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Book Chapter
Cleaning and Finishing
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2000
DOI: 10.31399/asm.tb.ttg2.t61120085
EISBN: 978-1-62708-269-3
... to develop or to enhance specific properties, such as lubricity or wear resistance. In addition to coatings for lubricity, titanium is coated or plated with corrosion-resistant metals (e.g., copper and platinum) as an alternative to oxide formation or as the basis for subsequent plating. Coatings...
Abstract
Cleaning procedures serve to remove scale, tarnish films, and other contaminants that form or are otherwise deposited on the surface of titanium during processing operations such as hot working and heat treatment. This chapter explains what makes titanium susceptible to the formation of scale and how it can be removed via belt grinding, abrasive blasting, and molten salt descaling baths. It also discusses the role of acid pickling, barrel finishing, polishing, and buffing as well as the use of chemical conversion coatings and protective platings.
Book Chapter
Electroless and Electrolytic Plating Procedures
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 1984
DOI: 10.31399/asm.tb.mpp.t67850538
EISBN: 978-1-62708-260-0
... edge preparation schemes. A very wide range of materials have been coated in this way. For metals, the procedures [ 19 ] [1] used can be categorized as follows: Direct plating . Iron, cobalt, nickel, ruthenium, palladium, osmium, iridium, and platinum. Galvanic initiation . Copper, silver...
Abstract
This appendix lists plating solutions and procedures used in metallographic edge preparation.
Book Chapter
Noble Metal Alloys
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2001
DOI: 10.31399/asm.tb.aub.t61170550
EISBN: 978-1-62708-297-6
... and to a lesser extent, with palladium. It is also used as a plating on jewelry metals for whiteness and wear resistance. Rhodium is the whitest of the platinum-group metals. Iridium Iridium, in unalloyed form, is fabricated into large crucibles that are used in the production of single crystals of yttrium...
Abstract
This article discusses the compositions, properties, and uses of silver, gold, and platinum group metals, including platinum, rhodium, iridium, ruthenium, and osmium. It describes the role of various alloying elements and explains how they affect physical, mechanical, and electrical properties as well as corrosion resistance.
Book Chapter
Miscellaneous Nonferrous Metals
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240597
EISBN: 978-1-62708-251-8
... Abstract This chapter discusses the compositions, properties, and applications of nonferrous metals, including zirconium, hafnium, beryllium, lead, tin, gold, silver, and platinum group metals. It also addresses fusible alloys and provides melting temperatures for several compositions...
Abstract
This chapter discusses the compositions, properties, and applications of nonferrous metals, including zirconium, hafnium, beryllium, lead, tin, gold, silver, and platinum group metals. It also addresses fusible alloys and provides melting temperatures for several compositions.
Book Chapter
Transformation of Austenite
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 August 1999
DOI: 10.31399/asm.tb.lmcs.t66560221
EISBN: 978-1-62708-291-4
.... 6.6 , and may be recognized in a section by the regular array of the plates of ferrite and cementite ( Fig. 9.1 (Part 1) f and 9.2a , but see discussion of Fig. 9.11 ). Fig. 9.1 (Part 1) Pearlite formation (at 705 and 650 °C) in isothermal transformation of 0.8% C eutectoid steels. 0.81C...
Abstract
This chapter discusses the isothermal transformation of austenite to pearlite, bainite, martensite, proeutectoid ferrite, and proeutectoid cementite. It describes the transformation mechanisms in eutectoid, hypoeutectoid, and hypereutectoid steels, the factors that influence nucleation and growth, and the characteristic features of the various microstructures. It also describes the transformation of austenite during continuous cooling.
Book Chapter
Nonferrous Metals—A Variety of Possibilities
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 October 2011
DOI: 10.31399/asm.tb.mnm2.t53060315
EISBN: 978-1-62708-261-7
...-point metals (bismuth, indium, lead, tin, zinc) Reactive metals (hafnium, titanium, and zirconium) Precious metals (gold, silver, platinum, palladium, iridium, rhodium, ruthenium, and osmium) Rare earth metals Semimetals (also known as metalloids) As this list indicates, some...
