This appendix lists the designations, commercial sources, and suppliers of different types of fibers and resins.

This article focuses on characterization techniques used for analyzing the physical behavior and chemical composition of thermoset resins, namely chromatography and infrared spectroscopy. The main purpose is to give sufficient detail to permit the reader understand a particular test technique and its value to the thermoset resin field. Epoxy resins are emphasized in the examples because they dominate the airframe and aerospace industries. The article also provides information on two categories of characterization of the processing behavior of thermoset. The first studies the thermal properties of reactive thermoset systems, while the second utilizes these thermal characteristics as the basis for monitoring and control during processing.

This article addresses some established protocols in characterizing thermoplastics, whether they are homogeneous resins, alloyed or blended compositions, or highly modified thermoplastic composites. It begins with a description of various approaches used for the determination of molecular weight (MW) by viscosity measurements. This is followed by a discussion of the use of cone and plate and parallel plate geometries in determining the viscoelastic properties of a polymer melt. Details on some of the chromatographic techniques that allow determination of MW and MW distribution of polymers are then provided. The article concludes with information on three distinctive, but complementary operations of thermoanalytical techniques, namely differential scanning calorimetry, thermogravimetric analysis, and thermomechanical testing.

This chapter discusses the use of thermoset and thermoplastic resins in polymer matrix composites. It begins by explaining how the two classes of polymer differ and how it impacts their use as matrix materials. It then goes on to describe the characteristics of polyester, vinyl ester, epoxy, bismaleimide, cyanate ester, polyimide, and phenolic resins and various toughening methods. The chapter also covers thermoplastic matrix materials and product forms and provides an introduction to the physiochemical tests used to characterize resins and cured laminates.

Polymer-matrix composites are among the lightest structural materials in use today. They are also highly resistant to corrosion and fatigue and their load-carrying capabilities, such as strength and stiffness, can be tailored for specific applications. This chapter discusses the primary advantages and disadvantages of polymer-matrix composites, how they are produced, and how they perform in different applications. It describes the construction of laminates, the fibers and resins used, and the methods by which they are combined. It explains how strength, modulus, toughness, and high-temperature and corrosion behaviors are determined by the orientation, shape, and spacing of fibers, the number of plies, resin properties, and consolidation and forming methods. The chapter also covers secondary fabrication processes, such as thermoforming, machining, and joining, as well as production equipment and product forms, and include guidelines for optimizing tradeoffs when selecting fibers, resins, and production techniques.

This chapter familiarizes readers with the many and varied thermoset composite fabrication processes and the types of applications for which they were developed. It describes wet lay-up, prepreg lay-up, and low-temperature vacuum bag curing prepreg processes, which are best suited for low-volume, medium-sized and larger parts. It also discusses filament winding and preforming processes (including weaving, knitting, stitching, and braiding) in addition to resin-transfer molding, resin film infusion, and pultrusion.

Electromagnetic induction, or simply "induction," is a method of heating electrically conductive materials such as metals. It is commonly used for heating workpieces prior to metalworking and in heat treating, welding, and melting. This technique also lends itself to various other applications involving packaging and curing of resins and coatings. This chapter provides a brief review of the history of induction heating and discusses its applications and advantages.

This chapter describes the molecular structures and chemical reactions associated with the production of thermoset and thermoplastic components. It compares and contrasts the mechanical properties of engineering plastics with those of metals, and explains how fillers and reinforcements affect impact and tensile strength, shrinkage, thermal expansion, and thermal conductivity. It examines the relationship between tensile modulus and temperature, provides thermal property data for selected plastics, and discusses the effect of chemical exposure, operating temperature, and residual stress. The chapter also includes a section on the uses of thermoplastic and thermosetting resins and provides information on fabrication processes and fastening and joining methods.

This chapter describes secondary processes employed in the production of powder-metal stainless steel parts, including various machining operations, welding, brazing, sinter bonding, resin impregnation, re-pressing and sizing, and surface finishing. It also discusses the factors that affect the machinability and weldability of sintered stainless steels.

