Stainless steel retains strength and has excellent oxidation resistance from room temperature to nearly 1000 deg C relative to competitive materials. This chapter focuses on the high-temperature oxidation of stainless steel by oxygen or water vapor. It begins by discussing the thermodynamic conditions and electrochemical nature of oxidation and providing information on transient oxidation. This is followed by a description of Wagner's theory for metal oxidation. The volatile nature of Cr 2 O 3 is then reviewed. The chapter further discusses the causes and preventive measures of spalling and cracking of oxide scale. It ends with a section providing information on oxidation behaviors under less-oxidizing atmospheres.

This chapter focuses on resistance characteristics and methods of protecting different forms of high-temperature gaseous corrosion, namely high-temperature oxidation, sulfidation, carburization, hydrogen effects, and hot corrosion.

This chapter covers common types of erosion, including droplet, slurry, cavitation, liquid impingement, gas flow, and solid particle erosion, and major types of wear, including abrasive, adhesive, lubricated, rolling, and impact wear. It also covers special cases such as galling, fretting, scuffing, and spalling and introduces the concepts of tribocorrosion and biotribology.

The design of case-hardened components is an iterative process, requiring the consideration of multiple interrelated factors. This chapter walks readers through the steps involved in selecting an appropriate material and assessing the influence of alloy composition and cooling rate on core properties including hardenability, microstructure, tensile and yield strength, ductility, toughness, and fatigue resistance. It likewise explains how carbon affects case hardenability, surface hardness, and case toughness and how case depth influences residual stresses and bending and contact fatigue. It also discusses the effect of quenching methods and addresses the issue of distortion.

This chapter presents a detailed discussion on the three most frequent gear failure modes. These include tooth bending fatigue, tooth bending impact, and abrasive tooth wear. Tooth bending fatigue includes surface contact fatigue (pitting), rolling contact fatigue, contact fatigue (spalling), thermal fatigue, and shaft fatigue. Tooth bending impact includes tooth shear, tooth chipping, case crushing, and torsional shear.

Gears can fail in many different ways, and except for an increase in noise level and vibration, there is often no indication of difficulty until total failure occurs. This chapter begins with the classification of gear failure modes, followed by sections discussing the characteristics of various fatigue failures. Then, it provides information on the modes of impact fractures, wear, scuffing, and stress rupture. Next, the chapter describes the causes of gear failures and discusses the processes involved in conducting the failure analysis. Finally, the chapter presents examples of gear failure analysis.

Many metallic components, such as retorts in heat treat furnaces, furnace heater tubes and coils in chemical and petrochemical plants, waterwalls and reheater tubes in boilers, and combustors and transition ducts in gas turbines, are subject to oxidation. This chapter explains how oxidation affects a wide range of engineering alloys from carbon and Cr-Mo steels to superalloys. It discusses the kinetics and thermodynamics involved in the formation of oxides and the effect of surface and bulk chemistry. It provides oxidation data for numerous alloys and intermetallics in terms of weight gain, metal loss, depth of attack, and oxidation rate. It also discusses the effect of metallurgical and environmental factors such as oxygen concentration, high-velocity combustion gas streams, chromium depletion and breakaway, component thickness, and water vapor.

This chapter covers coatings and treatments that are used to improve the friction and wear behaviors of materials. It describes modifications that work by hardening contacting surfaces, including heat treating, vacuum coating, thermal spray, and plating, and those that separate or lubricate surfaces, including solid film, chemical conversion, and vacuum coatings, surface oiling and texturing, and lubricating platings. It compares and contrasts methods based on thickness and depth and their relative effect on friction, erosion, and wear.

