This chapters discusses the basic steps in the failure analysis process. It covers examination procedures, selection and preservation of fracture surfaces, macro and microfractography, metallographic analysis, mechanical testing, chemical analysis, and simulated service testing.

Corrosion failures of welds can occur even when the proper base metal and filler metal have been selected, industry codes and standards have been followed, and welds have been deposited that possess full weld penetration and have proper shape and contour. This chapter describes some of the general characteristics associated with the corrosion of weldments. The role of macro- and microcompositional variations, a feature common to weldments, is emphasized in this chapter to bring out differences that need to be realized in comparing the corrosion of weldments to that of wrought materials. The discussion covers the factors influencing corrosion of weldments, microstructural features of weld microstructures, various forms of weld corrosion, and welding practice to minimize corrosion.

Carbon and low-alloy steels are the most frequently welded metallic materials, and much of the welding metallurgy research has focused on this class of materials. Key metallurgical factors of interest include an understanding of the solidification of welds, microstructure of the weld and heat-affected zone (HAZ), solid-state phase transformations during welding, control of toughness in the HAZ, the effects of preheating and postweld heat treatment, and weld discontinuities. This chapter provides information on the classification of steels and the welding characteristics of each class. It describes the issues related to corrosion of carbon steel weldments and remedial measures that have proven successful in specific cases. The major forms of environmentally assisted cracking affecting weldment corrosion are covered. The chapter concludes with a discussion of the effects of welding practice on weldment corrosion.

Many factors must be considered when welding dissimilar metals, and adequate procedures for the various metals and sizes of interest for a specific application must be developed and qualified. Most combinations of dissimilar metals can be joined by solid-state welding (diffusion welding, explosion welding, friction welding, or ultrasonic welding), brazing, or soldering where alloying between the metals is normally insignificant. This chapter describes the factors influencing joint integrity and discusses the corrosion behavior of dissimilar metal weldments.

Nickel-base alloys used for low-temperature aqueous corrosion are commonly referred to as corrosion-resistant alloys (CRAs), and nickel alloys used for high-temperature applications are known as heat-resistant alloys, high-temperature alloys, or superalloys. The emphasis in this chapter is on the CRAs and in particular nickel-chromium-molybdenum alloys. The chapter provides a basic understanding of general welding considerations and describes the welding metallurgy of molybdenum-containing CRAs and of nickel-copper, nickel-chromium, and nickel-chromium-iron CRAs. It discusses the corrosion behavior of nickel-molybdenum alloys and nickel-chromium-molybdenum alloys. Information on the phase stability and corrosion behavior of nickel-base alloys is also included.

This chapter reviews weld corrosion in three key application areas: petroleum refining and petrochemical operations, boiling water reactor piping systems, and components used in pulp and paper plants. The discussion of each area addresses general design and service characteristics, types of weld corrosion issues, and prevention or mitigation strategies.

Austenitic stainless steels exhibit a single-phase, face-centered cubic structure that is maintained over a wide range of temperatures. This chapter provides a basic understanding of grade designations, properties, and welding considerations of austenitic stainless steels. It also discusses general types of corrosive attack and their effects on service integrity as well as detection and control measures. The five corrosive attack mechanisms covered are intergranular corrosion, preferential attack associated with weld metal precipitates, pitting and crevice corrosion, stress-corrosion cracking, and microbiologically influenced corrosion.

This chapter addresses in-service monitoring and corrosion testing of weldments. Three categories of corrosion monitoring are discussed: direct testing of coupons, electrochemical techniques, and nondestructive testing techniques. The majority of the test methods for evaluating corrosion of weldments are used to assess intergranular corrosion of stainless steels and high-nickel alloys. Other applicable tests evaluate pitting and crevice corrosion, stress-corrosion cracking, and microbiologically influenced corrosion. Each of these test methods is reviewed in this chapter.

The nonferrous alloys described in this chapter include aluminum and aluminum alloys, copper and copper alloys, titanium and titanium alloys, zirconium and zirconium alloys, and tantalum and tantalum alloys. Some of the factors that affect the corrosion performance of welded nonferrous assemblies include galvanic effects, crevices, assembly stresses in products susceptible to stress-corrosion cracking, and hydrogen pickup and subsequent cracking. The emphasis is placed on the compositions, general welding considerations, and corrosion behavior of these alloys.

Ferritic stainless steels are essentially iron-chromium alloys with body-centered cubic crystal structures. Chromium content is usually in the range of 11 to 30%. The primary advantage of the ferritic stainless steels, and in particular the high-chromium, high-molybdenum grades, is their excellent stress-corrosion cracking resistance and good resistance to pitting and crevice corrosion in chloride environments. This chapter provides information on the classifications, properties, and general welding considerations of ferritic stainless steels. The emphasis is placed on intergranular corrosion, which is the most common cause of failure in ferritic stainless steel weldments. Two case histories involving intergranular corrosion failures of ferritic stainless steel weldments are included. A brief discussion on hydrogen embrittlement is also provided.

