This chapter discusses the factors that govern the mechanical properties of titanium, beginning with the morphology of the alpha phase. It explains that the shape of the alpha phase has a significant effect on many properties, including hardness, tensile strength, toughness, and ductility as well as creep, fatigue strength, and fatigue crack growth rate. It also discusses the influence of other titanium phases and the properties of titanium-based intermetallic compounds, metal-matrix composites, and shape-memory alloys.

This chapter discusses the advantages and disadvantages of metal matrix composites and the methods used to produce them. It begins with a review of the composition and properties of aluminum matrix composites. It then describes discontinuous composite processing methods, including stir and slurry casting, liquid metal infiltration, spray deposition, powder metallurgy, extrusion, hot rolling, and forging. The chapter also provides information on continuous-fiber aluminum and titanium composites as well as particle-reinforced titanium and fiber metal (glass aluminum) laminates.

This chapter discusses the types of fibers and matrix materials used in ceramic matrix composites and the role of interfacial coatings. It describes the methods used to produce ceramic composites, including powder processing, slurry infiltration and consolidation, polymer infiltration and pyrolysis, chemical vapor infiltration, directed metal oxidation, and liquid silicon infiltration.

This chapter discusses the effect of fiber length and orientation on the strength and stiffness of discontinuous-fiber composites. It also describes several fabrication processes, including spray-up, compression molding, reaction injection molding, and injection molding.

This chapter discusses the use of mechanical fastening and adhesive bonding, the primary methods for joining polymer matrix composites. It describes and analyzes the basic types of mechanically fastened joints, including single-hole and multirow bolted composite joints. It then reviews the advantages and disadvantages of adhesively bonded joints and compares and contrasts the long-term performance of various joint designs. The chapter also discusses the merits of stepped-lap and bonded-bolted joints.

This chapter covers basic machining and assembly operations, with an emphasis on hole preparation for mechanical fasteners. It describes manual, power feed, and automated drilling techniques as well as reaming and countersinking. It discusses various types of fasteners, including rivets, pins, and bolts, along with selection factors and special considerations for composite joints. It also includes information on interference-fit and blind fasteners as well as trimming operations, general assembly considerations, and sealing and painting procedures.

This chapter discusses composite testing procedures, including tension, compression, shear, flexure, and fracture toughness testing as well as adhesive shear, peel, and honeycomb flatwise tension testing. It also discusses specimen preparation, environmental conditioning, and data analysis.

This chapter discusses the use of thermoset and thermoplastic resins in polymer matrix composites. It begins by explaining how the two classes of polymer differ and how it impacts their use as matrix materials. It then goes on to describe the characteristics of polyester, vinyl ester, epoxy, bismaleimide, cyanate ester, polyimide, and phenolic resins and various toughening methods. The chapter also covers thermoplastic matrix materials and product forms and provides an introduction to the physiochemical tests used to characterize resins and cured laminates.

This chapter discusses the primary methods used to repair composites, including fill repairs, injection repairs, bolted repairs, and bonded repairs. It also discusses issues associated with field repairs.

This chapter explains how polymeric adhesives are applied to composite as well as metal parts, forming bonded structures. It describes surface preparation practices and techniques, epoxy selection and use, and bonding procedures.

This chapter discusses design and certification considerations, including materials and process selection, the building block approach to certification, design allowables, and design guidelines. It also includes information on damage tolerance and environmental sensitivity.

This chapter discusses the advantages and disadvantages of sandwich and integral cocured structures, and the methods by which they are made. It begins by explaining where and how sandwich construction is used and why it is so efficient. It then describes the design and fabrication of honeycomb panels and foam cores along with their respective applications and unique attributes. The chapter also discusses the cocuring process and its use in fabricating unitized structures.

Metal-matrix composites (MMCs) work at higher temperatures than their base metal counterparts and can be engineered for improved strength, stiffness, thermal conductivity, abrasion and/or creep resistance, and dimensional stability. This chapter examines the properties, compositions, and performance-cost tradeoffs of common MMCs, including aluminum-matrix composites, titanium-matrix composites, and fiber-metal laminates. It also explains how fiber-reinforced composites and laminates are made, describing both continuous and discontinuous fiber matrix production processes.

This chapter discusses the composition, properties, and uses of the most common beryllium alloys and composites. It provides information on beryllium-aluminum, beryllium-copper, and beryllium-titanium as well as beryllium-antimony and beryllium-iron systems.

This chapter discusses some of the promising developments in the use of titanium, including titanium aluminides, titanium matrix composites, superplastic forming, spray forming, nanotechnology, and rapid solidification rate processing. It also reports on efforts to increase the operating temperature range of conventional titanium alloys and reduce costs.

This chapter covers the basic metallurgy of titanium, explaining how it influences the development of microstructure and the mechanical properties that can be achieved. It describes the nature of each of the four major phases of titanium, the effect of alloying elements on phase transformations, and the formation of secondary phases. The chapter presents and interprets a wide range of micrographs and includes several tables containing composition and tensile property data for many titanium alloys.

This chapter examines the process, structure, and property relationships in titanium alloys. It provides information on microstructures and strengthening mechanisms, the role of alloy and interstitial elements, and the effect of composition, processing, and surface treatments on tensile and yield strength, fracture toughness, hardness, ductility, and creep and fatigue behaviors. The chapter covers wrought, cast, and powder metal titanium alloys and contains an extensive amount of property data.

Titanium and its alloys are used chiefly for their high strength-to-weight ratio, but they also have excellent corrosion resistance, better even than stainless steels. Titanium, as the chapter explains, is protected by a tenacious oxide film that forms rapidly on exposed surfaces. The chapter discusses the factors that influence the growth and quality of this naturally passivating film, particularly the role of oxidizing and inhibiting species, temperature, and alloying elements. It also discusses the effect of different corrosion processes and environments as well as hydrogen, stress-corrosion cracking, liquid metal embrittlement, and surface treatments.

Cleaning procedures serve to remove scale, tarnish films, and other contaminants that form or are otherwise deposited on the surface of titanium during processing operations such as hot working and heat treatment. This chapter explains what makes titanium susceptible to the formation of scale and how it can be removed via belt grinding, abrasive blasting, and molten salt descaling baths. It also discusses the role of acid pickling, barrel finishing, polishing, and buffing as well as the use of chemical conversion coatings and protective platings.

This chapter describes the basic steps in the production of titanium ingots and their subsequent conversion to standards product forms. It explains how titanium ore is reduced to a spongy residue, then granularized, compacted, and melted (along with alloying additions) to form an ingot, which may be remelted several times to achieve the necessary properties. It also discusses the cause of defects and ingot imperfections and the benefits of billet reduction and grain-refinement processes.