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solute drag
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Published: 01 November 2007
Image
Published: 01 December 2008
Fig. 5.21 (a) The model for solute drag effect on the migration of grain boundary (the solute drag effect decreases the mobility of the grain boundary M). (b) An electric circuit analogy
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Image
Published: 01 December 2008
Fig. 5.22 Calculated examples of the drag effect due to solute atoms on the grain growth. (a) Energy and the mobility of boundary. (b) Grain growth
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Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 January 2015
DOI: 10.31399/asm.tb.spsp2.t54410099
EISBN: 978-1-62708-265-5
... in the isothermal TTT diagram for 4340 steel ( Fig. 6.13 ). Such bays correlate with the presence of substitutional alloying elements that may partition to or from ferrite and concentrate at austenite-ferrite interfaces, creating a solute drag , or significant restraining force, on the formation of bainitic...
Abstract
Bainite is an intermediate temperature transformation product of austenite. This chapter describes the conditions under which bainite is likely to form. It discusses the effects of alloying on bainitic transformation, the difference between upper and lower bainite, and the influence of solute drag on bainite formation mechanisms. It also discusses the development of ferrite-carbide bainites and their effect on toughness, hardness, and ductility.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 November 2007
DOI: 10.31399/asm.tb.smnm.t52140071
EISBN: 978-1-62708-264-8
... effect of particle and solute drag. forging grain size heat treatment particle drag phase transformation recrystallization solute drag AS MENTIONED in Chapter 5, “Mechanical Properties,” it is important to keep the grain size of steels as small as possible in order to improve...
Abstract
Grain size has a determining effect on the mechanical properties of steel and responds favorably to forging and heat treating. This chapter explains how to measure and quantify grain size and how to control it through thermal cycling and forging operations. It describes how surface tension acting on grain-boundary segments contributes to grain growth and how the formation of new grains, driven by phase transformations and recrystallization, lead to a reduction in average grain size. It also discusses the effect of alloying elements on grain growth rates, particularly the curbing effect of particle and solute drag.
Image
Published: 01 December 2008
Fig. 5.20 Motion of solvent atoms and solute atoms according to the grain-boundary movement. (a) Transfer of solvent atoms. (b) Drag of solute atoms
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Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320123
EISBN: 978-1-62708-357-7
..., the interface energy of solid solutions in an alloy or of a ceramic and a metal is difficult to estimate because it is necessary to consider the chemical interactions between the atoms. The next exercise is the simplest example of calculation. [Exercise 5.3] Show the interface energy of L I /L II when...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 1983
DOI: 10.31399/asm.tb.mlt.t62860237
EISBN: 978-1-62708-348-5
... Solution strengthening Haasen (1965) Haasen (1968) Fleischer and Hibbard (1963) § 7.2.6 Athermal strengthening by grain boundaries and precipitates Brown and Ham (1971) § 7.3.3 Martensitic transformations Reed (1962) § 7.3.5 Yield points Hahn (1962...
Abstract
The mechanical properties of a material describe the relations between the stresses acting on the material and its resulting deformations. Stresses capable of producing permanent deformations, which remain after the stresses are removed, are considered in this chapter. The effects of cryogenic temperatures on the mechanical properties of metals and alloys are reviewed in this chapter; the effects on polymers and glasses are discussed briefly. The fundamental mechanisms controlling temperature-dependent mechanical behavior, phenomena encountered in low-temperature testing, and the mechanical properties of some representative engineering metals and alloys are described. Modifications of test procedures for low temperatures and sources of data are also included.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 March 2012
DOI: 10.31399/asm.tb.pdub.t53420143
EISBN: 978-1-62708-310-2
... of these substitutional alloying elements will have a significant effect on the reaction kinetics as well. The addition of substitutional elements will decrease the diffusion rate and slow down the reaction kinetics, an effect known as partitioning and solute drag. Much like carbon, these substitutional alloying elements...
Abstract
This chapter discusses the characteristics of eutectoid transformations, a type of solid-state transformation associated with invariant reactions, focusing on the iron-carbon system of steel. It describes the compositions, characteristics, and properties of ferrite, eutectoid, hypoeutectoid, and hypereutectoid structures and how they are affected by the addition of various alloying elements. The chapter also discusses the formation of peritectoid structures in the uranium-silicon alloy system.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 1995
DOI: 10.31399/asm.tb.sch6.t68200437
EISBN: 978-1-62708-354-6
... from a surface as a consequence of being exposed to flowing solids, fluids or gases. ACj In hypereutectoid steel, the temperature at which cementite goes into complete solution with austenite. Acj . . . The temperature at which austenite begins to form on heating. Ac3 . . . In hypoeutectoid steel...
