This chapter describes the causes of cracking, embrittlement, and low toughness in carbon and low-alloy steels and their differentiating fracture surface characteristics. It discusses the interrelated effects of composition, processing, and microstructure and contributing factors such as hot shortness associated with copper and overheating and burning as occur during forging. It addresses various types of embrittlement, including quench embrittlement, tempered-martensite embrittlement, liquid-metal-induced embrittlement, and hydrogen embrittlement, and concludes with a discussion on high-temperature hydrogen attack and its effect on strength and ductility.

This chapter discusses various types of material fracture toughness and the methods by which they are determined. It begins with a review of the basic principles of linear elastic fracture mechanics, covering the Griffith-Irwin theory of fracture, the concept of strain energy release rate, the use of fracture indices and failure criteria, and the ramifications of crack-tip plasticity in ductile and brittle fractures. It goes on to describe the different types of plain-strain and plane-stress fracture toughness, explaining how they are measured and how they are influenced by metallurgical and environmental variables and loading conditions. It also examines the crack growth resistance curves of several aluminum alloys and describes the characteristics of fracture when all or some of the applied load is in the plane of the crack.

The mechanical behavior of a material is its response to an applied load or force. Important mechanical properties are strength, hardness, stiffness, and ductility. This chapter discusses three principal ways in which these properties are tested: tension, compression, and shear. Important tensile properties that can be determined by the tensile test include yield strength, ultimate tensile strength, ductility, resilience, and toughness. The chapter describes the effects of stress concentrations on ductile metals under cyclic loads. Other topics covered include combined stresses, yield criteria, and residual stresses of metals.

Most quenched steels are tempered because the toughness of as-quenched steels is generally very poor. The tempering operation sacrifices strength for improvements in ductility and toughness. This chapter discusses the tempering process, the challenge of tempered martensite embrittlement, and the effect of wt% carbon on toughness. It also explains how alloying elements improve the hardenability and tempering response of plain carbon steels.

This chapter summarizes the performance attributes of advanced high-strength steels, namely stiffness, strength, strain hardening, fatigue, crashworthiness, formability, toughness, and bake hardening.

This chapter describes the classification of steels and the various compositional categories of commercial steel products. It explains how different alloying elements affect the properties of carbon and low-alloys steels and discusses strength, toughness, and corrosion resistance and how to improve them.

The design of case-hardened components is an iterative process, requiring the consideration of multiple interrelated factors. This chapter walks readers through the steps involved in selecting an appropriate material and assessing the influence of alloy composition and cooling rate on core properties including hardenability, microstructure, tensile and yield strength, ductility, toughness, and fatigue resistance. It likewise explains how carbon affects case hardenability, surface hardness, and case toughness and how case depth influences residual stresses and bending and contact fatigue. It also discusses the effect of quenching methods and addresses the issue of distortion.

Fracture is the separation of a solid body into two or more pieces under the action of stress. Fracture can be classified into two broad categories: ductile fracture and brittle fracture. Beginning with a comparison of these two categories, this chapter discusses the nature and causes of these failure modes. Some body-centered cubic and hexagonal close-packed metals, and steels in particular, exhibit a ductile-to-brittle transition when loaded under impact and the chapter describes the use of notched bar impact testing to determine the temperature at which a normally ductile failure transitions to a brittle failure. The discussion then covers the Griffith theory of brittle fracture and the formulation of fracture mechanics. Procedures for determination of the plane-strain fracture toughness are subsequently covered. Finally, the chapter describes the effects of microstructural variables on fracture toughness of steels, aluminum alloys, and titanium alloys.

This article discusses various factors influencing general polymeric behavior, ductile-brittle transitions, crazing, and the brittle fracture of polymeric materials. The discussion covers the effects of environment on glassy thermoplastic, several parametric descriptions of craze initiation, the kinetics of craze growth, and the effect of crazing on toughness of the plastic. In addition, the article provides information on various tests to determine stress-to-craze value, strain-to-craze value, and fracture toughness of the plastic.

This article briefly describes the historical development of fracture resistance testing of polymers and reviews several test methods developed for determining the fracture toughness of polymeric materials. The discussion covers J-integral testing, the methods for determining linear elastic fracture toughness, testing of thin sheets and films, normalization methods, and hysteresis methods.

