Aluminum has many outstanding properties, leading it to be used for a wide range of applications. It offers excellent strength-to-weight ratio, good corrosion and oxidation resistance, high electrical and thermal conductivity, exceptional formability, and relatively low cost. This chapter examines the metallurgy, composition, processing, and mechanical properties of aluminum and its alloys, both cast and wrought forms. It also covers heat treating and basic temper designations, including annealed, work hardened, solution heat treated, and solution heated treated and aged. The chapter concludes with information on corrosion and oxidation resistance.

Precipitation hardening is used extensively to strengthen aluminum alloys, magnesium alloys, nickel-base superalloys, beryllium-copper alloys, and precipitation-hardening stainless steels. This chapter discusses two types of particle strengthening: precipitation hardening, which takes place during heat treatment; and true dispersion hardening, which can be achieved by mechanical alloying and powder metallurgy consolidation. It provides information on the three steps of precipitation hardening of aluminum alloys: solution heat treating, rapid quenching, and aging.

This chapter discusses the basic principles of precipitation hardening, an important strengthening mechanism in nonferrous alloys as well as stainless steel. It begins with a detailed review of the theory of precipitation hardening, then describes its application to aluminum alloys and nickel-base superalloys.

The metallurgy of aluminum and its alloys offers a range of opportunities for employing heat treatments to obtain desirable combinations of mechanical and physical properties such that castings meet defined temper requirements. This chapter discusses the processes involved in solution heat treatment, quenching, precipitation hardening, and annealing of aluminum alloys. The effects of these processes on dimensional stability and residual stresses are also discussed. Troubleshooting and diagnosis of heat treating problems are covered in the concluding section of the chapter.

This data set presents aging response curves for a wide range of aluminum casting alloys. The aging response curves are of two types: room-temperature, or "natural," curves and artificial, or "high-temperature," curves. The curves in each group are presented in the numeric sequence of the casting alloy designation. The curves included are the results of measurements on individual lots considered representative of the respective alloys and tempers. The properties considered are yield strength, ultimate tensile strength, elongation, and Brinell hardness.

This appendix provides information on temper designations for strain-hardened aluminum, heat treatable aluminum alloys, and annealed aluminum products.

The term heat treatable alloys is used in reference to alloys that can be hardened by heat treatment, and this chapter briefly describes the major types of heat treatable nonferrous alloys. The discussion provides a general description of annealing cold-worked metals and describes some of the common nonferrous alloys that can be hardened through heat treatment. The nonferrous alloys covered include aluminum alloys, cobalt alloys, copper alloys, magnesium alloys, nickel alloys, and titanium alloys.

Magnesium occupies the highest anodic position on the galvanic series and can be subject to severe corrosion. The corrosion problem is due to the impurity elements iron, nickel, and copper. However, the use of higher-purity magnesium alloys has led to corrosion resistance approaching that of some of the competing aluminum casting alloys. This chapter begins with a general overview of magnesium metallurgy and alloy designations and moves on to discuss in detail the nominal compositions, mechanical properties, heat treatment, fabrication, and corrosion protection of magnesium casting alloys and wrought magnesium alloys. It also discusses the nominal compositions, properties, and applications of commercially pure zinc, zinc casting alloys, and wrought zinc alloys.

This chapter provides basic engineering information on aluminum alloys with an emphasis on their use in applications where weight is a significant design factor. It discusses the advantages and limitations of various types of aluminum along with their compositions, designations, and achievable strengths. It explains how some alloys are hardened through solution strengthening and cold working, while others are strengthened by precipitation hardening. It also describes production and fabrication processes such as melting, casting, rolling, forging, forming, extruding, heat treating, and joining, and includes a section on the causes and effects of corrosion and how they are typically controlled.

This appendix describes the information contained in titanium alloy datasheets and defines the many abbreviations that are used.

Many companies conduct only metallurgical evaluations in the wake of failures, discovering nothing more than the physical mechanism by which the failure occurred. The origin of failures, however, is often complex, involving not only physical mechanisms, but also human behavior and latent factors. Failures may also involve multiple parts, entire machines, or processes of any size and shape. The chapter examines the unique aspects of many failures and explains how they can sometimes be traced to systemic issues. It also covers the reasons why products fail, including improper service or operation, improper maintenance, improper testing, assembly errors, fabrication or manufacturing errors, and design errors. The case of the Tacoma Narrows Bridge collapse is presented to illustrate the consequence of overlooked factors, in this case, wind dynamics, and the importance of identifying root causes to prevent repeat failures.