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 March 2000
DOI: 10.31399/asm.tb.aet.t68260149
EISBN: 978-1-62708-336-2
..., and similar) have been used particularly for railway rolling stock bodies, load-bearing structures, and welded structures. These alloys respond well in solution heat treatment if the extrusion comes out of the press a little over 400 °C (752 °F), they have a low quench sensitivity, and they maintain good...
Abstract
This chapter discusses the extrusion characteristics of relatively soft aluminum alloys. It begins by identifying alloy designations within the class and the types of extrusions made from them. It then explains how extruded shapes and cross-sections are defined and how to analyze and assess important process variables such as runout, extrusion pressure, ram speed, and butt thickness. It also provides best practices for various operations and explains how to identify and remedy common extrusion defects.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240095
EISBN: 978-1-62708-251-8
... and thicken. The change in interface morphology of a succinonitrile-4% acetone solution with increasing solidification velocity is shown in Fig. 7.4 which demonstrates the evolution of a dendritic structure. Fig. 7.3 Dendrite formation and dendritic microstructure in a Cu-10at.%Co alloy. Source Ref...
Abstract
Almost all metals and alloys are produced from liquids by solidification. For both castings and wrought products, the solidification process has a major influence on both the microstructure and mechanical properties of the final product. This chapter discusses the three zones that a metal cast into a mold can have: a chill zone, a zone containing columnar grains, and a center-equiaxed grain zone. Since the way in which alloys partition on freezing, it follows that all castings are segregated to different categories. The different types of segregation discussed include normal, gravity, micro, and inverse. The chapter also provides information on grain refinement and secondary dendrite arm spacing and porosity and shrinkage in castings. It concludes with a brief overview of six of the most important casting processes in industries: sand casting, plaster mold casting, evaporative pattern casting, investment casting, permanent mold casting, and die casting.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 November 2013
DOI: 10.31399/asm.tb.mfub.t53740047
EISBN: 978-1-62708-308-9
... with specially bonded core sand and compacted much like the mold itself. Cores are placed in the drag, or bottom section, of the mold, and the mold is then closed by placing the cope, or top section, over the drag. Mold closing completes the production of the mold, into which the molten metal is then poured...
Abstract
This chapter covers the practices and procedures used for shape casting metals and alloys. It begins with a review of the factors that influence solidification and contribute to the formation of casting defects. It then describes basic melting methods, including induction, cupola, crucible, and vacuum melting, and common casting techniques such as sand casting, plaster and shell casting, evaporative pattern casting, investment casting, permanent mold casting, cold and hot chamber die casting, squeeze casting, semisolid metal processing, and centrifugal casting.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 January 2022
DOI: 10.31399/asm.tb.isceg.t59320063
EISBN: 978-1-62708-332-4
... a tendency to dislocate due to the upward lifting force of buoyancy of the liquid metal. This results in nonuniform wall thickness and, in extreme cases, nonfills. One solution is to use chaplets to support the core in both the drag and the cope. A second alternative is to modify the core print to balance...
Abstract
The casting engineer contributes to a successful component design by offering expertise in molding, core making, and material characteristics and by recommending the most suitable casting process to use to meet quality and cost targets. The casting engineer's responsibilities include recommending locator positioning; advising about lugs, hooks, or holes for casting handling through all processes; determining the choice of a parting plane and pouring orientation; designing cores for accurate positioning, suitable venting, and proper cleaning; guiding decisions about wall thicknesses and junctions; making suggestions about casting design to eliminate distortion; optimizing the gating design for slag-free metal; and establishing the feeding techniques to eliminate shrink porosity. This chapter provides the guidelines for these responsibilities. In addition, the guidelines for the use of chaplets and chills in cast iron castings; guidelines for drafts, machine stock, tolerances, and contraction or shrink rule; and guidelines for pattern layouts and nesting are also covered.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320259
EISBN: 978-1-62708-357-7
... hand, Mo segregates at pearlite/γ interface, and it makes interface transport slower by the solute drag effect (see Section 5.5.2 ). Appendix: Carburized Pearlite Pearlite was discovered by a founder of steel metallography, H.C. Sorby (1863), and it is a monumental eutectoid structure named...
