This article presents a general overview of outdoor weather aging factors, their effects on plastic materials, and the accelerated test methods that can be used to estimate the reaction of a plastic component during actual use. Weather and radiation factors that contribute to degradation in plastics include temperature variations, moisture, sunlight, oxidation, microbiologic attack, and other environmental elements. The article also describes the tests used to predict the behavior of a plastic material to outdoor exposure, discussing the use of xenon arc lamp for the weatherometer and fadeometer and the use of fluorescent sunlamp in test devices.

Irradiation-assisted stress-corrosion cracking (IASCC) has been a topic of engineering interest since it was first reported in the 1960s, having been observed in stainless steel cladding on light water reactor fuel elements. This chapter summarizes the results of decades of investigation, showing that IASCC can essentially be defined as the intergranular cracking of austenitic alloys in high-temperature water, where both the material and its environment have been altered by radiation. Of the many interactions that can occur when metals and water are exposed to radiation, the international consensus is that the three with the greatest impact on crack growth rates are the formation of material defects, radiation-induced segregation, and chemical reactions that increase the corrosion potential of water. The chapter discusses each of these in great detail, and includes information on predictive modeling as well.

This article describes the weldability tests that are used to evaluate the effects of welding on such properties and characteristics as base-metal and weld-metal cracking; base-metal and weld-metal ductility; weld penetration; and weld pool shape and fluid flow. It also describes several weldability tests for evaluating cracking susceptibility, classified as self-restraint or externally loaded tests. The article discusses the processes, advantages, and disadvantages of the weld pool shape tests, the weld penetration tests, and the Gleeble test.

This article discusses the chemical susceptibility of a polymeric material. The discussion covers significant absorption and transportation of an environmental reagent by the polymer; the chemical susceptibility of additives; and thermal degradation, thermal oxidative degradation, photo-oxidative degradation, environmental corrosion, and chemical corrosion of polymers. It also includes some of the techniques used to detect changes in structure during polymer exposure to hostile environments. In addition, the article describes the effects of environment on polymer performance, namely plasticization, solvation, swelling, environmental stress cracking, polymer degradation, surface embrittlement, and temperature effects.

Polymer composite materials are subject to degradation if not appropriately protected from the environment. Composite materials having polymeric matrices are susceptible to degradation from heat, sunlight, ozone, atomic oxygen (in space), moisture, solvents (chemicals), fatigue, excessive loading, and combinations of these environmental conditions. This chapter discusses the effects of heat, ultraviolet-light, and atomic oxygen on composite materials.

This chapter takes a practical approach to the problem of stress-corrosion cracking (SCC) in stainless steels, explaining how different application environments affect different grades of stainless steel. It describes the causes of stress-corrosion cracking in chloride, caustic, polythionic acid, and high-temperature environments and the correlating effects on austenitic, ferritic, duplex, martensitic, and precipitation hardening stainless steels and nickel-base alloys. It also discusses the contributing effects of sensitization and hydrogen embrittlement and the role of composition, microstructure, and thermal history. Sensitization is particularly detrimental to austenitic stainless steels, and in many cases, eliminating it will eliminate the susceptibility to SCC. The chapter includes an extensive amount of data and illustrations.

This chapter describes the conditions under which environmental degradation is likely to occur in polymer matrix composites and the potential damage it can cause. It discusses the problems associated with moisture absorption and exposure to solvents, fuels, ultraviolet radiation, lightning strikes, thermal oxidation, and extreme temperatures. It also discusses the factors that influence flammability.

This chapter provides a view of magnetism in materials used at low temperatures. The discussion covers the concepts, definitions, and systems of units that are unique to the study of magnetic properties. The chapter provides a description of some of the techniques and devices used for determining magnetic properties.

This chapter discusses the techniques applicable to the diagnosis of corrosion failures, including visual and microscopic examination of corroded surfaces and microstructure; chemical analysis of the metal, corrosion products, and bulk environment; nondestructive evaluation methods; corrosion testing techniques; and mechanical testing techniques. A guide to investigative techniques used in corrosion failure analysis is provided in a table, describing the advantages and limitations of each technique. The principal stages of the investigation and analysis of corrosion failures discussed in the chapter are: collection of background information and sampling; preliminary laboratory examination; detailed metallographic and fractographic examinations; chemical analysis of corrosion products and bulk materials; corrosion testing for quality control; mechanical testing for quality control; and analysis of results and report writing.

