Metal-matrix composites can operate at higher temperatures than their base metal counterparts and, unlike polymer-matrix composites, are nonflammable, do not outgas in a vacuum, and resist attack by solvents and fuels. They can also be tailored to provide greater strength and stiffness, among other properties, in preferred directions and locations. This chapter discusses the processes and procedures used in the production of fiber-reinforced aluminum and titanium metal-matrix composites. It explains how the length and orientation of reinforcing fibers affect the properties and processing characteristics of both aluminum and titanium composites. It also provides information on fiber-metal laminates and the use of different matrix metals and reinforcing materials.

This chapter discusses the advantages and disadvantages of metal matrix composites and the methods used to produce them. It begins with a review of the composition and properties of aluminum matrix composites. It then describes discontinuous composite processing methods, including stir and slurry casting, liquid metal infiltration, spray deposition, powder metallurgy, extrusion, hot rolling, and forging. The chapter also provides information on continuous-fiber aluminum and titanium composites as well as particle-reinforced titanium and fiber metal (glass aluminum) laminates.

This article discusses the role of alloying in the production and use of titanium. It explains how alloying elements affect transformation temperatures, tensile and creep strength, elasticity, hardness, and corrosion behaviors. It provides composition and property data for commercial grades of titanium, addresses processing issues, and identifies operating environments where certain titanium alloys are susceptible to stress-corrosion cracking.

Metal-matrix composites (MMCs) work at higher temperatures than their base metal counterparts and can be engineered for improved strength, stiffness, thermal conductivity, abrasion and/or creep resistance, and dimensional stability. This chapter examines the properties, compositions, and performance-cost tradeoffs of common MMCs, including aluminum-matrix composites, titanium-matrix composites, and fiber-metal laminates. It also explains how fiber-reinforced composites and laminates are made, describing both continuous and discontinuous fiber matrix production processes.

This chapter discusses the properties and uses of fiber-reinforced composites. It also describes the effect of volume fraction and fiber length.

This chapter discusses the ambient-temperature corrosion characteristics of aluminum metal-matrix composites (MMCs), including composites formed with boron, graphite, silicon carbide, aluminum oxide, and mica. It also discusses the effect of stress-corrosion cracking on graphite-aluminum composites and the use of protective coatings and design criteria for corrosion prevention.

This chapter discusses the types of fibers and matrix materials used in ceramic matrix composites and the role of interfacial coatings. It describes the methods used to produce ceramic composites, including powder processing, slurry infiltration and consolidation, polymer infiltration and pyrolysis, chemical vapor infiltration, directed metal oxidation, and liquid silicon infiltration.

This chapter discusses the effect of fiber length and orientation on the strength and stiffness of discontinuous-fiber composites. It also describes several fabrication processes, including spray-up, compression molding, reaction injection molding, and injection molding.

Polymer-matrix composites are among the lightest structural materials in use today. They are also highly resistant to corrosion and fatigue and their load-carrying capabilities, such as strength and stiffness, can be tailored for specific applications. This chapter discusses the primary advantages and disadvantages of polymer-matrix composites, how they are produced, and how they perform in different applications. It describes the construction of laminates, the fibers and resins used, and the methods by which they are combined. It explains how strength, modulus, toughness, and high-temperature and corrosion behaviors are determined by the orientation, shape, and spacing of fibers, the number of plies, resin properties, and consolidation and forming methods. The chapter also covers secondary fabrication processes, such as thermoforming, machining, and joining, as well as production equipment and product forms, and include guidelines for optimizing tradeoffs when selecting fibers, resins, and production techniques.

Ceramic-matrix composites possess many of the desirable qualities of monolithic ceramics, but are much tougher because of the reinforcements. This chapter explains how reinforcements are used in ceramic-matrix composites and how they alter energy-dissipating mechanisms and load-carrying behaviors. It compares the stress-strain curves for monolithic ceramics and ceramic-matrix composites, noting improvements afforded by the addition of reinforcements. It then goes on to discuss the key attributes, properties, and applications of discontinuously reinforced ceramic composites, continuous fiber ceramic composites, and carbon-carbon composites. It also describes a number of ceramic-matrix composite processing methods, including cold pressing and sintering, hot pressing, reaction bonding, directed metal oxidation, and liquid, vapor, and polymer infiltration.

This chapter discusses the failure mechanisms associated with fiber-reinforced composites. It begins with a review of fiber-matrix systems and the stress-strain response of unidirectional lamina and both notched and unnotched composite laminate specimens. It then explains how cyclic loading can lead to delamination, the primary failure mode of most composites, and describes some of the methods that have been developed to improve delamination resistance, assess damage tolerance, determine residual strength, and predict failure modes.

Titanium aluminides are lightweight materials that have relatively high melting points and good high-temperature strength. They also tend to be stronger and lighter than conventional titanium alloys, but considerably less ductile. This chapter begins with a review of the titanium-aluminum phase diagram, focusing on the properties, compositions, and microstructures of alpha-2 Ti3Al alloys. It then describes the properties, microstructures, and compositions of orthorhombic, gamma, and near-gamma alloys as well as the processing methods and procedures normally used in their production.

