This appendix contains a table listing cross-references of standard SAE carbon and low-alloy steels to selected chemically similar steels.

This appendix consists of a table listing cross reference to non-AISI and AISI steels of various countries, namely France, Germany, Italy, Japan, Sweden, the United Kingdom, and the United States.

This appendix discusses the general characteristics, composition, phase transformations, and properties of commercial stainless steels used for making high-quality knives.

This chapter provides perspective on the physical dimensions associated with the microstructure of steel and the instruments that reveal grain size, morphology, phase distributions, crystal defects, and chemical composition, from which properties and behaviors derive. The chapter also reviews the definitions and classifications used to identify and differentiate commercial steels, including the AISI/SAE and UNS designation systems.

This chapter examines the early literature on stainless steel to gain an understanding of the state-of-the-art of stainless steel as it progressed through the first 37 years after the discoveries made in Sheffield and Essen.

This appendix is a timeline of events related to the discovery, development, and commercialization of stainless steels.

This chapter provides an overview of the fundamental material- and process-related parameters of quenching on residual stress, distortion control, and cracking. It begins with a description of phase transformations during heating and quenching of steel. This is followed by a section on the effects of materials and quench process design on distortion of steel during heat treating. Details on stress raisers and their role in quench cracking are then presented. The chapter ends with various selected case histories of failures attributed to the quenching process.

This chapter discusses the factors that influence temperature in forging operations and presents equations that can be used to predict and control it. The discussion covers heat generation and transfer, the effect of metal flow, temperature measurement, testing methods, and the influence of equipment-related parameters such as press speed, contact time, and tooling geometries.

This chapter addresses some of the challenges involved in materials selection, providing context for much of the information presented in the book. It describes a typical four-step design scenario, noting material-related considerations and information needs. It explains how design decisions are complicated by the interconnected nature of material properties, design geometry, and manufacturing requirements and effects. The chapter also assesses the design impact of several materials and discusses codes, standards, and specifications.

The decomposition of austenite, during controlled cooling or quenching, produces a wide variety of microstructures in response to such factors as steel composition, temperature of transformation, and cooling rate. This chapter provides a detailed discussion on the isothermal transformation and continuous cooling transformation diagrams that characterize the conditions that produce the various microstructures. It discusses the mechanism and process variables of quenching of steel, explaining the factors involved in the mechanism of quenching. In addition, the chapter provides information on the causes and characteristics of residual stresses, distortion, and quench cracking of steel.

This chapter provides information on the properties and behaviors of stainless steels and stainless steel powders. It begins with a review of alloy designation systems and grades by which stainless steels are defined. It then describes the composition, metallurgy, and engineering characteristics of austenitic, ferritic, martensitic, duplex, and precipitation hardening stainless steel powders and metal injection molding grades.

Steels with chromium contents above 12% show high resistance to oxidation and corrosion and are generally designated as stainless steels. This chapter discusses the compositions, microstructures, heat treatments, and properties of martensitic, ferritic, austenitic, ferritic-austenitic (duplex), and precipitation hardening stainless steels. It also describes solidification sequences and explains how chromium carbides may segregate to grain boundaries at certain temperatures, making grain boundary regions susceptible to intercrystalline or intergranular corrosion.

Nitriding is a case-hardening process used for alloy steel gears and is quite similar to case carburizing. Nitriding of gears can be done in either a gas or liquid medium containing nitrogen. This chapter discusses the processes involved in gas nitriding. It reviews the effects of white layer formation in nitrided gears and presents general recommendations for nitrided gears. The chapter describes the microstructure, overload and fatigue damage, bending-fatigue life, cost, and distortion of nitrided gears. Information on nitriding steels used in Europe and the applications of nitrided gears are also provided. The chapter presents case studies on successful nitriding of a gear and on the failure of nitrided gears used in a gearbox subjected to a load with wide fluctuations.

With cold work, mechanical strength (measured either by yield strength or ultimate tensile strength) increases and ductility (measured by elongation, reduction of area, or fracture toughness) normally decreases. This chapter discusses the mechanisms that produce these changes and the factors that influence them. It explains how cold working increases dislocation density and how that affects the stress-strain characteristics of steel, particularly the onset of deformation. It describes the effects of deformation on ferrite, austenite, cementite, and pearlite, and how to optimize their microstructure for various applications through controlled deformation. It also provides information on subcritical annealing, the examination and control of texture, the use of optical microscopy to monitor the effects of recrystallization, and the effect of cold working on threaded fasteners, nails, and filaments used to manufacture cords.

This chapter provides a practical understanding of heat treatments and how to employ them to optimize the properties and structures of cast irons and steels. It discusses annealing, normalizing, quenching, tempering, patenting, carburizing, nitriding, carbonitriding, and nitrocarburizing. It describes the primary objectives of each treatment along with processing sequences, process parameters, and related phase transformations. The chapter contains more than 100 images, including time-temperature diagrams, transformation curves, data plots, and detailed micro- and macrographs. It also discusses the concepts of hardenability, critical diameter, quench severity, and Jominy testing.

This chapter describes the metallurgy, composition, and properties of steels and other alloys. It provides information on the atomic structure of metals, the nature of alloy phases, and the mechanisms involved in phase transformations, including time-temperature effects and the role of diffusion, nucleation, and growth. It also discusses alloying, heat treating, and defect formation and briefly covers condenser tube materials.

High-strength steels are susceptible to stress-corrosion cracking (SCC) even in moist air. This chapter identifies such steels and the applications where they are typically found. It provides information on crack growth kinetics and crack propagation models in which hydrogen embrittlement is the predominant mechanism. It explains how different application variables affect SCC, including loading mode, state of stress, type of steel, temperature, electrochemical potential, heat treatment, and deformation processes. It also compares SCC characteristics in different high-strength steels and discusses the influence of composition, steelmaking practice, and application environment.

This chapter describes the designations of carbon and low-alloy steels and their general characteristics in terms of their response to hardening and mechanical properties. The steels covered are low-carbon steels, higher manganese carbon steels, boron-treated carbon steels, H-steels, free-machining carbon steels, low-alloy manganese steels, low-alloy molybdenum steels, low-alloy chromium-molybdenum steels, low-alloy nickel-chromium-molybdenum steels, low-alloy nickel-molybdenum steels, low-alloy chromium steels, and low-alloy silicon-manganese steels. The chapter provides information on residual elements, microalloying, grain refinement, mechanical properties, and grain size of these steels. In addition, the effects of free-machining additives are also discussed.

Gas (atmosphere) carburizing is the de facto standard by which all other surface hardening techniques are measured and is the emphasis of this chapter. Initially, the chapter describes the process and equipment for gas carburizing. This is followed by sections discussing the processes involved in quenching, hardening, tempering, recarburizing, and cold treatment of carburized and quenched gears. Next, the chapter reviews the selection process of materials for carburized gears and provides information on carbon content, properties, and core hardness of gear teeth. The problems associated with carburizing are then covered, followed by the processes involved in heat treat distortion and shot peening of carburized and hardened gears. Information on grinding stock allowance on tooth flanks to compensate for distortion is also provided. The chapter further discusses the applications of carburized and hardened gears. Finally, it reviews vacuum carburizing and compares the attributes of conventional gas carburizing and vacuum carburizing.