This chapter presents guidelines for product designers to choose the best process and alloys while designing a casting. The discussion covers some of the factors pertinent to the selection of the best process for the product function and performance, namely geometric factors, mechanical properties, tooling cost per piece, and overall cost factors. The chapter contains tables listing several markets, products, popular processes, and common alloys and the common processes used for a variety of markets and products.

This article examines the composition and properties of magnesium and its alloys. It discusses alloy and temper designations, applications and product forms, and commercial alloy systems, and explains how alloying elements affect physical and mechanical properties, processing characteristics, and corrosion behaviors.

Nonferrous alloys are heat treated for a variety of reasons. Heat treating can reduce internal stresses, redistribute alloying elements, promote grain formation and growth, produce new phases, and alter surface chemistry. This chapter describes heat treatment processes and how nonferrous alloys respond to them. It provides information on aluminum, cobalt, copper, magnesium, nickel, and titanium alloys and their composition, microstructure, properties, and processing characteristics.

All superalloys, whether precipitation hardened or not, are heated at some point in their production for a subsequent processing step or, as needed, to alter their microstructure. This chapter discusses the changes that occur in superalloys during heat treatment and the many reasons such changes are required. It describes several types of treatments, including stress relieving, in-process annealing, full annealing, solution annealing, coating diffusion, and precipitation hardening. It discusses the temperatures, holding times, and heating and cooling rates necessary to achieve the desired objectives of quenching, annealing, and aging along with the associated risks of surface damage caused by oxidation, carbon pickup, alloy depletion, intergranular attack, and environmental contaminants. It also discusses heat treatment atmospheres, furnace and fixturing requirements, and practical considerations, including heating and cooling rates for wrought and cast superalloys and combined treatments such as solution annealing and vacuum brazing.

Magnesium, by volume, is two-thirds the weight of aluminum and one-quarter the weight of steel. It also has good damping capacity, giving it an edge over other metals in high-vibration environments. This chapter discusses the basic metallurgy, alloy designations, compositions, and mechanical properties of cast and wrought magnesium alloys. It also describes the processes used to produce magnesium parts, the causes and effects of corrosion, and the use of protective coatings and treatments.

This chapter examines the stress-corrosion cracking (SCC) failure of stainless steel pipe welds in boiling water reactor (BWR) service. It explains where most of the failures have occurred and provides relevant details about the materials of construction, fabrication techniques, environmental factors, and cracking characteristics. It includes a model that accounts for the primary factors involved in intergranular SCC, namely, tensile stresses above the yield stress of the base material, a sensitized microstructure, and reactor cooling water. The chapter also provides proven remedies and mitigation techniques corresponding to a wide range of issues related to stress, sensitization, and operating conditions.

This chapter discusses the processes used in manufacturing to thermally alter the properties of metals and alloys. It begins with a review of the iron-carbon system, the factors that affect hardenability, and the use of continuous cooling transformation diagrams. It then explains how various steels respond to heat treatments, such as annealing, normalizing, spheroidizing, tempering, and direct and interrupted quenching, and surface-hardening processes, such as flame and induction hardening, carburizing, nitriding, and carbonitriding. It also addresses the issue of temper embrittlement and discusses the effect of precipitation hardening on aluminum and other alloys.

Titanium alloys are classified according to the amount of alpha and beta phase material retained in their structures at room temperature. This chapter discusses the metallurgy, composition, processing, and properties of titanium and its alloys. It provides information on melting, forging, casting, heat treating, and secondary fabrication. It also discusses the advantages and disadvantages of titanium and its alloys in various applications.

This chapter describes the formability and forming characteristics of low-carbon sheet steels, coated sheet steels, stainless steels, and aluminum and magnesium alloys. It provides property data as well as flow stress curves for numerous grades of each material and explains how composition, microstructure, and processing methods influence forming behaviors.