Abstract
Nonferrous metals are of commercial interest both as engineering materials and as alloying agents. This chapter addresses both roles, discussing the properties, processing characteristics, and applications of several categories of nonferrous metals, including light metals, corrosion-resistance alloys, superalloys, refractory metals, low-melting-point metals, reactive metals, precious metals, rare earth metals, and metalloids or semimetals. It also provides a brief summary on special-purpose materials, including uranium, vanadium, magnetic alloys, and thermocouple materials.
Book Chapter
Tempering of Martensite
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 August 1999
DOI: 10.31399/asm.tb.lmcs.t66560283
EISBN: 978-1-62708-291-4
... within martensite plates (at transformation twins and at the midrib) and at plate interfaces. The platelets later agglomerate to form spheroidal particles that coarsen rapidly at high temperatures. Decomposition of Retained Austenite . Retained austenite decomposes to a mixture of ferrite...
Abstract
This chapter describes the effects that can be observed by light microscopy when a steel in the hardened condition, consisting of martensite and possibly some retained austenite, is heated at subcritical temperatures. It includes micrographs that illustrate the effect of carbide precipitation, the decomposition of retained austenite, and recovery and recrystallization. It also includes images that reveal the characteristic structures produced by tempering medium-carbon hypoeutectoid and hypereutectoid steels as well as the effects of plastic deformation, austenitic grain size, and temper brittleness.
Book Chapter
Corrosion
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 January 2015
DOI: 10.31399/asm.tb.tpmpa.t54480331
EISBN: 978-1-62708-318-8
... corrosion resistance is enhanced by alloying with palladium and by ion plating a thin coating of platinum. Titanium Grades The various titanium grades, as defined by ASTM International and the American Society of Mechanical Engineers, are numbered from 1 and upwards, where all numbers except 6 and 8...
Abstract
This chapter discusses the corrosion behavior of titanium, the types of corrosion that can occur, and the effect of alloying on corrosion resistance. It explains that, due to its tenacious oxide film, titanium has excellent corrosion resistance in oxidizing environments and that the resistance can be extended into the “reducing-acid” region by adding a small amount of palladium. It describes how different grades of titanium respond to different forms of attack, including uniform, crevice, and galvanic corrosion. It also identifies applications where corrosion is often a concern.
Book Chapter
Temperature, Strain, and Magnetic Field Measurements
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 June 1983
DOI: 10.31399/asm.tb.mlt.t62860515
EISBN: 978-1-62708-348-5
... construction of the device. Very little energy is required to increase the temperature of small specimens because heat capacity decreases with temperature; for example, the ratio of heat capacity at 300 K to that at 20 K is 18 for platinum, 50 for copper, and 76 for nickel. The Peltier heating or cooling...
Abstract
This chapter discusses three measurements parameters: temperature, strain, and magnetic field strength. It stresses the measurement of temperature because it is the primary variable in nearly all low-temperature material properties. The chapter contains information on methods and auxiliary materials. Areas of frequent concern, such as thermal contact, heat leak, thermal anchoring, thermal conductivity of greases, insulators, lead wires, ground loops, and feedthroughs are also reviewed. The chapter provides an overview and historical development of temperature scales because the practical use of all thermometers is associated with some approximation of the thermodynamic temperature scale. A short section is devoted to types of temperature measuring devices. The characteristics of commercially available resistance-type strain gauges at low temperatures are stressed.
Book Chapter
Anodic Protection
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2015
DOI: 10.31399/asm.tb.cpi2.t55030180
EISBN: 978-1-62708-282-2
... The cathode should be a permanent-type electrode that is not dissolved by the solution or the currents impressed between the vessel wall to be protected and the electrode. The cathodes used in most of the initial applications were made of platinum-clad brass ( Ref 1 , 3 – 6 ). These cathodes were excellent...
