This chapter discusses some of the methods and measurements used to construct phase diagrams. It explains how cooling curves were widely used to determine phase boundaries, and how equilibrated alloys examined under controlled heating and cooling provide information for constructing isothermal and vertical sections as well as liquid projections. It also explains how diffusion couples provide a window into local equilibria and identifies typical phase diagram construction errors along with problems stemming from phase-boundary curvatures and congruent transformations.

This chapter discusses the selection, use, and integration of methods to control process variables in induction heating, including control of workpiece and processing temperature and materials handling systems. The discussion of temperature control includes a review of proportional controllers and heat-regulating devices. Integration of control functions is illustrated with examples related to heating of steel slabs, surface hardening of steel parts, vacuum induction melting for casting operations, and process optimization for electric-demand control. Distributed control within larger manufacturing systems is discussed. The chapter also covers nondestructive techniques for process control and methods for process simulation.

Besides the induction coil and workpiece, the induction generator (source of ac power) is probably the most important component of an overall induction heating system. Such equipment is typically rated in terms of its frequency and maximum output power (in kilowatts). This chapter addresses the selection of power supplies in terms of these two factors as well as the operational features of different types of sources. The six different types of power supplies for induction heating applications covered in this chapter are line-frequency supplies, frequency multipliers, motor-generators, solid-state (static) inverters, spark-gap converters, and radio-frequency power supplies. The chapter discusses the design and characteristics of each of the various types of power supplies.

This appendix provides a brief introduction to Thermo-Calc, explains what it is, and lists its uses. Instructions for accessing a demonstration version of the software are also provided.

This chapter discusses the engineering significance of steel and briefly describes its chemical composition, crystal structure, Fe-C phases, and associated characterization techniques.

This chapter is a detailed account of various factors pertinent to the development and launch of a product. It begins by describing the five phases in the product launch process, namely product design and development, process design and development, product and process validation, product launch, and continuous improvement. This is followed by sections covering product-process flow diagrams and also the process elements considered for process failure mode and effects analysis. Some of the aspects covered by the engineering specifications to meet the product performance requirements are then reviewed. Details on product validation requirements and definitions of parameters related to the launch process are also provided. The chapter discusses the purpose of manufacturing control plan, along with an illustration of a manufacturing control plan outlined for a safety-critical suspension casting. It ends with an overview of the contents of a program launch manual.

This chapter provides a brief overview of phase diagrams, explaining what they represent and how and why they are used. It identifies key points, lines, and features on a binary nickel-copper phase diagram and explains what they mean from a practical perspective. It also discusses the concept of equilibrium, the significance of Gibb’s phase rule, the theorem of Le Chatelier, and the use of the lever rule.

This chapter provides an overview of the physical metallurgy of beryllium, discussing phases and phase transformations, physical and mechanical properties, heat treatment, and alloying. It explains how the atomic structure of beryllium, particularly its sp hybrid state, contributes to the anisotropy of elastic constants and slip properties, resulting in a specific stiffness, or modulus-to-density ratio, six times higher than that of any other structural material.

This chapter discusses the design and operation of hydraulic presses. It begins by describing the role of each major component in a hydraulic system. It then explains the difference between pump-driven and accumulator-driven presses and the types of applications for which are suited. The chapter goes on to describe the load, energy, and time-dependent characteristics of hydraulic presses and the factors that determine accuracy. It also explains how hydraulic presses are used for deep drawing, fine blanking, and hydroforming as well as warm forming and hot stamping operations.

This chapter discusses the unique characteristics of isomorphous alloy systems. It begins with a review of the naming conventions for multi-component systems and the construction of a three-dimensional phase diagram for a two-component alloy system. It explains how phase diagrams can be constructed from time-temperature cooling curves and how they can be used to predict the phases present, their chemical compositions, and relative amounts. It also shows how phase diagrams can be modified to account for nonequilibrium cooling conditions.

