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Published: 01 March 2012
Fig. 9.16 Regions of spinodal decomposition and classical nucleation and growth of precipitates. (a) Phase diagram with a miscibility gap. (b) Variation in free energy with composition for the system shown in (a) at temperature T ′. Source: Ref 9.9 as published in Ref 9.10
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Published: 01 June 2008
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Published: 01 December 2008
Fig. 6.9 The uphill diffusion in the spinodal decomposition. When A-B is strongly repulsive, the diffusion coefficient will take a negative value. (a) The phase diagram. (b) The change in structure and composition. (c) The free energy and the diffusion coefficient
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Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 March 2012
DOI: 10.31399/asm.tb.pdub.t53420171
EISBN: 978-1-62708-310-2
..., and goes on to identify the most common superlattice structures and their corresponding alloy phases. It also discusses the factors that limit the formation of superlattices along with the kinetics of spinodal decomposition and its effect on microstructure development. antiphase boundaries...
Abstract
This chapter explains how the presence of intermediate phases affects the melting behavior of binary alloys and the transformations that occur under different rates of cooling. It begins by examining the phase diagrams of magnesium-lead and copper-zinc, noting some of the complexities associated with intermediate phases. It then discusses the difference between ordered and disordered phases and how they are accounted for on phase diagrams. It describes how the atoms in a disordered solution may arrange themselves into an ordered array, forming a superlattice in the process of cooling, and goes on to identify the most common superlattice structures and their corresponding alloy phases. It also discusses the factors that limit the formation of superlattices along with the kinetics of spinodal decomposition and its effect on microstructure development.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240053
EISBN: 978-1-62708-251-8
... of free energy that governs whether or not a phase transformation is possible, and then the kinetic considerations that determine the rate at which transformations take place. The chapter also describes important solid-state transformations such as spinodal decomposition and martensitic transformation...
Abstract
This chapter provides a short introduction to phase transformations, namely, the liquid-to-solid phase transformations that occur during solidification and the solid-to-solid transformations that are important in processing, such as heat treatment. It also introduces the concept of free energy that governs whether or not a phase transformation is possible, and then the kinetic considerations that determine the rate at which transformations take place. The chapter also describes important solid-state transformations such as spinodal decomposition and martensitic transformation.
Image
Published: 01 March 2012
Fig. 9.15 Two sequences for the formation of a two-phase mixture by diffusion processes. (a) Classical nucleation and growth. (b) Spinodal decomposition. Source: Ref 9.9 as published in Ref 9.10
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Published: 01 March 2012
Fig. 9.21 Backscatter scanning electron micrograph of an iron-copper alloy that was rapidly solidified after undergoing liquid-phase spinodal decomposition. Source: Ref 9.12 as published in Ref 9.10
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Image
Published: 01 October 2011
Fig. 14.8 Two sequences for the formation of a two-phase mixture by diffusion processes. (a) Classical nucleation and growth. (b) Spinodal decomposition. Nominal chemical concentration, X 0 , is between two different equilibrium concentrations, X e * and X e **.
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Image
Published: 01 March 2012
Fig. 9.18 Miscibility gap. Region 1: Homogenous α is stable. Region 2: Homogenous α is metastable; only incoherent phases can nucleate. Region 3: Homogeneous α is metastable; coherent phases can nucleate. Region 4: Homogeneous α is unstable; spinodal decomposition occurs. Source: Ref 9.11
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Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 October 2011
DOI: 10.31399/asm.tb.mnm2.t53060333
EISBN: 978-1-62708-261-7
... growth from small composition fluctuations ( Fig. 14.8b ). Fig. 14.8 Two sequences for the formation of a two-phase mixture by diffusion processes. (a) Classical nucleation and growth. (b) Spinodal decomposition. Nominal chemical concentration, X 0 , is between two different equilibrium...
Abstract
Nonferrous alloys are heat treated for a variety of reasons. Heat treating can reduce internal stresses, redistribute alloying elements, promote grain formation and growth, produce new phases, and alter surface chemistry. This chapter describes heat treatment processes and how nonferrous alloys respond to them. It provides information on aluminum, cobalt, copper, magnesium, nickel, and titanium alloys and their composition, microstructure, properties, and processing characteristics.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320167
EISBN: 978-1-62708-357-7
... into α 1 rich in A and α 2 rich in B. (See Sections 4.4 and 9.1 for metallographic consideration of spinodal decomposition. Fig. 6.9 The uphill diffusion in the spinodal decomposition. When A-B is strongly repulsive, the diffusion coefficient will take a negative value. (a) The phase diagram...
Abstract
This chapter provides a detailed discussion on the Brownian motion, diffusion coefficient , and Fick's diffusion laws. It presents a review of solid phase diffusion and discusses the mechanism of diffusion and diffusion coefficient.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320091
EISBN: 978-1-62708-357-7
... the binodal curve. A binodal curve can be often seen in a solid solution as well as in a liquid solution, and a peculiar microstructure can be formed (it is called the spinodal decomposition). Fig. 4.13 Binodal curve of liquids (the hatched area indicates the miscibility gap). (a) Normal type...
