This chapter describes the classification of steels and the various compositional categories of commercial steel products. It explains how different alloying elements affect the properties of carbon and low-alloys steels and discusses strength, toughness, and corrosion resistance and how to improve them.

This chapter describes the basic steps in the steelmaking process. It explains how iron is reduced from ore in the liquid state through the classic blast furnace process and in the solid state by direct reduction. It discusses the conversion of iron to steel and the technological advancements that led from open hearth steelmaking to basic oxygen processes and ultimately the electric arc furnace (EAF). It describes the versatility, efficiency, and scalability of the EAF process and its impact on recycling and sustainability. It explains how EAF refining and deoxidation practices have changed over time, and describes secondary refining processes such as degassing, homogenization, rinsing, and remelting.

This chapter focuses on the evolution of steel production from 1870 to 1900. It begins with a review of the life of the inventor of the air-boiling process, William Kelly. This is followed by a discussion on how Bessemer's air-blowing process entered the steel production industry and the development of the Kelly-Bessemer process by Alexander Holley. The chapter then discusses how Andrew Carnegie lowered the cost to produce steel, how he entered the iron and steelmaking industry, and how Captain Billy Jones joined Carnegie to expand Carnegie steel. The chapter further provides information on the great strike of 1892 at Homestead and the rapid growth in steel markets. It ends with a discussion about the factors that led Carnegie to sell his steel empire.

Tool steels are the ferrous alloys used to manufacture tools, dies, and molds that shape, form, and cut other materials, including steels, nonferrous metals, and plastics. This chapter explores the considerations that make tool steels a very special class of steels, the long historical evolution of iron and steel manufacture, including steels for tools, and the development of tool steels as they emerged from the general class of iron and steel products.

Many of the structural characteristics of steel products are a result of changes that occur during solidification, particularly volume contractions and solute redistribution. This chapter discusses the solidification process and how it affects the quality and behaviors of steel. It explains how steel shrinks as it solidifies, causing issues such as pipe and voids, and how differences in the solubility of solid and liquid steel lead to compositional heterogeneities or segregation. It describes the dendritic nature of solidification, peritectic and eutectic reactions, microporosity, macro- and microsegregation, and hot cracking, as well as the effects of solidification and remelting on castings, ingots, and continuous cast products. It explains how to determine where defects originate in continuous casters and how to control alumina, sulfide, and nitride inclusions.