The temperature and atmosphere conditions must be precisely controlled in order to achieve the desired metallurgical results during heat treating operations. In order to ensure the repeatability of operation, a heat treating system must have the necessary sensors, timers, and variable (temperature, atmosphere, etc.) controllers to hold the process within prescribed or specified limits. This chapter discusses temperature and atmosphere sensors used in a heat treating system. The temperature sensors covered are contact and noncontact types. The atmosphere sensors covered are oxygen probe, dew point, and infrared. The chapter concludes with an overview of the development of integrated control systems.

Process gas control for plasma (ion) nitriding is a matter of estimating the flows necessary to accomplish the required surface metallurgy. This chapter reviews several studies aimed at better understanding process gas control in plasma nitriding and its influence on compound zone formation. Emphasis is placed on the effect of sputtering on the kinetics of compound zone formation. The discussion covers the processes involved in process gas control analysis by photo spectrometry and mass spectrometry and the difficulties associated with gas analysis.

The first step in the hardening of steel is getting it hot enough to form austenite, from which martensite can form upon quenching. Not all steels have the same austenitization requirements, however. High-carbon wear-resistant steels, such as bearing and tool steels, require the presence of carbides during austenitization; plain carbon and low-alloy steels do not. This chapter describes the austenitization process used in each of the two cases, namely single-phase austenitization (the accepted method for plain carbon low-alloy steels) and two-phase austenitization (required for high-carbon steels). It also addresses process-specific issues, explaining how the presence of carbides (in the two-phase process) produces significant changes, and how homogenization and austenite grain growth influence the single-phase process.

This chapter discusses the use of phase diagrams in alloy design, processing, and performance assessment. The examples cover both ferrous and nonferrous metals and a variety of goals and objectives. The chapter also identifies limitations and pitfalls associated with the use of phase diagrams.

This chapter begins by presenting a generic eutectic phase diagram and identifying critical points, lines, and features. It then describes the composition and properties of aluminum-silicon and lead-tin eutectic systems, the characteristics of eutectic morphologies, the solidification and scale of eutectic structures, and the competitive growth of dendrites and eutectic colonies or cells. It also examines the different types of precipitation structures that form during slow cooling cycles.

This chapter provides a short introduction to phase transformations, namely, the liquid-to-solid phase transformations that occur during solidification and the solid-to-solid transformations that are important in processing, such as heat treatment. It also introduces the concept of free energy that governs whether or not a phase transformation is possible, and then the kinetic considerations that determine the rate at which transformations take place. The chapter also describes important solid-state transformations such as spinodal decomposition and martensitic transformation.

This chapter describes the various phases that form in tool steels, starting from the base of the Fe-C system to the effects of the major alloying elements. The emphasis is on the phases themselves: their chemical compositions, crystal structures, and properties. The chapter also provides general considerations of phases and phase diagrams and the determination of equilibrium phase diagrams. It describes the formation of martensite, characteristics of alloy carbides, and the design of tool steels.

The microstructure of superalloys is highly complex, with a large number of dispersed intermetallics and other phases that modify alloy behavior through their composition, morphology, and distribution. This chapter provides an overview of the most notable phases, including the matrix phase and geometrically and topologically close-packed phases, and describes how superalloy microstructure can be modified via heat treatments and directional solidification. It also discusses the role of carbides, borides, oxides, and nitrides and the detrimental effects of sulfocarbides.

This article focuses on characterization techniques used for analyzing the physical behavior and chemical composition of thermoset resins, namely chromatography and infrared spectroscopy. The main purpose is to give sufficient detail to permit the reader understand a particular test technique and its value to the thermoset resin field. Epoxy resins are emphasized in the examples because they dominate the airframe and aerospace industries. The article also provides information on two categories of characterization of the processing behavior of thermoset. The first studies the thermal properties of reactive thermoset systems, while the second utilizes these thermal characteristics as the basis for monitoring and control during processing.