Abstract
This chapter explains the significance of the phase diagram and its use in the development of new materials. The chapter describes the basic rules of heterogeneous equilibrium, presents a comparison between liquidus line and solidus line, and provides information on the solubility curve and the binodal curve.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320001
EISBN: 978-1-62708-357-7
... Spinodal decomposition 1960 Lifshitz-Wagner Ostwald ripening Kaufman-Hillert Calculation of phase diagrams Because the main topics in Table 1.1 are explained in detail in the following chapters, the historical overview is discussed a little more here. 1.4 Flowering of Materials Science...
Abstract
This chapter explains the distinction between materials and matter through the concept of microstructure. It presents the history of matter science and the establishment of metallography. The chapter provides an overview of the progress of steel technology, progress in synthetic polymers and ceramics, and establishment and development of materials science.
Series: ASM Technical Books
Publisher: ASM International
Published: 31 December 2020
DOI: 10.31399/asm.tb.phtbp.t59310351
EISBN: 978-1-62708-326-3
... through heat treatment include: Solution-treated and aged aluminum alloys (e.g., aluminum-copper alloys) Solution-treated and aged cobalt alloys Solution-treated copper alloys (such as beryllium bronze, spinodal-hardening alloys, and order-hardening alloys) Quench-hardened (martensitic...
Abstract
The term heat treatable alloys is used in reference to alloys that can be hardened by heat treatment, and this chapter briefly describes the major types of heat treatable nonferrous alloys. The discussion provides a general description of annealing cold-worked metals and describes some of the common nonferrous alloys that can be hardened through heat treatment. The nonferrous alloys covered include aluminum alloys, cobalt alloys, copper alloys, magnesium alloys, nickel alloys, and titanium alloys.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240063
EISBN: 978-1-62708-251-8
... of the system is reduced, such as in the case for spinodal decomposition, which was covered in Chapter 4, “Introduction to Phase Transformations,” in this book. What is important is that the free energy of the system is reduced during diffusion. Fig. 5.1 Free-energy changes during diffusion...
Abstract
Diffusion is the movement of atoms through the crystalline lattice. This chapter discusses the two main types of diffusion that can occur in solids: interstitial diffusion and substitutional diffusion. It describes Fick's first and second laws of diffusion, with emphasis on several applications of the latter. The chapter also provides information on the temperature dependence of diffusion, intrinsic diffusion coefficients (Kirkendall effect), and high diffusion paths.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.9781627083577
EISBN: 978-1-62708-357-7
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.ssde.t52310091
EISBN: 978-1-62708-286-0
... believed to be a result of the miscibility gap that exists in the iron-chromium system, by which ferrite undergoes spinodal decomposition into the iron-rich α, normal ferrite, and the chromium-rich α′, which is a brittle ordered alloy. Higher levels of chromium or the presence of copper or molybdenum...
Abstract
This chapter provides information on the structure, design aspects, mechanical properties, forming, machining, and corrosion resistance characteristics of duplex stainless steels. The different types of corrosion covered are general corrosion, pitting corrosion, crevice corrosion, and stress corrosion cracking.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 March 2012
DOI: 10.31399/asm.tb.pdub.t53420339
EISBN: 978-1-62708-310-2
... or precipitation within a metastable miscibility gap in the alloy system. They may form by homogeneous nucleation and grow at small undercoolings or by spinodal decomposition at large undercoolings or supersaturations. The GP zones are the first to nucleate because of their small size and coherency...
Abstract
This chapter discusses the basic principles of precipitation hardening, an important strengthening mechanism in nonferrous alloys as well as stainless steel. It begins with a detailed review of the theory of precipitation hardening, then describes its application to aluminum alloys and nickel-base superalloys.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.ssde.t52310109
EISBN: 978-1-62708-286-0
... with temper embrittlement, which occurs in martensitic alloys at the same temperature. Temper embrittlement is the segregation of phosphorus to prior austenitic grain boundaries and does not occur in fully ferritic alloys. The α′ is the ordered equiatomic chromium iron phase that forms by spinodal...
Abstract
This chapter discusses the alloy composition, metallurgy, mechanical behavior, stabilization, texture, anisotropy, high-temperature properties, and corrosion and oxidation resistance of ferritic stainless steels.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 30 April 2024
DOI: 10.31399/asm.tb.phtpp.t59380235
EISBN: 978-1-62708-456-7
... furnace which uses a mesh-type or cast-link belt to carry parts through the furnace. beta annealing Producing a beta phase by heating certain titanium alloys in the temperature range of which this phase forms followed by cooling at an appropriate rate to prevent its decomposition. black oxide A black...
Abstract
The appendix provides a glossary of practical heat treating terms.
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