockwell, Vickers, Brinell, and Knoop) used for testing of metals are based on the idea that hardness represents the resistance against permanent plastic deformation of the material to be tested. However, elastic deformation must be considered in hardness measurement of elastomers. This chapter discusses the equipment and processes involved in the durometer (Shore) test, the International Rubber Hardness Degree test, and other specialized tests. It presents the criteria that can be used to select a suitable hardness testing method for elastomers or plastics and describes processes involved in specimen preparation and equipment calibration.

The shock-resisting tool steels, designated as group S steels in the AISI classification system, have been developed to produce good combinations of high hardness, high strength, and high toughness or impact fracture resistance. This chapter describes the alloying effects of silicon on the properties of shock-resisting tool steels. In addition, it discusses the compositions, characteristics, applications, advantages, and disadvantages of shock-resisting steels with and without tungsten.

Leaks can occur as the result of several failure causes. This chapter reviews the causes, features, and impact of various types of leaks, namely gasket leaks, O-ring leaks, bond-joint leaks, weld leaks, polyvinyl chloride leaks, valve leaks, and structural leaks.

Statistics, data analysis, root cause analysis, and problem-solving processes play a key role in failure investigations. This chapter explains how to collect failure investigation data, how to build and maintain a database for company-related failures, and how to use corresponding statistics including type of failure, material, and root cause. It describes the purpose and benefits of conducting a root cause analysis and the factors, namely relative failure importance and company value, that determine when an investigation should be performed. The chapter also discusses the four-step problem-solving process as it applies to failure investigation, how to assemble an investigation team, and the details of organization and planning. It concludes with a case history of the Firestone 500 steel-belted tire failure, stressing the importance of a systematic approach to failure investigations.

The air-hardening cold-work tool steels, designated as group A steels in the AISI classification system, achieve their processing and performance characteristics with combinations of high carbon and moderately high alloy content. This chapter describes the microstructural features and hardenability of air-hardening cold-work tool steels and discusses the processes involved in the hardening and tempering of tool steels.

This chapter discusses the tooling used for autoclave curing, one of the most common composite fabrication processes. The discussion covers curing practices, material selection factors, and design challenges associated with thermal expansion, tool shrinkage, part complexity, and heating and cooling rates. The chapter also includes best practices and recommendations for toolmaking and assembly.

Adhesive bonding is a widely used industrial joining process in which a polymeric material is used to join two separate pieces (the adherends or substrates). This chapter begins with a discussion on the advantages and disadvantages of adhesive bonding, followed by a section providing information on the theory of adhesion. The chapter then describes the considerations for designing adhesively bonded joints and for testing or characterizing adhesive materials. The following section covers the characteristics of the most important synthetic adhesive systems and five groups of adhesives, namely structural, hot melt, pressure sensitive, water based, and ultraviolet and electron beam cured. The chapter ends with a discussion on some general guidelines for adhesive bonding and the basic steps in the adhesive bonding process.

This chapter reviews materials issues encountered in joining, including challenges involved in welding of dissimilar metal combinations; joining of plastics by mechanical fastening, solvent and adhesive bonding, and welding; joining of thermoset and thermoplastic composite materials by mechanical fastening, adhesive bonding, and, for thermoplastic composites, welding; the making of glass-to-metal seals; and joining of oxide and nonoxide ceramics to themselves and to metals by solid-state processes and by brazing. The classification, types, applications, and the mechanism of each of these methods are covered. The factors influencing joint integrity and the main considerations in welding dissimilar metal combinations are also discussed.

This chapters discusses the basic steps in the failure analysis process. It covers examination procedures, selection and preservation of fracture surfaces, macro and microfractography, metallographic analysis, mechanical testing, chemical analysis, and simulated service testing.

Steels for hot-work applications, designated as group H steels in the AISI classification system, have the capacity to resist softening during long or repeated exposures to high temperatures needed to hot work or die cast other materials. These steels are subdivided into three classes according to the alloying approach: chromium hot-work steels, tungsten hot-work steels, and molybdenum hot-work steels. This chapter discusses the composition, characteristics, applications, advantages, and disadvantages of each of these steels.

This chapter describes the various types of cushion systems used in forming presses and their effect on part quality. It begins with a review of the deep drawing process, explaining that wrinkling, tearing, and fracture are the result of excess or insufficient material flow, which can be prevented by maintaining the correct amount of holding force on the periphery of the blank. It then describes how blank holding force is generated in double-action presses and the extent to which displacement profiles can be adjusted on both the inner and outer slides. The discussion then turns to single-action presses that incorporate some type of cushion system. The chapters describes the many ways that cushion systems are implemented in forming presses and the force and displacement characteristics achievable with each method. It also explains how multipoint cushion systems are designed and how they facilitate uniform metal flow into the die cavity of large deep-drawn parts.

This chapter focuses on the evolution of steel production from 1870 to 1900. It begins with a review of the life of the inventor of the air-boiling process, William Kelly. This is followed by a discussion on how Bessemer's air-blowing process entered the steel production industry and the development of the Kelly-Bessemer process by Alexander Holley. The chapter then discusses how Andrew Carnegie lowered the cost to produce steel, how he entered the iron and steelmaking industry, and how Captain Billy Jones joined Carnegie to expand Carnegie steel. The chapter further provides information on the great strike of 1892 at Homestead and the rapid growth in steel markets. It ends with a discussion about the factors that led Carnegie to sell his steel empire.

This chapter provides information on the major drivers for automakers and the solutions to address these industry drivers and meet their business goals. It discusses the importance of steel in the industry and briefly describes the development and significance of advanced high-strength steels for the industry.

This article focuses on friction and wear as they relate to polymeric materials, covering friction and wear applications for polymeric materials. The discussion covers the causes and mechanisms of friction, wear, and lubrication; different test methods developed to simulate friction and wear mechanisms; and friction and wear test data used for polymeric materials.

Containment materials used in power generating applications are subject to molten salt corrosion. This chapter reviews the data relevant to corrosion problems in molten salt environments. It describes the corrosion behavior of steel, aluminum, nickel, and titanium alloys in molten chlorides, molten nitrates, molten fluorides, molten carbonates, and molten sodium hydroxide.