This chapter discusses various factors pertinent to the prevention of corrosion in alloys for petroleum applications and reviews the selection of stainless steels for petroleum applications, including oil country tubular goods, line pipe, offshore platforms, liquefied natural gas vessels, and refinery equipment.

This chapter discusses the metallurgy, phase structure, thermal processing, and applications of martensitic stainless steels. The phenomenon of martensite formation is explained. A table listing the compositions of martensitic stainless steels is also presented.

This chapter describes the classification of steels and the various compositional categories of commercial steel products. It explains how different alloying elements affect the properties of carbon and low-alloys steels and discusses strength, toughness, and corrosion resistance and how to improve them.

This chapter describes the applications with the greatest impact on titanium consumption and global market trends. It explains where, how, and why titanium alloys are used in aerospace, automotive, chemical processing, medical, and military applications as well as power generating equipment, sporting goods, oil and gas production, and marine vessels.

This chapter addresses the issue of stress-corrosion cracking (SCC) in carbon and low-alloy steels. It discusses crack initiation, propagation, and fracture in aqueous chloride, hydrogen sulfide, sulfuric acid, hydroxide, ammonia, nitrate, ethanol, methanol, and hydrogen gas environments. It explains how composition and microstructure influence SCC, as do mechanical properties such as strength and fracture toughness and processes such as welding and cold work. It also discusses the role of materials selection and best practices for welding.

This chapter presents the primary considerations and mechanisms for corrosion and how they are involved in the selection of materials for process equipment in petroleum refineries and petrochemical plants. In addition, specific information on mechanical properties, corrosion, sulfide stress cracking, hydrogen-induced cracking, stress-oriented hydrogen-induced cracking, hydrogen embrittlement cracking, stress-corrosion cracking, velocity-accelerated corrosion, erosion-corrosion, and corrosion control is provided.

Induction heat treating is used in a wide range of applications. Typical uses, as described in this chapter, include the surface hardening of many types of shafts as well as gears and sprockets and the through-hardening of gripping teeth, cutting edges, and impact zones incorporated into various types of tools and track pins manufactured for off-highway equipment.

Aluminum is the second most widely used metal in the world. It is readily available, offers a wide range of properties, and can be shaped, coated, and joined using a variety of methods. This chapter discusses some of the key attributes of wrought and cast aluminum alloys and the classifications, designations, and grades of available product forms. It also explains how aluminum alloys are used in aerospace, automotive, rail, and marine applications as well as in building and construction, electrical products, manufacturing equipment, packaging, and consumer durables such as appliances and furniture.

The challenge of materials selection is to achieve adequate performance at the lowest possible cost. Corrosion resistance is not the only property to be considered in making materials selections. Typical requirements and some of the procedures involved in making a selection and some of the factors that must be considered when determining the corrosion performance of a given material are listed in this chapter. The various steps that might be included in a materials selection process are then examined. These include a review of operating conditions and design, the selection of candidate materials, the in-depth evaluation of each candidate material, fabrication requirements, follow-up monitoring, and final materials selection. Material considerations such as cost, materials properties, and processing and fabrication requirements are subsequently covered. Finally, the chapter provides information on materials selection under general corrosion conditions and under conditions of localized corrosion forms such as pitting, crevice corrosion, and stress-corrosion cracking.

Failure analysis of steel welds may be divided into three categories. They include failures due to design deficiencies, weld-related defects usually found during inspection, and failures in field service. This chapter emphasizes the failures due to various discontinuities in the steel weldment. These include poor workmanship, a variety of hydrogen-assisted cracking failures, stress-corrosion cracking, fatigue, and solidification cracking in steel welds. Hydrogen-assisted cracking can appear in four common forms, namely underbead or delayed cracking, weld metal fisheyes, ferrite vein cracking, and hydrogen-assisted reduced ductility.

This chapter outlines the step-by-step processes by which materials are selected in order to prevent or control corrosion and includes information on materials that are resistant to the various forms of corrosion. The various forms of corrosion covered are general (uniform) corrosion, localized corrosion, galvanic corrosion, intergranular corrosion, stress-corrosion cracking, hydrogen damage, and erosion-corrosion. In addition, the economic importance of cost-effective materials selection is also considered.

This chapter describes the causes of cracking, embrittlement, and low toughness in carbon and low-alloy steels and their differentiating fracture surface characteristics. It discusses the interrelated effects of composition, processing, and microstructure and contributing factors such as hot shortness associated with copper and overheating and burning as occur during forging. It addresses various types of embrittlement, including quench embrittlement, tempered-martensite embrittlement, liquid-metal-induced embrittlement, and hydrogen embrittlement, and concludes with a discussion on high-temperature hydrogen attack and its effect on strength and ductility.

Compared with other deformation processes used to produce semifinished products, the hot-working extrusion process has the advantage of applying pure compressive forces in all three force directions, enhancing workability. The available variations in the extrusion process enable a wide spectrum of materials to be extruded. This chapter focuses on the processes involved in the extrusion of semifinished products in various metals and their alloys, namely tin, lead, lead-base soft solders, tin-base soft solders, zinc, magnesium, aluminum, copper, titanium, zirconium, iron, nickel, and powder metals. It discusses their properties and applications as well as suitable equipment for extrusion. It further discusses the processes involved in the extrusion of semifinished products in exotic alloys and extrusion of semifinished products from metallic composite materials.