Thermal barrier coatings (TBCs) are applied using thermal spray coating (TSC) processes to components that are internally cooled and operated in a heated environment. The TSC microstructures are prone to interactions with common metallographic procedures that may result in artifacts and misinterpretation of the TSC microstructure. This article aims to aid in identifying metallographic TSC artifacts, specifically in the air plasma spray zirconia-based TBC, including both of its common constituents, the bond coating and the top coating. Artifacts that result from specific sectioning and mounting practices, as well as from different polishing times, are presented. Additionally, the article discusses the factors in optical microscopy and scanning electron microscopy that affect microstructure interpretation.

This article summarizes the results of work completed by the ASM Thermal Spray Society Advisory Committee to identify key research challenges and opportunities in the thermal spray field. It describes and prioritizes research priorities related to emerging process methods, thermal spray markets and applications, and process robustness, reliability, and economics.

This article, prepared under the auspices of the ASM Thermal Spray Society Committees on Accepted Practices, describes a procedure for evaluating residual stresses in thermal spray coatings, which is an extension of the well-known layer removal method to include the Young’s modulus and Poisson’s ratio properties of the thermal spray coating material and the substrate. It presents questions and answers that were selected to introduce residual stresses in thermal spray coatings. The article describes equipment and the laboratory procedure for the modified layer removal method and provides the description of the residual stress specimen. It also describes the procedures for applying or installing bonded resistance strain gages, the dimensions of the test specimen, the procedure for removing layers, and the method for interpreting the data to evaluate residual stresses. The spreadsheet program, “ MLRM for Residual Stresses ,” is available as a supplement to this document.

Superalloys tend to operate in environments where they are subjected to high-temperature corrosion, oxidation, and the erosive effects of hot gases. This chapter discusses the nature of these attacks and the effectiveness of various protection methods. It describes the primary forms of oxidation, the development of protective oxides, and the conditions associated with mixed gas corrosion and hot corrosion attack. It discusses oxidation and corrosion testing, the equipment used, and various ways to present the associated data. It describes the effect of gaseous oxidation on different alloys, discusses the formation of oxide scale in the presence of mixed gases, and explains how alloy composition contributes to oxide growth. The chapter discusses the underlying chemistry of hot corrosion, how to identify its effects, and how it progresses under various conditions. It also discusses protective coatings, including aluminide diffusion, overlay, and thermal barrier types, and how they perform in different environments based on their ability to tolerate strain.

Cold spray coatings technology has the potential to provide surface enhancement for applications in sectors such as defense and aerospace, oil and gas, power generation, medical, automotive, electronics, and railways. The ability to deposit clean metallic coatings is used in applications requiring corrosion/oxidation protection, erosion/wear protection, additive manufacturing, and fabricating free forms. This chapter discusses the function, advantages, and benefits of some of these applications.

This chapter explains how materials selection becomes much more difficult when designing for high-temperature corrosion environments. It also discusses the use of cladding and weld overlays to compensate for material deficiencies and prolong service life.

This article provides a brief description of commercially important thermal spray processes and gives examples of applications and application requirements. The processes covered are flame, wire arc, plasma, high-velocity oxyfuel processes, detonation gun, and cold spray methods. Examples are provided of the applications in aerospace, automotive, and medical device industries as well as the use of thermal spray as an additive manufacturing technique.

Superalloys are nickel, iron-nickel, and cobalt-base alloys designed for high-temperature applications, generally above 540 deg C. This chapter covers the metallurgy, composition, and properties of cast and wrought superalloys. It provides information on melting, heat treating, and secondary fabrication processes. It also covers coating technology, including aluminide diffusion and overlay coatings, and addresses the advantages and disadvantages of superalloys in various applications.

This appendix includes selected references on topics related to the production and application of superalloys, including properties and microstructure; melting/ingot breakdown; forging/powder metallurgy; machining, heat treating, joining, refurbishment/repair; investment casting; coatings/corrosion; and modeling.

This chapter discusses the use of coating methods and materials and their impact on corrosion and wear behaviors. It provides detailed engineering information on a wide range of processes, including organic, ceramic, and hot dip coating, metal plating and cladding, and the use of weld overlays, thermal spraying, and various deposition technologies.

The basic concept for most methods of corrosion protection is to remove one or more of the electrochemical cell components so that the pure metal or metal alloy of interest will not corrode. Another widely used corrosion protection approach is to change the nature of the anode so that it becomes the cathode (cathodic protection). This chapter briefly reviews these methods of corrosion protection. The factors affecting corrosion behavior are covered. In addition, the chapter provides information on coatings and inhibitors, which are used in corrosion protection.