This chapter provides practical information on surface treatments that work by altering the surface chemistry of metals and alloys. It discusses the use of phosphate and chromate conversion coatings as well as anodizing, steam oxidation, diffusion coatings, and pack cementation. The chapter also covers ion implantation and laser alloying.

Organic coatings (paints and plastic or rubber linings), metallic coatings, and nonmetallic inorganic coatings (conversion coatings, cements, ceramics, and glasses) are used in applications requiring corrosion protection. These coatings and linings may protect substrates by three basic mechanisms: barrier protection, chemical inhibition, and galvanic (sacrificial) protection. This chapter begins with a section on organic coating and linings, providing a detailed account of the steps involved in the coating process, namely, design and selection, surface preparation, application, and inspection and quality assurance. The next section discusses the methods by which metals, and in some cases their alloys, can be applied to almost all other metals and alloys: electroplating, electroless plating, hot dipping, thermal spraying, cladding, pack cementation, vapor deposition, ion implantation, and laser processing. The last section focuses on nonmetallic inorganic coatings including ceramic coating materials, conversion coatings, and anodized coatings.

This chapter covers a wide range of finishing and coating operations, including cleaning, honing, polishing and buffing, and lapping. It discusses the use of rust-preventative compounds, conversion coatings, and plating metals as well as weld overlay, thermal spray, and ceramic coatings and various pack cementation and deposition processes. It also discusses the selection and use of industrial paints and paint application methods.

This chapter provides details on powder-binder processing for three materials, namely precipitation-hardened 17-4 PH stainless steel, cemented carbides, and alumina. The types of powders, binders, feedstock, shaping processes, debinding, sintering cycles, compositions, microstructure, distortion, postsintering treatments, and mechanical properties are presented for each. The shaping options include powder-binder approaches such as binder jetting, injection molding, extrusion, slip and slurry casting, centrifugal casting, tape casting, and additive manufacturing. Sintering options are outlined with respect to attaining high final properties.

This chapter introduces the key powder fabrication attributes to assist in the identification of the right powders for an application. First, it describes the characteristics of engineering powders such as particle size distribution, powder shape and packing density, surface area, powder flow and rheology, and chemical analysis. The chapter then describes the general categories of powder fabrication methods, namely mechanical comminution, electrochemical precipitation, thermochemical reaction, and phase change and atomization. It provides information on the two largest contributors to powder price, namely raw material cost and conversion cost. The applicability of various processes to specific material systems is mentioned throughout this chapter.

This chapter begins with a brief review of the different types of surface treatments and coatings used in industry and their effect on properties and performance. It then discusses the importance of corrosion and wear treatments and the consequences of failing to properly implement them in critical industries such as mining, energy production, transportation, and mineral and chemical processing. The chapter also describes basic approaches to dealing with corrosion and wear in steel.

This chapter compares and contrasts surface-engineering processes based on process availability, corrosion and wear performance, distortion effects, penetration depth or attainable coating thickness, and cost. It provides both quantitative and qualitative information as well as measured property values.

Superalloys tend to operate in environments where they are subjected to high-temperature corrosion, oxidation, and the erosive effects of hot gases. This chapter discusses the nature of these attacks and the effectiveness of various protection methods. It describes the primary forms of oxidation, the development of protective oxides, and the conditions associated with mixed gas corrosion and hot corrosion attack. It discusses oxidation and corrosion testing, the equipment used, and various ways to present the associated data. It describes the effect of gaseous oxidation on different alloys, discusses the formation of oxide scale in the presence of mixed gases, and explains how alloy composition contributes to oxide growth. The chapter discusses the underlying chemistry of hot corrosion, how to identify its effects, and how it progresses under various conditions. It also discusses protective coatings, including aluminide diffusion, overlay, and thermal barrier types, and how they perform in different environments based on their ability to tolerate strain.

This chapter discusses the use of coating methods and materials and their impact on corrosion and wear behaviors. It provides detailed engineering information on a wide range of processes, including organic, ceramic, and hot dip coating, metal plating and cladding, and the use of weld overlays, thermal spraying, and various deposition technologies.

This chapter discusses the types of fibers and matrix materials used in ceramic matrix composites and the role of interfacial coatings. It describes the methods used to produce ceramic composites, including powder processing, slurry infiltration and consolidation, polymer infiltration and pyrolysis, chemical vapor infiltration, directed metal oxidation, and liquid silicon infiltration.

