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miscibility
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Published: 01 March 2012
Fig. 3.23 Schematic binary phase diagram showing miscibility in both the liquid and solid states. Source: Ref 3.2
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Image
Published: 01 March 2012
Fig. 3.25 Schematic binary phase diagrams with solid-state miscibility where the liquidus shows (a) a maximum and (b) a minimum. Source: Ref 3.2
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Image
Published: 01 March 2012
Fig. 4.2 Schematic binary phase diagram showing miscibility in both the liquid and solid states. Source: Ref 4.1
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Image
Published: 01 March 2012
Fig. 4.8 Schematic binary phase diagrams with solid-state miscibility where the liquidus shows (a) a maximum and (b) a minimum. Source: Ref 4.1
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Published: 01 March 2012
Fig. 9.18 Miscibility gap. Region 1: Homogenous α is stable. Region 2: Homogenous α is metastable; only incoherent phases can nucleate. Region 3: Homogeneous α is metastable; coherent phases can nucleate. Region 4: Homogeneous α is unstable; spinodal decomposition occurs. Source: Ref 9.11
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Published: 01 March 2012
Fig. 12.16 Schematic binary phase diagrams with solid-state miscibility where the liquidus shows (a) a maximum and (b) a minimum. Source: Ref 12.1
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Published: 01 December 2008
Fig. 4.13 Binodal curve of liquids (the hatched area indicates the miscibility gap). (a) Normal type of binodal curve of water and phenol. (b) Inverted type of binodal curve of polyvinyl methyl ether (PVME) (molecular weight 51,500) and polystyrene (PS) (molecular weight 20,400)
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Image
Published: 01 December 2008
Fig. 4.17 Miscibility gap of A-B-C ternary system (the dashed line shows the spinodal curve). The upper figure is the free-energy surface. The lower figure is the isothermal phase diagram.
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Published: 01 December 2008
Fig. 4.18 Analysis of miscibility gap island (MGI) (see Fig. 7.13 ). (a) Free-energy surface. (b) Isothermal diagram. (c) Section of free energy along A-D. (d) View of vertical section
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Image
Published: 01 December 2008
Fig. 4.20 Analysis of miscibility gap island in a composite system of compounds
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Published: 01 December 2008
Fig. 4.21 Miscibility gap of a solid solution is caused by the repulsive reaction between atoms. However, the miscibility gap island is caused by the difference in interatomic binding forces.
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Published: 01 December 2008
Fig. 7.12 The miscibility gap island in A-B-C ternary system (see Fig. 4.18 ). (a) In a disordered solid solution. (b) When ordering is considered
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Published: 01 December 2008
Fig. 7.13 The analysis of the miscibility gap island extended by ordering (see Fig. 4.18 ). (a) Free energy of A-BC system ( T = 1500 K). (b) Phase diagram of A-BC system. (c) Phase diagram of A-B-C system
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in Phase Diagram Problems and Solutions
> Phase Diagrams: Key Topics in Materials Science and Engineering
Published: 31 January 2024
Fig. A34 Iron-tin phase diagram. This system contains a miscibility gap, which is where a liquid separates into two liquids of different composition. These liquids are treated like any other phase. The exact boundaries are not fully identified; hence, the dashed line is used for the phase
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Published: 01 December 2008
Fig. 4.2 Calculated example ( Exercise 4.1 ) of phase diagram for completely miscible type
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Published: 01 March 2012
Fig. 4.9 Schematic binary phase diagram with a minimum in the liquidus and a miscibility gap in the solid state. Source: Ref 4.1
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Published: 01 March 2012
Fig. 5.1 Schematic binary phase diagram with a minimum in the liquidus and a miscibility gap in the solid state. Source: Ref 5.1
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Published: 01 March 2012
Fig. 3.24 Use of Gibbs energy curves to construct a binary phase diagram that shows miscibility in both the liquid and solid states. Source: Ref 3.3 as published in Ref 3.2
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Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2008
DOI: 10.31399/asm.tb.tm.t52320091
EISBN: 978-1-62708-357-7
... ) ] } Figure 4.2(a) shows the calculated phase diagram on the assumption that the melting points of both components are T A = 1000 K and T B = 500 K. Figure 4.2(b) shows the free-energy diagram at T = 800 K. Fig. 4.2 Calculated example ( Exercise 4.1 ) of phase diagram for completely miscible...
Abstract
This chapter explains the significance of the phase diagram and its use in the development of new materials. The chapter describes the basic rules of heterogeneous equilibrium, presents a comparison between liquidus line and solidus line, and provides information on the solubility curve and the binodal curve.
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