Abstract
Anodic protection is used on a smaller scale than other corrosion control techniques due to the fundamental electrochemistry involved. This chapter provides a brief history of the technique, discusses anodic protection use, and compares anodic and cathodic protection. The background and theory of anodic protection are summarized. In addition to briefly describing the various items used for each component of an anodic protection system, the chapter presents design concerns as well as applications of the system. Factors concerning the economic justification of anodic protection are also described.
Book Chapter
Corrosion Resistance
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2000
DOI: 10.31399/asm.tb.ttg2.t61120123
EISBN: 978-1-62708-269-3
.... Surface Treatment Precious metals, such as platinum and palladium, have been ion plated, ion implanted, or thermal diffused into titanium alloy surfaces to achieve improved resistance to reducing acids. This approach has not been used commercially for industrial components because of high cost...
Abstract
Titanium and its alloys are used chiefly for their high strength-to-weight ratio, but they also have excellent corrosion resistance, better even than stainless steels. Titanium, as the chapter explains, is protected by a tenacious oxide film that forms rapidly on exposed surfaces. The chapter discusses the factors that influence the growth and quality of this naturally passivating film, particularly the role of oxidizing and inhibiting species, temperature, and alloying elements. It also discusses the effect of different corrosion processes and environments as well as hydrogen, stress-corrosion cracking, liquid metal embrittlement, and surface treatments.
Book Chapter
Principles of Aqueous Corrosion
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 January 2000
DOI: 10.31399/asm.tb.cub.t66910049
EISBN: 978-1-62708-250-1
... results in ferrous ions combining with electrons to form new iron atoms at the metal surface. This is equivalent to a metal plating process. The reaction from right to left involves the removal of an iron atom from the metal surface with the formation of a new ferrous ion (Fe 2+ ) in solution. Two...
Abstract
This chapter discusses the principles of corrosion of metals in aqueous environments. The thermodynamics of aqueous corrosion is the subject of the first half of this chapter, which addresses concepts such as corrosion reactions and free-energy change, the relationship between free energy and electrochemical potential, the effect of ionic concentration on electrode potential, and the corrosion behavior of a metal based on its potential-pH diagram. The corrosion (potential-pH) behavior of iron, gold, copper, zinc, aluminum, and titanium are described. Understanding the kinetics of corrosion and the factors that control the rates of corrosion reactions requires examination of the concepts of polarization behavior and identification of the various forms of polarization in an electrochemical cell. These concepts, addressed in the remaining of this chapter, include anodic and cathodic reactions, the mixed-potential theory, and the exchange currents.
Book Chapter
Special Applications of Induction Heating
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 June 1988
DOI: 10.31399/asm.tb.eihdca.t65220281
EISBN: 978-1-62708-341-6
... and special glass components, the molten glass must be kept free of contaminants. For this reason, it is generally melted in a platinum crucible. It is also important that the glass be kept free of the products of combustion. Hence, the platinum crucible is induction heated. Because platinum has a low...
Abstract
Induction heating has found widespread use as a method to raise the temperature of a metal prior to forming or joining, or to change its metallurgical structure. However, induction heating has specialized capabilities that make it suitable for applications outside of metal treatment and fabrication. This chapter summarizes some of the special applications of induction heating, including those in the plastics, packaging, electronics, glass, chemical, and metal-finishing industries. The chapter concludes with a discussion of the application of induction heating for vacuum processes.
Book Chapter
Etching Methods
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 August 1999
DOI: 10.31399/asm.tb.lmcs.t66560453
EISBN: 978-1-62708-291-4
... Saturated solution of ammonium nitrate in water. Method of Use Etch electrolytically at approx. 0.1 A/cm 2 at 6 V for up to 3 min. Specimen anode. The cathode may be of platinum or stainless steel. Use Distinguishes between grain-boundary sulfide precipitation and grain-boundary liquation...
Abstract
This appendix provides information on the chemical composition, method of use, and applications of various etchants used in the metallography of carbon steels.