Abstract
This chapter provides a classification of the types of microstructural changes and transformations and then reviews each type. It presents the Johnson-Mehl-Avrami-Kolmogorov (JMAK) equation and explains the thermodynamics of eutectic solidification and eutectoid transformation. An appendix covers growth of eutectoid structure in carburized pearlite.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 31 December 2020
DOI: 10.31399/asm.tb.phtbp.t59310001
EISBN: 978-1-62708-326-3
... solution. It also explains the aspects of a phase diagram that shows what phase or phases are present in the alloy under conditions of thermal equilibrium. Finally, a discussion on the applications of equilibrium phase diagrams is presented. atomic bonding body-centered cubic equilibrium phase...
Abstract
The building block of all matter, including metals, is the atom. This chapter initially provides information on atomic bonding and the crystal structure of metals and alloys, followed by a description of three crystal lattice structures of metals: face-centered cubic, hexagonal close-packed, and body-centered cubic. It then describes the four main divisions of crystal defects, namely point defects, line defects, planar defects, and volume defects. The chapter provides information on grain boundaries of metals, processes involved in atomic diffusion, and key properties of a solid solution. It also explains the aspects of a phase diagram that shows what phase or phases are present in the alloy under conditions of thermal equilibrium. Finally, a discussion on the applications of equilibrium phase diagrams is presented.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 November 2012
DOI: 10.31399/asm.tb.ffub.t53610461
EISBN: 978-1-62708-303-4
... in individual circumstances: Increase surface hardness. This is a rather obvious solution to abrasive wear problems; however, it may not always be the answer to a specific problem. In cutting tools, such as various types of knives, blades, and the like, increasing the hardness may indeed make...
Abstract
This chapter discusses the causes and effects of wear along with prevention methods. It covers abrasive, erosive, erosion-corrosion, grinding, gouging, adhesive, and fretting wear. It also discusses various forms of contact-stress fatigue, including subsurface-origin fatigue, surface-origin fatigue, subcase-origin fatigue (spalling fatigue), and cavitation fatigue.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 March 2012
DOI: 10.31399/asm.tb.pdub.t53420303
EISBN: 978-1-62708-310-2
... by the shear displacement of iron atoms into an interstitial, supersaturated solid solution of iron and carbon. This metastable state has bct structure, which is even less densely packed than austenite. This results in lattice distortion that provides strength/hardness by impeding dislocation movements...
Abstract
This chapter examines two important strengthening mechanisms, martensitic and bainitic transformations, both of which occur under nonequilibrium cooling conditions. It explains how time-temperature-transformation diagrams are constructed and how they are used to understand and control the formation of martensite and bainite in steel and other alloys. It describes the morphology of both types of structures, the factors that influence their formation, how they respond to tempering processes, and their effect on mechanical properties and behaviors. It also discusses the role of transformation hysteresis in shape memory alloys.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 April 2013
DOI: 10.31399/asm.tb.imub.t53720161
EISBN: 978-1-62708-305-8
... added to epoxy mounts for edge retention, but this addition is really not a satisfactory solution. Taper Sectioning Taper sectioning (mounting) generally is regarded as a special mounting technique. It enables the metallographer to examine in greater detail the immediate subsurface structure...
Abstract
This chapter describes the methods and equipment applicable to metallographic studies and discusses the preparation of specimens for examination by light optical microscopy. Five major operations for preparation of metallographic specimens are discussed: sectioning, mounting, grinding, polishing, and etching. The discussion covers their basic principles, advantages, types, and applications, as well as the equipment setup. The chapter includes tables that list etchants used for microscopic examination. It also provides information on microscopic examination, microphotography, and the effects of grain size on the structural properties of the material.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 1984
DOI: 10.31399/asm.tb.mpp.t67850001
EISBN: 978-1-62708-260-0
... and efficiently. Thus, macroetching is an extremely powerful tool and is a cornerstore of the overall quality program. The earliest macroetchants were rather weak solutions used at room temperature. Reaumur (1683-1757) used macroetchants to distinguish between different types of steel and sketched...
Abstract
This chapter describes several macroscopic examination techniques, including macroetching, contact printing, fracturing, and lead exudation. It explains how each method is implemented, why it is used, and what it reveals about manufacturing processes, defects, imperfections, and failure mechanisms.