The objective of mechanical testing of an engineered material is to provide data necessary for the analysis, design, and fabrication of structural components using the material. The testing of filament-wound composite materials offers unique challenges because of the special characteristics of composites. This chapter describes suitable static mechanical test techniques for characterizing laminated composite materials. The approach is to provide recommended techniques, based on consensus opinions of fabricators and users of filament-wound composites, and to survey available techniques that have been used successfully in the field. The chapter describes the effects of various factors on the properties of composite constituents, including fibers, resins, and unidirectional plies. Some aspects of specimen selection are also described. The chapter provides information on pressure bottles and tubular parts that have been developed as standard test specimens for combined load testing of composites.

The tail rotor blade of a helicopter developed a visible crack during service. The cracked region was removed from the blade and the fracture surface was examined in a SEM, revealing shallow pitting on the inside surface of the skin and a corresponding reduction in thickness. Based on these findings, investigators concluded that the failure was due to a fatigue crack initiated from a corrosion pit, which may have been caused by chemicals released by the burning of bonding resin.

This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, and/or conformation of the base polymers. The thermal analysis techniques covered are differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. The basic thermal properties covered include thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass-transition temperatures. The article further describes various factors influencing the determination of service temperature of a material. Representative examples of different types of engineering thermoplastics are discussed in terms of structure and thermal properties. The article also discusses the thermal and related properties of thermoset resin systems.

This article describes the mechanisms of moisture-induced damage in polymeric materials, covering the characteristics of important structural plastics; the effects of moisture on glass transition temperature, modulus, creep, and stress relaxation of plastic materials; and moisture-induced fatigue failure in composites. The effect of moisture on the mechanical properties of thermoset resins and thermoplastics are also discussed.

This chapter provides an overview of the tools and techniques, as well as some of the underlying theory, that have proven useful for process modeling and simulation. It begins by presenting the framework of a thermoset cure model that accounts for kinetics, viscosity, heat transfer, flow, voids, and residual stress. It then discusses each variable in detail, explaining how it affects the cure process, how it is measured, and how it can be expressed mathematically in the form of a simple model. The discussions throughout the chapter are supported by numerous images, diagrams, and data plots.

This article reviews various analytical techniques most commonly used in plastic component failure analysis. The description of the techniques is intended to make the reader familiar with the general principles and benefits of the methodologies. The descriptions of the analytical techniques are supplemented by a series of case studies that include pertinent visual examination results and the corresponding images that aided in the characterization of the failures. The techniques covered include Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and dynamic mechanical analysis. The article also discusses various analytical methods used to characterize the molecular weight distribution of a polymeric material. It provides information on a wide range of mechanical tests that are available to evaluate plastics and polymers, covering the various considerations in the selection and use of test methods.

This chapter instructs the metallographer on the basic skills required to prepare a polished metallographic specimen. It is organized in a chronological sequence starting with the information-gathering process on the material being investigated, then moving on to sectioning, mounting, grinding, and polishing processes, and ending with methods used to properly store metallographic specimens. The discussion covers the preparation procedures, the materials being investigated, and equipment used to perform these procedures.

This chapter addresses the hardware requirements for filament winding, from elementary processing equipment to more advanced systems. The chapter describes the equipment, defines how it is best used, and presents real-life examples. It describes a helical horizontal filament winding machine system and a vertical winding machine. The chapter provides information on in-plane (polar) winders and several types of creels, namely stationary and no twist, rotating, braking, and combinations thereof. Comprehensive descriptions of mandrel designs used in filament winding are presented in text and illustration. The chapter also reviews process control of filament winding parameters, including for some specialized winding processes and unique component types.

This chapter discusses design and certification considerations, including materials and process selection, the building block approach to certification, design allowables, and design guidelines. It also includes information on damage tolerance and environmental sensitivity.

This chapter reviews the development of filament winding systems and the automated processes used in state-of-the-art filament winding facilities. It first provides a description on the early stages of modern filament winding, followed by brief information on the advances of filament winding in the computer age. Then, the chapter discusses the requirements for filament winding in manufacturing oil and gas industry components and in high-volume production of sporting goods, propane tanks, and curing ovens. The chapter concludes with examples of the versatility of filament winding in producing complex parts.