Medium-carbon steels are typically hardened for high-strength, high-fatigue-resistant applications by austenitizing, quenching to martensite, and tempering. This chapter explains how microalloying with vanadium, niobium, and/or titanium provides an alternate way to improve the mechanical properties of such steels. It also addresses microalloyed forging steels and explains how nontraditional bainitic microstructures can be produced by direct cooling after forging.

This article discusses the effect of alloying on high-strength low-alloy (HSLA) steels. It explains where HSLA steels fit in the continuum of commercial steels and describes the six general categories into which they are divided. It provides composition data for standard types or grades of HSLA steel along with information on available mill forms, key characteristics, and intended uses. The article explains how small amounts of alloying elements, particularly vanadium, niobium, and titanium, control not only the properties of HSLA steels, but also their manufacturability.

Austenite is the key to the versatility of steel and the controllable nature of its properties. It is the parent phase of pearlite, martensite, bainite, and ferrite. This chapter discusses the importance of austenite, beginning with the influence of austenitic grain size and how to accurately measure it. It then describes the principles of austenite formation and grain growth and examines several time-temperature-austenitizing diagrams representing various alloying and processing conditions. The chapter concludes with a discussion on hot deformation and subsequent recrystallization.

This chapter introduces the metallographer to the various types of steels and cast irons and explains how they are classified and defined. Classification and designation details are provided for plain carbon steels, alloy steels, and gray, white, ductile, and malleable cast irons.

This chapter discusses various alloying and processing approaches to increase the strength of low-carbon steels. It describes hot-rolled low-carbon steels, cold-rolled and annealed low-carbon steels, interstitial-free or ultra-low carbon steels, high-strength, low-alloy (HSLA) steels, dual-phase (DP) steels, transformation-induced plasticity (TRIP) steels, and martensitic low-carbon steels. It also discusses twinning-induced plasticity (TWIP) steels along with quenched and partitioned (Q&P) steels.

Structural steels are used for components such as I-beams and automobile frames. This chapter focuses on processing these steels to attain a fine primary ferrite grain size to develop high strength. It first reviews the concepts and principles of recrystallization in plastically deformed metals. The chapter reviews the concepts of annealing of cold worked metals. It then looks at hot working and the grain size associated with it. Additionally, the chapter reviews the methods of strengthening in the steels that rely mainly on reduction in the primary ferrite grain size. It discusses basic methods used to develop a small austenite grain size, and hence a small primary ferrite grain size. Then, the chapter covers the processes involved in the precipitation hardening of the ferrite. Finally, it examines some commercial thermomechanical processes used on structural steels, namely hot deformation and controlled cooling.

Inclusions and chemical segregation are factors in many process-induced failures involving steel parts. Inclusions are nonmetallic compounds introduced during production; segregation is a type of chemical partitioning that occurs during solidification. This chapter discusses the origins of segregation and inclusions and their effect on the mechanical properties and microstructure of steel. It explains how to identify various types of inclusions and characteristic segregation patterns, such as banding. It also describes the effect of hot work processing on solidification structure and the chemical variations produced by interdendritic segregation.