This chapter describes the phases and constituents present in iron-carbon steels in near-equilibrium conditions. It explains how to use phase diagrams to predict and manage the development of ferrite, austenite, cementite, and pearlite through controlled cooling. It discusses the transformations, grain structure, and properties associated with each phase and identifies the primary stabilizing elements. It includes several micrographs revealing various microstructural features and describes the processing route by which they were achieved. It explains how to estimate the volume fraction of iron-carbon phases in equilibrium and how to determine the amount of each phase that must be present to reach a desired composition. The chapter also discusses the phases associated with hypo- and hyper-eutectoid steels and presents more than a dozen micrographs, identifying important structural features along with cooling conditions and sample preparation procedures.

The microstructure of superalloys is highly complex, with a large number of dispersed intermetallics and other phases that modify alloy behavior through their composition, morphology, and distribution. This chapter provides an overview of the most notable phases, including the matrix phase and geometrically and topologically close-packed phases, and describes how superalloy microstructure can be modified via heat treatments and directional solidification. It also discusses the role of carbides, borides, oxides, and nitrides and the detrimental effects of sulfocarbides.

This chapter explains how the presence of intermediate phases affects the melting behavior of binary alloys and the transformations that occur under different rates of cooling. It begins by examining the phase diagrams of magnesium-lead and copper-zinc, noting some of the complexities associated with intermediate phases. It then discusses the difference between ordered and disordered phases and how they are accounted for on phase diagrams. It describes how the atoms in a disordered solution may arrange themselves into an ordered array, forming a superlattice in the process of cooling, and goes on to identify the most common superlattice structures and their corresponding alloy phases. It also discusses the factors that limit the formation of superlattices along with the kinetics of spinodal decomposition and its effect on microstructure development.

This chapter discusses the development of the nomenclature used to describe the constitution and structure of metals and alloys, particularly the phases observed in the microstructure of steel. It also points out some of the problems with current nomenclature and provides recommendations on how to avoid them.

This chapter describes the iron-carbon phase diagram, its modification by alloying elements, and the effect of carbon on the chemistry and crystallography of austenite, ferrite, and cementite found in Fe-C alloys and steels. It also lays the groundwork for understanding important metallurgical concepts, including solubility, critical temperature, dislocation defects, slip, and diffusion, and how they affect the microstructure, properties, and behaviors of steel.

Structurally differentiated intermetallic phases are important constituents in the microstructure of aluminum alloys, with the potential to influence properties, behaviors, and processing characteristics. These phases can form in aluminum-silicon alloys with transition metals (Fe, Mn, Ni, Cr, V, Ti) and with metals such as Mg and Cu. This chapter is a compilation of phase diagrams, microstructure images, and tables, providing information on more than 30 binary, ternary, and quaternary alloy systems associated with intermetallic phases in aluminum-silicon castings. Each section includes tabular information and data on the intermetallic phases in the aluminum corner of the equilibrium phase diagram, the characteristics of the crystal lattice of intermetallic phases, the chemical composition of the alloy intermetallic phases, and equilibrium reactions in the alloy system.