This chapter is dedicated mostly to the metallurgical effects on the corrosion behavior of corrosion-resistant alloys. It begins with a section describing the importance of alloying elements on the corrosion behavior of nickel alloys. The chapter considers the metallurgical effects of alloy composition for heat-resistant alloys, nickel corrosion-resistant alloys, and nickel-base alloys. This chapter also discusses the corrosion implications of changing the alloy microstructure via solid-state transformation, second-phase precipitation, or cold work. It concludes with a comparison of corrosion behavior between cast and wrought product forms.

This chapter is dedicated mostly to the metallurgical effects on the corrosion behavior of corrosion-resistant alloys. It begins with a section describing the importance of alloying elements on the corrosion behavior of nickel alloys. The chapter considers the metallurgical effects of alloy composition for heat-resistant alloys, nickel corrosion-resistant alloys, and nickel-base alloys. This chapter also discusses the corrosion implications of changing the alloy microstructure via solid-state transformation, second-phase precipitation, or cold work. It concludes with a comparison of corrosion behavior between cast and wrought product forms.

This chapter describes the effects of metallurgical variables on the corrosion of aluminum alloys. Emphasis is placed on the effect of constituent particles on pitting corrosion of aluminum.

This chapter discusses the effects of metallurgical variables on dealloying corrosion. It begins by describing the processes involved in dealloying of metal alloys in aqueous environments. This is followed by a discussion on the morphology of porous dealloyed structures below and above the critical potential. Some features experimentally observed for dealloying systems are then considered. The chapter concludes by briefly reviewing the proposed mechanisms for the formation of porous metals, namely ionization-redeposition mechanism, surface diffusion mechanism, volume diffusion mechanism, and percolation model of selective dissolution.

Phases are distinct states of aggregation of matter and one of the primary leverage points for understanding and applying materials. This chapter discusses the phase nature of metals and alloys, the concept of solid solutions, and the use of phase diagrams. It also describes some of the metallurgical effects of freezing or solidification, including the segregation of solutes and the formation of metal glasses.

This chapter reviews the concepts of fracture mechanics and their application to materials evaluation and the design of cryogenic structures. Emphasis is placed on an explanation of technology, a review of fracture mechanics testing methods, and a discussion on the many factors contributing to the fracture behavior of materials at cryogenic temperatures. Three approaches of elastic-plastic fracture mechanics are covered, namely the crack opening displacement, the J-integral, and the R-curve methods. The chapter also discusses the influence of thermal and metallurgical effects on toughness at low temperatures.

This chapter compares and contrasts empirical approaches for partitioning hysteresis loops and predicting creep-fatigue life. The first part of the chapter presents experimental partitioning methods, explaining how they can be used to partition any loading cycle into its basic strain-range components. The methods covered include rapid cycling between peak stress extremes, half-cycle rapid loading and unloading, and variations of the incremental step-stress approach. The methods are then compared based on their ability to predict creep-fatigue life. The chapter goes on from there to describe how fatigue life can be estimated from ductility measurements when cyclic data are unavailable or are likely to change. It also explains how cyclic life is influenced by the time-dependent nature of creep-plasticity and the physical and metallurgical effects of environmental exposure.

This chapter provides an introduction to various forms of corrosion, namely uniform corrosion, localized corrosion, mechanically assisted degradation, environmentally induced cracking, microbiologically influenced corrosion, and metallurgically influenced corrosion.

The tensile test provides a relatively easy, inexpensive technique for developing mechanical property data for the selection, qualification, and utilization of metals and alloys in engineering service. The tensile test requires interpretation, and interpretation requires a knowledge of the factors that influence the test results. This chapter provides a metallurgical perspective for such interpretation. The topics covered include elastic behavior, anelasticity, damping, proportional limit, yield point, ultimate strength, toughness, ductility, strain hardening, and yielding and the onset of plasticity. The chapter describes the effects of grain size on yielding, effect of cold work on hardness and strength, and effects of temperature and strain-rate on the properties of metals and alloys. It provides information on true stress-strain relationships and special tests developed to measure the effects of test/specimen conditions. Finally, the chapter covers the characterization of tensile fractures of ductile metals and alloys.

Carbon and low-alloy steels are the most frequently welded metallic materials, and much of the welding metallurgy research has focused on this class of materials. Key metallurgical factors of interest include an understanding of the solidification of welds, microstructure of the weld and heat-affected zone (HAZ), solid-state phase transformations during welding, control of toughness in the HAZ, the effects of preheating and postweld heat treatment, and weld discontinuities. This chapter provides information on the classification of steels and the welding characteristics of each class. It describes the issues related to corrosion of carbon steel weldments and remedial measures that have proven successful in specific cases. The major forms of environmentally assisted cracking affecting weldment corrosion are covered. The chapter concludes with a discussion of the effects of welding practice on weldment corrosion.