Book Chapter
Cathodic Protection
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2015
DOI: 10.31399/asm.tb.cpi2.t55030184
EISBN: 978-1-62708-282-2
... Table 5 Consumption rates of impressed-current anode materials Material Typical anode current density Consumption rate per A · yr A/m 2 A/ft 2 Pb-6Sb-1Ag 160–220 15–20 0.045–0.09 kg (0.1–0.2 lb) Platinum (plated on substrate) 540–1080 50–100 0.006 g (0.0002 oz) Platinum...
Abstract
This chapter provides a detailed account of cathodic protection. It begins by discussing the fundamentals of cathodic protection followed by a description of the various types of cathodic protection. It then describes the origins, types, and alleged failures of cathodic protection criteria. This is followed by a section providing information on anode materials that are used for cathodic protection applications. General guidelines for designing the cathodic protection systems are also listed. Finally, the chapter presents various examples on cathodic protection of steel structures. The examples are selected to familiarize the design engineer with the steps to follow in selecting a specific corrosion-control method.
Book Chapter
Surface Engineering to Add a Surface Layer or Coating
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 March 2001
DOI: 10.31399/asm.tb.secwr.t68350125
EISBN: 978-1-62708-315-7
... Abstract This chapter discusses the use of coating methods and materials and their impact on corrosion and wear behaviors. It provides detailed engineering information on a wide range of processes, including organic, ceramic, and hot dip coating, metal plating and cladding, and the use of weld...
Abstract
This chapter discusses the use of coating methods and materials and their impact on corrosion and wear behaviors. It provides detailed engineering information on a wide range of processes, including organic, ceramic, and hot dip coating, metal plating and cladding, and the use of weld overlays, thermal spraying, and various deposition technologies.
Book Chapter
Aqueous Corrosion Failures
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 30 November 2013
DOI: 10.31399/asm.tb.uhcf3.t53630211
EISBN: 978-1-62708-270-9
... and other salts dissolved in water. This sequence is called the galvanic series and is shown in Table 1 for many pure metals and select alloys. Galvanic series in seawater at 25 °C (77 °F) Table 1 Galvanic series in seawater at 25 °C (77 °F) Cathodic end (least easily corroded) Platinum...
Abstract
This chapter outlines the major types of corrosion, their interactions, their complicating effects on fracture and wear, and some possible prevention methods. The types of corrosion considered in the chapter are galvanic corrosion, uniform corrosion, pitting corrosion, crevice corrosion, microbiologically influenced corrosion, stress-corrosion cracking, and corrosion fatigue.
Book Chapter
The Role of Materials in Defining Process Constraints
Available to PurchaseBook: Principles of Soldering
Series: ASM Technical Books
Publisher: ASM International
Published: 01 April 2004
DOI: 10.31399/asm.tb.ps.t62440145
EISBN: 978-1-62708-352-2
... of the solder. In the semiconductor and optoelectronic industries, platinum overlaid with a gold flash is a frequent choice of wettable metallization. Thin-film deposition equipment with a platinum sputtering source is often readily available, and the materials cost is insignificant compared to the process...
Abstract
This chapter considers the materials and processing aspects of soldering and the manner in which these interrelate in the development of joining processes. It discusses the processes involved in eliminating or suppressing metallurgical and mechanical constraints as well as constraints imposed by the components.
Book Chapter
Etchants for Revealing Macrostructure
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 1984
DOI: 10.31399/asm.tb.mpp.t67850509
EISBN: 978-1-62708-260-0
.... Use electrolytically with polished surface. Platinum or stainless steel cathode, 60-100°F, 6 V dc, 1 A/in2, 2-7 min. Good for welds (Miller and Houston). Use electrolytically with polished sample. Use stainless steel cathode, 3 A/in2. Instantaneous contact made with specimen. Current density cut...
Abstract
This appendix provides a list of etch compositions and procedures that reveal the macrostructure of aluminum, beryllium, bismuth, antimony, cobalt, copper, lead, magnesium, nickel, tin, titanium, zinc, and their respective alloys as well as iron, steel, noble metals, refractory metals, silicon, zirconium, and hafnium.
Book
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2001
DOI: 10.31399/asm.tb.aub.9781627082976
EISBN: 978-1-62708-297-6
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