This appendix is a timeline of events related to the discovery, development, and commercialization of stainless steels.

This chapter presents the history of stainless steel and provides an overview of the key concepts discussed in this book. This book covers a broad spectrum of historical events, many of which have not been touched upon in other works on stainless steel. It includes the discoveries of the various metallic elements that are used in the various alloys of stainless steel and discusses numerous experiments conducted during the 19th century with iron-base alloys containing chromium and carbon.

This appendix provides tensile property and fracture toughness data for various low-alloy and stainless steels.

The various types of stainless steel have very different deformation characteristics in terms of strain hardening and anisotropy. It is important to understand and exploit these characteristics to optimize forming of stainless steels. This chapter discusses the various deformation processes involved in sheet-forming techniques, namely stretch forming and deep drawing. In addition, it provides information on some of the factors pertinent to cold-heading and hot forming of stainless long products.

Steels that resist corrosive attack from normal atmospheric exposure and contain a minimum of 10.5% Cr and 50% Fe are generally classified as stainless steels. Their special qualities lie in a chromium-rich oxide surface film that quickly regrows when damaged. This chapter discusses the classification, composition, properties, treatments, and applications of austenitic, ferritic, martensitic, duplex, precipitation-hardening, powder metallurgy, and cast stainless steels. It also reviews the history of stainless steels and provides information on alloy designation systems.

This chapter discusses the growing use of sintered stainless steels in automotive applications and various types of filters and filtering media. It also describes how these materials are produced in the form of metal foams and cellular structures and how they serve as flake pigments in corrosion-resistant coatings.

This chapter describes some of the technological milestones of the early 20th century, including the invention of tungsten carbide tool steel, the use of age-hardening aluminum in the Wright Flyer , the development of a new heat treating process for aluminum alloys, and Ford’s pioneering use of weight-saving vanadium alloys in Model T cars. It explains how interest in chromium alloys spread throughout the world, spurring the development of commercial stainless steels. The chapter concludes with a bullet point timeline of early 20th century achievements and a brief assessment of more recent innovations.

Steels with chromium contents above 12% show high resistance to oxidation and corrosion and are generally designated as stainless steels. This chapter discusses the compositions, microstructures, heat treatments, and properties of martensitic, ferritic, austenitic, ferritic-austenitic (duplex), and precipitation hardening stainless steels. It also describes solidification sequences and explains how chromium carbides may segregate to grain boundaries at certain temperatures, making grain boundary regions susceptible to intercrystalline or intergranular corrosion.

This article discusses the steps in the primary processing of stainless steels: melting, refining, remelting, casting, and hot rolling. It provides information of the major categories of defects in hot rolled stainless steels, namely hot mill defects, inclusion-related defects, and hot ductility-related defects.

Stainless steels and nickel-base alloys are recognized for their resistance to general corrosion and other categories of corrosion. This chapter examines the effects of specific alloying elements, metallurgical structure, and mechanical conditioning on the corrosion resistance of these alloys. Some categories of corrosion covered are pitting, crevice, intergranular, stress-corrosion cracking, general, and high-temperature corrosion.

Stainless steels have a wide variety of applications for household products, food-handling equipment, major appliances, medical equipment, and industrial equipment. Stainless is also featured in many architectural designs and monuments. Many of the most important applications of stainless steel can be found in the transportation industry, where both the cutlery martensitic and the chromium-nickel austenitic stainless steels have been used. This chapter provides a detailed discussion on these applications.

This chapter discusses the development of stainless steel. It begins with some information on the discovery of stainless steel. This is followed by a discussion on the most important patents issued for stainless steel. Applications of stainless steel beyond their original use in cutlery and tableware are then presented. Information on the development of alloys for specific applications and on the argon oxygen decarburization process is also provided. The chapter ends with a discussion on the major use for stainless steel after WWII.

This chapter presents a brief description of the three-step process: melting, decarburizing, and alloying. It also discusses the following processes: wild process, rustless process, and Linde Argon-Oxygen decarburization process.

This chapter focuses on the metallurgical factors governing the machinability of stainless steels. It begins by describing the chemistry, cleanliness, structure, processing history, and the cross-section size of the stock of the different grades of stainless steel. This is followed by a general description of the machining behavior of the stainless steel families, namely ferritic, martensitic, austenitic, precipitation hardening, duplex, and super stainless steels. The beneficial effect of controlled inclusions is then discussed. The chapter ends with a section providing information on high-speed tool steel and carbide tooling, along with tool coatings and coolants applicable to stainless steel.

This chapter examines the early literature on stainless steel to gain an understanding of the state-of-the-art of stainless steel as it progressed through the first 37 years after the discoveries made in Sheffield and Essen.

In 1924, the American Society for Testing and Materials (ASTM) organized the symposium "Corrosion and Heat Resisting Alloys, and Electrical Resistance Alloys." It was the beginning of a major role that ASTM played in the history of stainless steel. This chapter provides information on the papers presented at the 1924 symposium. It also describes the role of ASTM in stainless steel standardization after the 1924 symposium.