This chapter is intended to identify materials, processes, and designs that will lead to great advances in powder-binder forming technologies. It discusses some of the structures obtained through these advances in powder-binder technologies such as binder jetting and extrusion-based additive manufacturing, including bound-metal deposition and fused-filament fabrication: oxidation-resistant high-temperature alloys, anisotropic structures, submicrometer-scale structures, surface hard materials, and artist metallic clays. Some of the advances discussed include the developments in process involving plastics, emulsions, ceramics, and porous structures and foams. Improvements in the design processes have led to the development of functional structures, controlled porosity, and bioinspired structures.

Fabricated powder metallurgy (P/M) parts are evaluated and tested at several stages during manufacturing for part acceptance and process control. The various types of tests included are dimensional evaluation, density measurements, hardness testing, mechanical testing, and nondestructive testing. This chapter is a detailed account of these testing methods. It describes the four most common types of defects in P/M parts, namely ejection cracks, density variations, microlaminations, and poor sintering. The chapter discusses the capabilities and limitations of various nondestructive evaluation methods to flaw detection in P/M parts. The nondestructive evaluation methods covered are mechanical proof testing, metallography, liquid penetrant crack detection, filtered particle crack detection, magnetic particle crack inspection, direct current resistivity testing, x-ray radiography, computed tomography, gamma-ray density determination, and ultrasonic techniques.

The conversion of feedstock into a shape involves the application of heat and pressure, and possibly solvents. This chapter discusses the operating principle, advantages, limitations, and applications of such shaping processes, namely additive manufacturing, cold isostatic pressing, die compaction, extrusion, injection molding, slip casting, slurry processes, and tape casting. Information on equipment setup, requirements, and the various factors influencing these processes are described. In addition, the chapter provides information on novel approaches and processing costs applicable to these shaping processes.

This chapter discusses the basic principles of corrosion, explaining how and why it occurs and how it is categorized and dealt with based on the appearance of corrosion damage or the mechanism of attack. It explains where different forms of corrosion are likely to occur and identifies metals likely to be affected. It also discusses the selection and use of protective coatings and the tests that have been developed to measure their effectiveness.

This chapter covers the basic steps of the powder metallurgy process, including powder manufacture, powder blending, compacting, and sintering. It identifies important powder characteristics such as particle size, size distribution, particle shape, and purity. It compares and contrasts mechanical, chemical, electrochemical, and atomizing processes used in powder production, discusses powder treatments, and describes consolidation techniques along with secondary operations used to obtain special properties or improve dimensional precision. It also discusses common defects such as ejection cracks, density variations, and microlaminations.

This chapter discusses common forms of corrosion, including uniform corrosion, galvanic corrosion, pitting, crevice corrosion, dealloying corrosion, intergranular corrosion, and exfoliation. It describes the factors that contribute to stress-corrosion cracking, hydrogen embrittlement, and corrosion fatigue and compares and contrasts their effects on mechanical properties, performance, and operating life. It also includes information on high-temperature oxidation and corrosion prevention techniques.

Corrosion problems can be divided into eight categories based on the appearance of the corrosion damage or the mechanism of attack: uniform or general corrosion; pitting corrosion; crevice corrosion, including corrosion under tubercles or deposits, filiform corrosion, and poultice corrosion; galvanic corrosion; erosion-corrosion, including cavitation erosion and fretting corrosion; intergranular corrosion, including sensitization and exfoliation; dealloying; environmentally assisted cracking, including stress-corrosion cracking, corrosion fatigue, and hydrogen damage (including hydrogen embrittlement, hydrogen-induced blistering, high-temperature hydrogen attack, and hydride formation). All these forms are addressed in this chapter in the context of aqueous corrosion. For each form, a general description is provided along with information on the causes and the list of metals that can be affected, with particular emphasis on the recognition and prevention measures.

This chapter introduces the key powder fabrication attributes to assist in the identification of the right powders for an application. First, it describes the characteristics of engineering powders such as particle size distribution, powder shape and packing density, surface area, powder flow and rheology, and chemical analysis. The chapter then describes the general categories of powder fabrication methods, namely mechanical comminution, electrochemical precipitation, thermochemical reaction, and phase change and atomization. It provides information on the two largest contributors to powder price, namely raw material cost and conversion cost. The applicability of various processes to specific material systems is mentioned throughout this chapter.

This chapter describes the processes involved in alloy production, including melting, casting, solidification, and fabrication. It discusses the effects of alloying on solidification, the formation of solidification structures, supercooling, nucleation, and grain growth. It describes the design and operation of melting furnaces as well as melting practices and the role of fluxing. It also discusses casting methods, nonferrous casting alloys, and atomization processes used to make metal powders.

All materials are susceptible to corrosion or some form of environmental degradation. Although no single material is suitable for all applications, usually there are a variety of materials that will perform satisfactorily in a given environment. The intent of this chapter is to review the corrosion behavior of the major classes of metals and alloys as well as some nonmetallic materials, describe typical corrosion applications, and present some unique weaknesses of various types of materials. It also aims to point out some unique material characteristics that may be important in material selection, and discuss, where appropriate, the characteristic forms of corrosion that attack specific materials. The materials addressed in this chapter include carbon steels, weathering steels, and alloy steels; nickel, copper, aluminum, titanium, lead, magnesium, tin, zirconium, tantalum, niobium, and cobalt and their alloys; polymers; and other nonmetallic materials, including rubber, carbon and graphite, and woods.

The machinery and equipment required for rod and tube extrusion is determined by the specific extrusion process. This chapter provides a detailed description of the design requirements and principles of machinery and equipment for direct and indirect hot extrusion. It then covers the presses and auxiliary equipment for tube extrusion, induction furnaces for billet processing, handling systems for copper and aluminum alloy products, extrusion cooling systems, and age-hardening ovens. Next, the chapter describes the principles and applications of equipment for the production of aluminum and copper billets. Then, it focuses on process control in both direct and indirect hot extrusion of aluminum alloys without lubrication. The chapter describes the technology of electrical and electronic controls in the extrusion process. It ends with a discussion on the factors that influence the productivity and quality of the products in the extrusion process and methods for process optimization.

Liquid penetrant, magnetic particle, and eddy current inspection are used to detect surface flaws. This chapter is a detailed account of the physical principles, process description, equipment requirements, selection criteria, advantages, limitations, and applications of these surface flaw detection techniques.

This chapter describes the processes involved in the fabrication of wrought and cast metal products. It discusses deformation processes including bending and forming, material removal processes such as milling, cutting, and grinding, and joining methods including welding, soldering, and brazing. It also discusses powder consolidation, rolling, drawing and extrusion, and common forging methods.

This chapter covers the practices and procedures used for shape casting metals and alloys. It begins with a review of the factors that influence solidification and contribute to the formation of casting defects. It then describes basic melting methods, including induction, cupola, crucible, and vacuum melting, and common casting techniques such as sand casting, plaster and shell casting, evaporative pattern casting, investment casting, permanent mold casting, cold and hot chamber die casting, squeeze casting, semisolid metal processing, and centrifugal casting.

This chapter explains how to prepare metallographic samples for light microscopy and how to anticipate and avoid related problems. It describes standard practices and procedures for sectioning, mounting, grinding, and polishing and identifies common defects along with their causes and cures. It also provides recommendations for handling specific materials and addresses safety concerns.