Stainless steel powders are usually made by water or gas atomization. This chapter describes both processes and the properties and characteristics of the powders they produce. It also discusses secondary processes, including drying, screening, annealing, and lubricating, and the effects of iron contamination on corrosion resistance.

This chapter covers the basic steps of the powder metallurgy process, including powder manufacture, powder blending, compacting, and sintering. It identifies important powder characteristics such as particle size, size distribution, particle shape, and purity. It compares and contrasts mechanical, chemical, electrochemical, and atomizing processes used in powder production, discusses powder treatments, and describes consolidation techniques along with secondary operations used to obtain special properties or improve dimensional precision. It also discusses common defects such as ejection cracks, density variations, and microlaminations.

This chapter provides a qualitative overview of powder preparation technologies including milling, mechanical alloying, electrolytic dissolution, metal oxide reduction, solid-state reactive synthesis, and gas, water, and centrifugal atomization. It discusses the general implementation of each process, the materials for which they are used, and the powder characteristics that can be achieved.

This chapter discusses the methods by which stainless steel powders are shaped and compacted prior to sintering, including rigid die compaction, metal injection molding, extrusion, and hot isostatic pressing. It explains where each process is used and how processing parameters, such as temperature and pressure, and powder characteristics, such as particle size and shape, influence the quality of manufactured parts. It describes the various stages of metal powder compaction, the role of lubricants, and how to account for dimensional changes in the design of tooling and process sequences.

This chapter discusses the advantages of using powder metallurgy to produce magnetic materials, particularly its ability to control chemistry and near-net shape. It also explains how process parameters and powder characteristics influence the physical and magnetic properties of common stainless steels.

This chapter introduces the key powder fabrication attributes to assist in the identification of the right powders for an application. First, it describes the characteristics of engineering powders such as particle size distribution, powder shape and packing density, surface area, powder flow and rheology, and chemical analysis. The chapter then describes the general categories of powder fabrication methods, namely mechanical comminution, electrochemical precipitation, thermochemical reaction, and phase change and atomization. It provides information on the two largest contributors to powder price, namely raw material cost and conversion cost. The applicability of various processes to specific material systems is mentioned throughout this chapter.

Increasing growth of high-pressure cold spraying applications on the industrial scale have forced global powder producers to face this challenge and develop specific powders for cold spray applications. This chapter provides information on the properties, classification, characteristics, manufacturing, and procedures for packaging of powders specific to cold spray applications.

This chapter discusses the growing role of powder metallurgy in the production of intermetallic, Heusler, and high-entropy alloys. It reviews the challenges of producing these materials by conventional methods and the advantages of sinter-based PM techniques. It explains why PM processes are better suited for complex materials than casting and compares the properties of intermetallic, Heusler, and high-entropy alloys prepared by casting and powder-metal techniques.

This chapter provides details on powder-binder processing for three materials, namely precipitation-hardened 17-4 PH stainless steel, cemented carbides, and alumina. The types of powders, binders, feedstock, shaping processes, debinding, sintering cycles, compositions, microstructure, distortion, postsintering treatments, and mechanical properties are presented for each. The shaping options include powder-binder approaches such as binder jetting, injection molding, extrusion, slip and slurry casting, centrifugal casting, tape casting, and additive manufacturing. Sintering options are outlined with respect to attaining high final properties.

Binder removal approaches involve various combinations of heat, solvents, vacuum, and pressure. In each variant, the goal is binder removal without component damage. This chapter addresses the factors that control success, showing how process decisions depend on the powder and binder characteristics. The chapter starts with a comparison of binder-, lubricant-, and polymer-removal situations that arise after powder shaping and then describes the general principles of binder removal in powder-binder techniques. The subsequent sections discuss in detail characteristics, operating procedure, equipment setup, advantages, limitations, and applications of first- and second-stage binder removal processes, as well as the factors influencing these processes. Cost issues associated with binder-removal technologies are also discussed.

High-pressure cold spray repair process has been used on a number of different applications in the defense industry. This chapter describes various applications for cold spray systems that have operating pressures greater than 2.4 MPa (350 psi) and operating temperatures greater than 500 deg C (930 deg F).

This chapter recounts some of the early efforts and milestones in the development of stainless steel powders and their use in powder metallurgy applications.

This chapter elucidates the indispensable role of characterization in the development of cold-sprayed coatings and illustrates some of the common processes used during coatings development. Emphasis is placed on the advanced microstructural characterization techniques that are used in high-pressure cold spray coating characterization, including residual-stress characterization. The chapter includes some preliminary screening of tool hardness and bond adhesion strength, as well as a distinction between surface and bulk characterization techniques and their importance for cold spray coatings. The techniques covered are optical microscopy, X-Ray diffraction, scanning electron microscopy, focused ion beam machining, electron probe microanalysis, transmission electron microscopy, and electron backscattered diffraction. The techniques also include electron channeling contrast imaging, X-Ray photoelectron spectroscopy, X-ray fluorescence, Auger electron spectroscopy, Raman spectroscopy, oxygen analysis, and nanoindentation.

This chapter describes the most effective ways to improve the corrosion resistance of sintered stainless steels, including increasing alloy content, optimizing the sintering process, and the use of surface treatments and modifications.

This chapter explains the basic terminology and principles of metallurgy as they apply to extrusion. It begins with an overview of crystal structure in metals and alloys, including crystal defects and orientation. This is followed by sections discussing the development of the continuous cast microstructure of aluminum and copper alloys. The discussion provides information on billet and grain segregation and defects in continuous casting. The chapter then discusses the processes involved in the deformation of pure metals and alloys at room temperature. Next, it describes the characteristics of pure metals and alloys at higher temperatures. The processes involved in extrusion are then covered. The chapter provides details on how the toughness and fracture characteristics of metals and alloys affect the extrusion process. The weld seams in hollow profiles, the production of composite profiles, and the processing of composite materials, as well as the extrusion of metal powders, are discussed. The chapter ends with a discussion on the factors that define the extrudability of metallic materials and how these attributes are characterized.

This chapter provides information on the properties and behaviors of stainless steels and stainless steel powders. It begins with a review of alloy designation systems and grades by which stainless steels are defined. It then describes the composition, metallurgy, and engineering characteristics of austenitic, ferritic, martensitic, duplex, and precipitation hardening stainless steel powders and metal injection molding grades.

Titanium is a lightweight metal used in a growing number of applications for its strength, toughness, stiffness, corrosion resistance, biocompatibility, and high-temperature operating characteristics. This chapter discusses the applications, metallurgy, properties, compositions, and grades of commercially pure titanium and alpha and near-alpha, alpha-beta, and beta titanium alloys. It describes primary and secondary fabrication processes, including melting, forging, forming, heat treating, casting, machining, and joining as well as powder metallurgy and direct metal deposition. It also compares and contrasts the properties of wrought, cast, and powder metal titanium products and discusses corrosion behaviors.

This chapter covers various consolidation techniques used in powder metallurgy, including laser sintering (pressureless sintering), hot pressing, high-pressure torsion, microwave sintering, spark plasma sintering, and pulse plasma sintering. It also discusses the effect of milling parameters on mechanically alloyed powders, their consolidation characteristics, and the properties of bulk components.

This chapter discusses the growing use of sintered stainless steels in automotive applications and various types of filters and filtering media. It also describes how these materials are produced in the form of metal foams and cellular structures and how they serve as flake pigments in corrosion-resistant coatings.