This chapter discusses the effects of metallurgical factors on the corrosion resistance of magnesium alloys. The factors are chemical composition, heat treating, grain size, and cold-work effects. The chapter describes the causes of corrosion failures in magnesium alloys, namely heavy-metal contamination, blast residues, flux inclusions, and galvanic attack.

Many metallic components, such as retorts in heat treat furnaces, furnace heater tubes and coils in chemical and petrochemical plants, waterwalls and reheater tubes in boilers, and combustors and transition ducts in gas turbines, are subject to oxidation. This chapter explains how oxidation affects a wide range of engineering alloys from carbon and Cr-Mo steels to superalloys. It discusses the kinetics and thermodynamics involved in the formation of oxides and the effect of surface and bulk chemistry. It provides oxidation data for numerous alloys and intermetallics in terms of weight gain, metal loss, depth of attack, and oxidation rate. It also discusses the effect of metallurgical and environmental factors such as oxygen concentration, high-velocity combustion gas streams, chromium depletion and breakaway, component thickness, and water vapor.

Steel is an important material because of its tremendous flexibility in metal working and heat treating to produce a variety of mechanical, physical, and chemical properties. The purpose of this chapter is to present the metallurgical principles of heat treatment of steel in a generalized manner. The chapter provides a discussion on the constitution of commercially pure iron, subsequently leading to discussion on the iron-carbon alloy system. The chapter also describes the effect of carbon on the constitution of iron and of the solubility of carbon in iron. It provides information on transformations and on the classification of steels by carbon content. The chapter ends with a discussion on the effect of time on transformation and on the use of time-temperature-transformation diagrams.

This chapter presents basic principles and the theoretical results of heat transport in solids. Thermal conductivity and thermal diffusivity are the principal properties discussed. Discussions are also included on the effects of temperature, magnetic field, and metallurgical variations caused by composition, processing, and heat-treatment differences. Numerous graphs illustrate the qualitative and quantitative effects of these variables. Measurement methods and associated accuracies and pertinent empirical correlations are presented.

This chapter introduces the concepts of mechanical properties and the various underlying metallurgical mechanisms that can be used to alter the strength of materials. The mechanical properties discussed include elasticity, plasticity, creep deformation, fatigue, toughness, and hardness. The strengthening mechanisms covered are solid-solution strengthening, cold working, and dispersion strengthening. The effect of grain size on the yield strength of a material is also discussed.

This chapter discusses various factors that affect corrosion of stainless steel weldments. It begins by providing an overview of the metallurgical factors associated with welding. This is followed by a discussion on preferential attack associated with weld metal precipitates in austenitic stainless steels as well as several forms of corrosion associated with welding. The effects of gas-tungsten arc weld shielding gas composition and heat-tint oxides on corrosion resistance are then covered. Microbiological corrosion of butt welds in water tanks is also illustrated. In addition, the chapter provides information on corrosion of ferritic and duplex stainless steel weldments.

Stainless steels and nickel-base alloys are recognized for their resistance to general corrosion and other categories of corrosion. This chapter examines the effects of specific alloying elements, metallurgical structure, and mechanical conditioning on the corrosion resistance of these alloys. Some categories of corrosion covered are pitting, crevice, intergranular, stress-corrosion cracking, general, and high-temperature corrosion.

This chapter discusses the stress-strain response of materials, how it is measured, and how it used to set performance expectations. It begins by describing the common tensile test and how it sheds light on the elastic design of structures as well as plasticity and fracture behaviors. It explains how engineering and true stress-strain curves differ, how one is used for design and the other for analyzing metal forming operations. It discusses the effect of holes, fillets, and radii on the distribution of stresses and the use of notch tensile testing to detect metallurgical embrittlement. The chapter also covers compression, shear, and torsion testing, the prediction of yielding, residual stress, and hardness.

Titanium alloys are generally resistant to stress-corrosion cracking (SCC), but under certain conditions, the potential for problems exists. This chapter identifies the types of service environments where titanium alloys have exhibited signs of SCC. It begins by describing the nominal composition, designation, and grade of nearly two dozen commercial titanium alloys and the different types of media (including oxidizers, organic compounds, hot salt, and liquid metal) in which SCC has been observed. It discusses the mechanical and metallurgical factors that influence SCC behavior and examines the cracking and fracture mechanisms that appear to be involved. The chapter also includes information on SCC test standards and provides detailed guidelines on how to prevent or mitigate the effects of SCC.