A compressor blade made of titanium alloy fractured during an engine test. The material and processing conditions of the blade were found to be satisfactory, turning the focus of the investigation to operating anomalies and human error. A photograph of the failed blade shows well-defined chevron marks along the fracture surface that end in a shear lip on the convex side. Further examination using a SEM shows that the failure was due to overload. Based on these observations and the results of tensile testing and microstructural analysis, investigators concluded that a sudden impact load on the concave side of the blade caused it to fracture.

This report describes the failure of a gas turbine in a combined-cycle power plant and the examination and tests that were conducted to determine the cause. Based on microstructural analysis, hardness measurements, and tensile tests, the failure was attributed to inadequate clearances in the seal land region between two stages in the compressor section of the rotor. The report also recommends changes to remediate the problem.

This appendix focuses on procedures, techniques, and precautions associated with the investigation and analysis of metallurgical failures that occur in service. It describes the steps of an orderly failure analysis from collecting and examining samples to performing mechanical and nondestructive tests, preparing and examining fractographs and micrographs, determining failure mode, writing the report, and developing follow-up recommendations. It also examines the fundamental mechanisms of failure, why they occur, and how to identify them by their characteristic features.

A turbine blade in an aircraft engine failed, fracturing at the root above the fir tree region. Fractography indicated that a fatigue crack initiated at the trailing edge of the blade and the final fracture occurred when the crack reached critical length. Although the exact cause of crack initiation could not be established, material defects, improper root loading, and high operating temperatures were ruled out. This chapter describes how investigators came to their conclusions and what they learned through visual and SEM examination and qualitative elemental analysis. It includes images of the microstructure and fracture surfaces and explains what some of the details reveal about the failure.

A test flight was cut short after a fire warning came on indicating a problem with one of the four engines on an aircraft. A visual examination following the precautionary landing revealed several burned hoses, a melted bolt, and fuel leaking from the base of the main burner. The fuel nozzle was also damaged, and based on its microstructure, came very close to melting. Investigators determined that the burner was mounted backwards, facing the compressor rather than the turbine. They also recommended a redesign to prevent the fuel nozzle from being reversed.

An aircraft crashed following the loss of yaw control in full airborne flight. The subsequent discovery of broken shutter bolts in the rear pitch reaction control valve led to an inspection campaign that found bolt failures of a similar nature in valves on several other aircraft. The bolts were removed and analyzed to determine the mode and cause of failure. Based on the results of macroscopy, scanning electron fractography, metallographic examination, and chemical analysis, the failures were caused by stress corrosion cracking, and in one case, overtightening.

A low-pressure turbine rotor blade failed in service, causing extensive engine damage. A section of the blade broke off around 25 mm from the root platform, producing a flat fracture surface that appeared smooth on one end and grainy elsewhere. Based on their examination, investigators concluded that the nickel-base superalloy blade was exposed to high temperatures and stresses, initiating a crack that propagated under cyclic loading. This chapter provides a summary of the investigation and the insights acquired using scanning electron fractography, metallography, and hardness measurements.

A pair of bearings mounted side by side in an aircraft engine failed in service. Photographs show that the inner rings were either broken or deformed, the balls were worn and flattened, and the cages severely damaged. The bearing races were damaged as well, but only on one side indicating a directional thrust. In addition to their examination, investigators also conducted metallographic studies and hardness tests, which indicated that the balls and inner rings reached temperatures above 825 °C (1520 °F). Based on their findings, investigators concluded that the bearings failed due to overheating, possibly as a result of misalignment compounded by insufficient lubrication and high speeds.

This chapter provides an overview of the tools and techniques used to examine failure specimens and the wealth of information that can be obtained from fracture surfaces, cracks, wear patterns, and other such features. It discusses the use of metallography, fractography, and optical and electron microscopy. It presents a number of images recorded using these methods and explains what they reveal about the mode of fracture and the state of the component prior to failure.

This chapter discusses the techniques applicable to the diagnosis of corrosion failures, including visual and microscopic examination of corroded surfaces and microstructure; chemical analysis of the metal, corrosion products, and bulk environment; nondestructive evaluation methods; corrosion testing techniques; and mechanical testing techniques. A guide to investigative techniques used in corrosion failure analysis is provided in a table, describing the advantages and limitations of each technique. The principal stages of the investigation and analysis of corrosion failures discussed in the chapter are: collection of background information and sampling; preliminary laboratory examination; detailed metallographic and fractographic examinations; chemical analysis of corrosion products and bulk materials; corrosion testing for quality control; mechanical testing for quality control; and analysis of results and report writing.