Superalloys tend to operate in environments where they are subjected to high-temperature corrosion, oxidation, and the erosive effects of hot gases. This chapter discusses the nature of these attacks and the effectiveness of various protection methods. It describes the primary forms of oxidation, the development of protective oxides, and the conditions associated with mixed gas corrosion and hot corrosion attack. It discusses oxidation and corrosion testing, the equipment used, and various ways to present the associated data. It describes the effect of gaseous oxidation on different alloys, discusses the formation of oxide scale in the presence of mixed gases, and explains how alloy composition contributes to oxide growth. The chapter discusses the underlying chemistry of hot corrosion, how to identify its effects, and how it progresses under various conditions. It also discusses protective coatings, including aluminide diffusion, overlay, and thermal barrier types, and how they perform in different environments based on their ability to tolerate strain.

High strain rate tensile testing is used to understand the response of materials to dynamic loading. The behavior of materials under high strain rate tensile loads may differ considerably from that observed in conventional tensile tests. This chapter discusses the processes involved in determining strain rate effects in tension by conventional tensile tests and covers expanding ring tests, flat plate impact tests, split-Hopkinson pressure bar tests, and rotating wheel tests.

This chapter covers the friction and wear behaviors of carbon, alloy, and tool steels. It begins a review of commercially available shapes and forms. It then describes the metallurgy and microstructure of various designations and grades of each type of steel and explains how it affects their performance in adhesive and abrasive wear applications and in environments where they are subjected to solid particle, droplet, slurry, and cavitation erosion and fretting damage.

Titanium and its alloys are used chiefly for their high strength-to-weight ratio, but they also have excellent corrosion resistance, better even than stainless steels. Titanium, as the chapter explains, is protected by a tenacious oxide film that forms rapidly on exposed surfaces. The chapter discusses the factors that influence the growth and quality of this naturally passivating film, particularly the role of oxidizing and inhibiting species, temperature, and alloying elements. It also discusses the effect of different corrosion processes and environments as well as hydrogen, stress-corrosion cracking, liquid metal embrittlement, and surface treatments.

Durability is a generic term used to describe the performance of a material or a component made from that material in a given application. In order to be durable, a material must resist failure by wear, corrosion, fracture, fatigue, deformation, and exposure to a range of service temperatures. This chapter covers several types of component and material failure associated with wear, temperature effects, and crack growth. It examines temperature-induced, brittle, ductile, and fatigue failures as well as failures due to abrasive, erosive, adhesive, and fretting wear and cavitation fatigue. It also discusses preventative measures.

This chapter discusses the process characteristics, advantages, disadvantages, and applications of various processes involved in surface hardening of steel. These include pack carburizing, liquid carburizing, gas carburizing, vacuum carburizing, plasma carburizing, gas nitriding, liquid nitriding, carbonitriding, and hardfacing. The chapter describes two surface hardening processes by localized heat treatment: flame hardening and induction hardening. It also briefly summarizes other surface hardening processes, namely, aluminizing, siliconizing, chromizing, titanium carbide coatings, and boronizing.

This chapter explains how to take the known facts of a specific failure, place them in a systematic context to arrive at a logical conclusion, and point to a corrective measure. It presents example examinations to describe a systematic approach to failure examination.

This chapter covers the different types of wear encountered in metalworking processes. It discusses the mechanisms involved in adhesive, abrasive, chemical, and fatigue wear and key contributing factors, including the composition and structure of tool and workpiece materials, the characteristics of contact surfaces, and loading forces imposed by the process. It describes the nature of metal transfer between tool and workpiece surfaces and the role of lubricants, coatings, and textures. It also discusses the use of wear maps, the effects of adhesion, and material-lubricant interactions.

This chapter is a detailed account of the applications of stainless steel in automotive and transport systems. The discussion covers exhaust systems, structural components, automotive components, trucks, and rail transport.

This chapter concerns itself with the tribology of ceramics, cermets, and cemented carbides. It begins by describing the composition and friction and wear behaviors of aluminum oxide, silicon carbide, silicon nitride, and zirconia. It then compares and contrasts the microstructure, properties, and relative merits of cermets with those of cemented carbides.

This chapter compares and contrasts surface-engineering processes based on process availability, corrosion and wear performance, distortion effects, penetration depth or attainable coating thickness, and cost. It provides both quantitative and qualitative information as well as measured property values.