This chapter addresses the issue of stress-corrosion cracking (SCC) in carbon and low-alloy steels. It discusses crack initiation, propagation, and fracture in aqueous chloride, hydrogen sulfide, sulfuric acid, hydroxide, ammonia, nitrate, ethanol, methanol, and hydrogen gas environments. It explains how composition and microstructure influence SCC, as do mechanical properties such as strength and fracture toughness and processes such as welding and cold work. It also discusses the role of materials selection and best practices for welding.

Bainite is an intermediate temperature transformation product of austenite. This chapter describes the conditions under which bainite is likely to form. It discusses the effects of alloying on bainitic transformation, the difference between upper and lower bainite, and the influence of solute drag on bainite formation mechanisms. It also discusses the development of ferrite-carbide bainites and their effect on toughness, hardness, and ductility.

This chapter discusses the stress-strain response of ferritic microstructures and its influence on tensile deformation, strain hardening, and ductile fracture of carbon steels. It describes the ductile-to-brittle transition that occurs in bcc ferrite, the effects of aging and grain size on strength and toughness, continuous and discontinuous yielding behaviors, and dispersion and solid-solution strengthening processes.

This chapter describes heat treatments that produce uniform grain structures, reduce residual stresses, and improve ductility and machinability. It also discusses spheroidizing treatments that improve strength and toughness by promoting dispersions of spherical carbides in a ferrite matrix. The chapter concludes with a brief discussion on the mechanical properties of ferrite/pearlite microstructures in medium-carbon steels.

Most steels that are hardened are subjected to a subcritical heat treatment referred to as tempering. Tempering improves the toughness of as-quenched martensitic microstructures but lowers strength and hardness. This chapter describes the microstructural changes that occur during tempering and their effect on the mechanical properties of steel. It also discusses the effect of alloying elements and the formation of oxide colors.

Alloy steels are alloys of iron with the addition of carbon and one or more of the following elements: manganese, chromium, nickel, molybdenum, niobium, titanium, tungsten, cobalt, copper, vanadium, silicon, aluminum, and boron. Alloy steels exhibit superior mechanical properties compared to plain carbonsteels as a result of alloying additions. This chapter describes the beneficial effects of these alloying elements in steels. It discusses the mechanical properties, nominal compositions, advantages, and engineering applications of various classes of alloy steels. They are low-alloy structural steels, SAE/AISI alloy steels, high-fracture-toughness steels, maraging steels, austenitic manganese steels, high-strength low-alloy steels, dual-phase steels, and transformation-induced plasticity steels.

Tool steels are specialty steels, produced in relatively low volumes, optimized for applications requiring precise combinations of wear resistance, toughness, and hot hardness. This chapter describes the AISI classification system by which tool steels are defined. It discusses primary types, including high-speed and shock-resisting steels, and their associated subtype groups (W, L, S, O, A, D, H, M, and T series). It also discusses the types of carbides found in tool steels and their influence on mechanical properties. The chapter concludes with a discussion on heat treatment effects unique to tool steels, including two-phase effects, austenite stabilization, and the conditioning of retained austenite.

This article discusses the composition and morphology of compacted graphite (CG) iron relative to that of gray and ductile iron. It explains that the graphite in CG iron is intermediate in shape between the spheroidal graphite found in ductile iron and the flake graphite in gray iron, giving it distinct advantages in a number of applications. The article also discusses the role of melt treatment elements and explains how alloying and heat treatment affect tensile strength, hardness, toughness, and ductility.

This article discusses the production, properties, and uses of high-alloy white irons. It explains how the composition and melt are controlled to produce a large volume of eutectic carbides, making these irons particularly hard and resistant to wear, and how the metallic matrix supporting the carbide phase can be adjusted via alloy content and heat treatment to optimize the balance between abrasion resistance and impact toughness. It also describes the effect of alloying elements and inoculants on various properties and behaviors and provides information on commercial alloy grades and applications.

This article discusses the role of alloying in the production and use of carbon and low-alloy steels. It explains how steels are defined and selected based on alloy content and provides composition and property data for a wide range of designations and grades. It describes the effect of alloying on structure and composition and explains how alloy content can be controlled to optimize properties and behaviors such as ductility, strength, toughness, fatigue and fracture resistance, and resistance to corrosion, wear, and high-temperature creep. It also examines the effect of alloying on processing characteristics such as hardenability, formability, weldability, machinability, and temper embrittlement. In addition, the article provides an extensive amount of engineering data with relevance in materials selection.