This chapter discusses the factors that govern the mechanical properties of titanium, beginning with the morphology of the alpha phase. It explains that the shape of the alpha phase has a significant effect on many properties, including hardness, tensile strength, toughness, and ductility as well as creep, fatigue strength, and fatigue crack growth rate. It also discusses the influence of other titanium phases and the properties of titanium-based intermetallic compounds, metal-matrix composites, and shape-memory alloys.

Titanium alloys are generally resistant to stress-corrosion cracking (SCC), but under certain conditions, the potential for problems exists. This chapter identifies the types of service environments where titanium alloys have exhibited signs of SCC. It begins by describing the nominal composition, designation, and grade of nearly two dozen commercial titanium alloys and the different types of media (including oxidizers, organic compounds, hot salt, and liquid metal) in which SCC has been observed. It discusses the mechanical and metallurgical factors that influence SCC behavior and examines the cracking and fracture mechanisms that appear to be involved. The chapter also includes information on SCC test standards and provides detailed guidelines on how to prevent or mitigate the effects of SCC.

Titanium alloys are classified according to the amount of alpha and beta phase material retained in their structures at room temperature. This chapter discusses the metallurgy, composition, processing, and properties of titanium and its alloys. It provides information on melting, forging, casting, heat treating, and secondary fabrication. It also discusses the advantages and disadvantages of titanium and its alloys in various applications.

Titanium is a lightweight metal used in a growing number of applications for its strength, toughness, stiffness, corrosion resistance, biocompatibility, and high-temperature operating characteristics. This chapter discusses the applications, metallurgy, properties, compositions, and grades of commercially pure titanium and alpha and near-alpha, alpha-beta, and beta titanium alloys. It describes primary and secondary fabrication processes, including melting, forging, forming, heat treating, casting, machining, and joining as well as powder metallurgy and direct metal deposition. It also compares and contrasts the properties of wrought, cast, and powder metal titanium products and discusses corrosion behaviors.

This chapter discusses the various methods used to join titanium alloy assemblies, focusing on welding processes and procedures. It explains how welding alters the structure and properties of titanium and how it is influenced by composition, surface qualities, and other factors. It describes several welding processes, including arc welding, resistance welding, and friction stir welding, and addresses related issues such as welding defects, quality control, and stress relieving. The chapter also covers mechanical fastening techniques along with adhesive bonding and brazing.

This appendix provides datasheets describing the chemical composition, processing characteristics, mechanical and fabrication properties, and heat treating of commercially pure and modified titanium. The datasheets address four grades of unalloyed titanium (ASTM Grade 1, UNS R50250; ASTM Grade 2, UNS R50400; ASTM Grade 3, UNS R50550; and ASTM Grade 4, UNS R50700), two grades of modified titanium (ASTM Grade 7, UNS R52400; and ASTM Grade 11, UNS R52250), and alloy Ti-0.3Mo-0.8Ni (ASTM Grade 12, UNS R53400).

This appendix provides datasheets describing the chemical composition, processing characteristics, mechanical and fabrication properties, and heat treating of alpha and near-alpha titanium alloys. Datasheets are provided for the following alloys: Ti-3Al-2.5V (ASTM Grade 9, UNS R56320), Ti-5Al-2.5Sn (UNS R54520/R54521), Ti-6Al-2Nb-1Ta-0.8Mo (UNS R56210), Ti-6Al-2Sn-4Zr-2Mo-0.08Si (UNS R54620), Ti-8Al-1Mo-1V (UNS R54810), and Ti-6Al-2.75Sn-4Zr-0.4Mo-0.45Si (Ti-1100).

This appendix provides datasheets describing the chemical composition, processing characteristics, mechanical and fabrication properties, and heat treating of various grades of alpha-beta titanium. Datasheets are provided for the following alloys: Ti-5Al-2Sn-2Zr-4Mo-4Cr (UNS: R58650, Ti-17); Ti-6Al-2Sn-4Zr-6Mo (UNS R56260, Ti-6246); Ti-6Al-4V (UNS R56400) and Ti-6Al-4V ELI (UNS R56401); Ti-6Al-6V-2Sn (UNS R56620, Ti-662); Ti-7Al-4Mo (UNS R56740); Ti-6Al-1.7Fe-0.1Si (TiMetal 62S); Ti-4.5Al-3V-2Mo-2Fe (SP-700); Ti-6Al-7Nb (IMI 367); Ti-4Al-4Mo-2Sn-0.5Si (IMI 550); Ti-4Al-4Mo-4Sn-0.5Si (IMI 551); Ti-6Al-2Sn-2Zr-2Mo-2Cr-0.25Si (Ti-6-22-22S); Ti-5Al-2.5Fe (DIN 3.7110, Tikrutan LT 35); and Ti-5Al-5Sn-2Zr-2Mo-0.25Si (UNS R54560, Ti-5522-S).