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Published: 01 March 2012
Fig. 9.16 Regions of spinodal decomposition and classical nucleation and growth of precipitates. (a) Phase diagram with a miscibility gap. (b) Variation in free energy with composition for the system shown in (a) at temperature T ′. Source: Ref 9.9 as published in Ref 9.10 More
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Published: 01 June 2008
Fig. 4.10 Spinodal decomposition. Source: Ref 3 More
Image
Published: 01 December 2008
Fig. 6.9 The uphill diffusion in the spinodal decomposition. When A-B is strongly repulsive, the diffusion coefficient will take a negative value. (a) The phase diagram. (b) The change in structure and composition. (c) The free energy and the diffusion coefficient More
Book Chapter

Series: ASM Technical Books
Publisher: ASM International
Published: 01 March 2012
DOI: 10.31399/asm.tb.pdub.t53420171
EISBN: 978-1-62708-310-2
..., and goes on to identify the most common superlattice structures and their corresponding alloy phases. It also discusses the factors that limit the formation of superlattices along with the kinetics of spinodal decomposition and its effect on microstructure development. antiphase boundaries...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240053
EISBN: 978-1-62708-251-8
... of free energy that governs whether or not a phase transformation is possible, and then the kinetic considerations that determine the rate at which transformations take place. The chapter also describes important solid-state transformations such as spinodal decomposition and martensitic transformation...
Image
Published: 01 March 2012
Fig. 9.15 Two sequences for the formation of a two-phase mixture by diffusion processes. (a) Classical nucleation and growth. (b) Spinodal decomposition. Source: Ref 9.9 as published in Ref 9.10 More
Image
Published: 01 March 2012
Fig. 9.21 Backscatter scanning electron micrograph of an iron-copper alloy that was rapidly solidified after undergoing liquid-phase spinodal decomposition. Source: Ref 9.12 as published in Ref 9.10 More
Image
Published: 01 October 2011
Fig. 14.8 Two sequences for the formation of a two-phase mixture by diffusion processes. (a) Classical nucleation and growth. (b) Spinodal decomposition. Nominal chemical concentration, X 0 , is between two different equilibrium concentrations, X e * and X e **. More
Image
Published: 01 March 2012
Fig. 9.18 Miscibility gap. Region 1: Homogenous α is stable. Region 2: Homogenous α is metastable; only incoherent phases can nucleate. Region 3: Homogeneous α is metastable; coherent phases can nucleate. Region 4: Homogeneous α is unstable; spinodal decomposition occurs. Source: Ref 9.11 More
Series: ASM Technical Books
Publisher: ASM International
Published: 01 October 2011
DOI: 10.31399/asm.tb.mnm2.t53060333
EISBN: 978-1-62708-261-7
... growth from small composition fluctuations ( Fig. 14.8b ). Fig. 14.8 Two sequences for the formation of a two-phase mixture by diffusion processes. (a) Classical nucleation and growth. (b) Spinodal decomposition. Nominal chemical concentration, X 0 , is between two different equilibrium...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320167
EISBN: 978-1-62708-357-7
... into α 1 rich in A and α 2 rich in B. (See Sections 4.4 and 9.1 for metallographic consideration of spinodal decomposition. Fig. 6.9 The uphill diffusion in the spinodal decomposition. When A-B is strongly repulsive, the diffusion coefficient will take a negative value. (a) The phase diagram...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320091
EISBN: 978-1-62708-357-7
... the binodal curve. A binodal curve can be often seen in a solid solution as well as in a liquid solution, and a peculiar microstructure can be formed (it is called the spinodal decomposition). Fig. 4.13 Binodal curve of liquids (the hatched area indicates the miscibility gap). (a) Normal type...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320001
EISBN: 978-1-62708-357-7
... Spinodal decomposition 1960 Lifshitz-Wagner Ostwald ripening Kaufman-Hillert Calculation of phase diagrams Because the main topics in Table 1.1 are explained in detail in the following chapters, the historical overview is discussed a little more here. 1.4 Flowering of Materials Science...
Series: ASM Technical Books
Publisher: ASM International
Published: 31 December 2020
DOI: 10.31399/asm.tb.phtbp.t59310351
EISBN: 978-1-62708-326-3
... through heat treatment include: Solution-treated and aged aluminum alloys (e.g., aluminum-copper alloys) Solution-treated and aged cobalt alloys Solution-treated copper alloys (such as beryllium bronze, spinodal-hardening alloys, and order-hardening alloys) Quench-hardened (martensitic...
Book Chapter

Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240063
EISBN: 978-1-62708-251-8
... of the system is reduced, such as in the case for spinodal decomposition, which was covered in Chapter 4, “Introduction to Phase Transformations,” in this book. What is important is that the free energy of the system is reduced during diffusion. Fig. 5.1 Free-energy changes during diffusion...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.9781627083577
EISBN: 978-1-62708-357-7
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.ssde.t52310091
EISBN: 978-1-62708-286-0
... believed to be a result of the miscibility gap that exists in the iron-chromium system, by which ferrite undergoes spinodal decomposition into the iron-rich α, normal ferrite, and the chromium-rich α′, which is a brittle ordered alloy. Higher levels of chromium or the presence of copper or molybdenum...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 March 2012
DOI: 10.31399/asm.tb.pdub.t53420339
EISBN: 978-1-62708-310-2
... or precipitation within a metastable miscibility gap in the alloy system. They may form by homogeneous nucleation and grow at small undercoolings or by spinodal decomposition at large undercoolings or supersaturations. The GP zones are the first to nucleate because of their small size and coherency...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.ssde.t52310109
EISBN: 978-1-62708-286-0
... with temper embrittlement, which occurs in martensitic alloys at the same temperature. Temper embrittlement is the segregation of phosphorus to prior austenitic grain boundaries and does not occur in fully ferritic alloys. The α′ is the ordered equiatomic chromium iron phase that forms by spinodal...
Series: ASM Technical Books
Publisher: ASM International
Published: 30 April 2024
DOI: 10.31399/asm.tb.phtpp.t59380235
EISBN: 978-1-62708-456-7
... furnace which uses a mesh-type or cast-link belt to carry parts through the furnace. beta annealing Producing a beta phase by heating certain titanium alloys in the temperature range of which this phase forms followed by cooling at an appropriate rate to prevent its decomposition. black oxide A black...