This article discusses the properties, behaviors, and uses of cobalt and its alloys. It explains how cobalt alloys are categorized and describes the commercial designations and grades that are available. It also provides composition information and explains how alloying elements and carbides affect toughness, hardness, ductility, and strength as well as resistance to heat, corrosion, and wear.

Ceramic-matrix composites possess many of the desirable qualities of monolithic ceramics, but are much tougher because of the reinforcements. This chapter explains how reinforcements are used in ceramic-matrix composites and how they alter energy-dissipating mechanisms and load-carrying behaviors. It compares the stress-strain curves for monolithic ceramics and ceramic-matrix composites, noting improvements afforded by the addition of reinforcements. It then goes on to discuss the key attributes, properties, and applications of discontinuously reinforced ceramic composites, continuous fiber ceramic composites, and carbon-carbon composites. It also describes a number of ceramic-matrix composite processing methods, including cold pressing and sintering, hot pressing, reaction bonding, directed metal oxidation, and liquid, vapor, and polymer infiltration.

This chapter discusses the types, methods, and advantages of heat treating procedures, including annealing, normalizing, tempering, and case hardening. It describes the iron-carbon system, the formation of equilibrium and metastable phases, and the effect of alloy elements on hardenability and tempering response. It discusses the significance of critical temperatures, the use of transformation diagrams, and types of annealing treatments. It also provides information on heat treating furnaces, the effect of heating rate on transformation temperatures, quench and temper procedures, and the use of cold treating.

This chapter covers the basic steps of the powder metallurgy process, including powder manufacture, powder blending, compacting, and sintering. It identifies important powder characteristics such as particle size, size distribution, particle shape, and purity. It compares and contrasts mechanical, chemical, electrochemical, and atomizing processes used in powder production, discusses powder treatments, and describes consolidation techniques along with secondary operations used to obtain special properties or improve dimensional precision. It also discusses common defects such as ejection cracks, density variations, and microlaminations.

This chapter covers the practical aspects of machining, particularly for turning, milling, drilling, and grinding operations. It begins with a discussion on machinability and its impact on quality and cost. It then describes the dimensional and surface finish tolerances that can be achieved through conventional machining methods, the mechanics of chip formation, the factors that affect tool wear, the selection and use of cutting fluids, and the determination of machining parameters based on force and power requirements. It also includes information on nontraditional machining processes such as electrical discharge, abrasive jet, and hydrodynamic machining, laser and electron beam machining, ultrasonic impact grinding, and electrical discharge wire cutting.

This chapter describes the physical characteristics, properties, and behaviors of solid solutions under equilibrium conditions. It begins with a review of a single-component pure metal system and its unary phase diagram. It then examines the solid solution formed by copper and nickel atoms. It discusses the difference between interstitial and substitutional solid solutions and the factors that determine the type of solution that two metals are likely to form. It also addresses the development of intermediate phases, the role of free energy, transformation kinetics, liquid-to-solid and solid-state phase transformations, and the allotropic nature of metals.

Generally, binders consist of at least three ingredients: a backbone to provide strength (compounds such as polyethylene, polypropylene, ethylene vinyl acetate, and polystyrene); a filler, such as polyacetal and paraffin wax, to occupy space between particles; and additives, such as stearates, stearic acid, or magnesium stearate, as well as phosphates and sulfonates, to adjust viscosity, lubricate tooling, disperse particles, or induce binder wetting of the powder. In the case of binders deposited via ink jet printing, the binder contains solvents to lower the viscosity for easier jetting. The chapter provides a detailed description of these constituents. The requirements of a binder as well as the factors determining the physical and thermal properties of polymers are discussed. Then, two factors associated with solvation of polymers, namely solubility parameter and wetting, are covered. The chapter ends with information on the specification of polymers used in binders.

This chapter is a detailed account of various attributes related to mixing and testing of powder-binder feedstocks. Mixing parameters and their effects on feedstock properties is discussed. The attributes reviewed include mixture homogeneity, wetting, powder-binder ratio, feedstock density, elastic modulus, rheological behavior, particle size, formulation control, feedstock mixing, and feedstock properties. The chapter also provides information on the processes involved in feedstock preparation and testing.