A brittle fracture occurs at stresses below the material's yield strength (i.e., in the elastic range of the stress-strain diagram). This chapter focuses on brittle fracture in metals and, more specifically, ferrous alloys. It lists the factors that must all be present simultaneously in order to cause brittle fracture in a normally ductile steel. The chapter then discusses the macroscale characteristics and microstructural aspects of brittle fracture. A summary of the types of embrittlement experienced by ferrous alloys is presented. The chapter concludes with a brief section providing information on mixed fracture morphology.

The physical properties of a material are those properties that can be measured or characterized without the application of force and without changing material identity. This chapter discusses in detail the common physical properties of metals, namely density, electrical properties, thermal properties, magnetic properties, and optical properties. Some physical properties for a number of metals are given in a table.

This chapter first covers some basic principles of electrochemical corrosion and then some of the various types of corrosion. Some of the more common types of corrosion discussed include uniform corrosion, galvanic corrosion, pitting, crevice corrosion, erosion-corrosion, cavitation, fretting corrosion, intergranular corrosion, exfoliation, dealloying corrosion, stress-corrosion cracking, and corrosion fatigue. The chapter discusses the processes involved in corrosion control by retarding either the anodic or cathodic reactions. The rate of corrosion is reduced by conditioning of the metal, by conditioning the environment, and by electrochemical control. Finally, the chapter deals with high-temperature oxidation that usually occurs in the absence of moisture.

This chapter concentrates almost exclusively on inspection techniques related to pressure vessels and pipework. The discussion covers the general aspects associated with inspection and the key factors relevant to it. In addition, the chapter addresses processes involved in data collection and management, namely data acquisition, reporting, trending, reviewing, and auditing. Capabilities and limitations of in-service inspection techniques are discussed in the Appendix to this chapter.

This chapter discusses the processes involved in the heat treatment of steel, namely austenitizing, hardening, quenching, and tempering. It begins with an overview of austenitizing of steels by induction heating, followed by a discussion on the processes involved in transformation of the soft austenite into martensite or lower bainite in the hardening operation. The chapter provides information on various quenching systems and a description of quenching techniques, namely austempering, martempering, and patenting. Difficulties associated with hardening of steel are discussed. Further, the chapter describes the equipment used for and principal variables of tempering. It discusses the causes for various forms of embrittlement due to tempering. Information on multiple tempering, protective-atmosphere tempering, and selective tempering are also provided, along with processes involved in selection of tempering temperature. The chapter ends with a section discussing various effects, advantages, and disadvantages of precipitation hardening.

This chapter discusses the compositions, properties, and applications of nonferrous metals, including zirconium, hafnium, beryllium, lead, tin, gold, silver, and platinum group metals. It also addresses fusible alloys and provides melting temperatures for several compositions.

This chapter reviews weld corrosion in three key application areas: petroleum refining and petrochemical operations, boiling water reactor piping systems, and components used in pulp and paper plants. The discussion of each area addresses general design and service characteristics, types of weld corrosion issues, and prevention or mitigation strategies.

This article reviews fatigue test methodologies, provides an overview of general fatigue behavior (crack initiation and propagation) in engineering plastics, and discusses some of the factors affecting the fatigue performance of polymers. In addition, it provides information on fractography that provides useful insight into the nature of fracture processes.

This chapter discusses common forms of corrosion, including uniform corrosion, galvanic corrosion, pitting, crevice corrosion, dealloying corrosion, intergranular corrosion, and exfoliation. It describes the factors that contribute to stress-corrosion cracking, hydrogen embrittlement, and corrosion fatigue and compares and contrasts their effects on mechanical properties, performance, and operating life. It also includes information on high-temperature oxidation and corrosion prevention techniques.

This chapter discusses the basic principles of corrosion, explaining how and why it occurs and how it is categorized and dealt with based on the appearance of corrosion damage or the mechanism of attack. It explains where different forms of corrosion are likely to occur and identifies metals likely to be affected. It also discusses the selection and use of protective coatings and the tests that have been developed to measure their effectiveness.

This chapter, a detailed account of furnaces and related equipment for heat treating, begins by describing three basic modes of heat transmission, namely conduction, convection, and radiation, followed by a discussion on the working principle, applications, advantages, and disadvantages of furnaces classified based on the heat transfer medium employed. The types of furnaces covered are batch-type, continuous-type, liquid bath, fluidized bed, and vacuum. The subsequent sections provide information on furnace parts, fixtures, quenching mediums, and quenching systems. The final section of the chapter describes the types of atmospheres available, emphasizing their applications and limitations.