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metal-oxide frits
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Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 November 2013
DOI: 10.31399/asm.tb.mfub.t53740325
EISBN: 978-1-62708-308-9
... bonding properties, they are particularly useful in polishing tougher metals, such as alloy steels, high-speed steels, and malleable and wrought iron. Silicon carbide is harder than aluminum oxide, and it fractures easily, providing new cutting surfaces that extend the useful life of the abrasive. Silicon...
Abstract
This chapter covers a wide range of finishing and coating operations, including cleaning, honing, polishing and buffing, and lapping. It discusses the use of rust-preventative compounds, conversion coatings, and plating metals as well as weld overlay, thermal spray, and ceramic coatings and various pack cementation and deposition processes. It also discusses the selection and use of industrial paints and paint application methods.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 August 1999
DOI: 10.31399/asm.tb.caaa.t67870191
EISBN: 978-1-62708-299-0
... 50 μm (2 mils) thick. Anodic coatings have a porous outer portion and a thin barrier layer adjacent to the metal interface. The porous outer portion of the coating consists of close-packed cells of oxide, predominantly hexagonal in shape, each of which contains a single pore ( Fig. 9 ). In order...
Abstract
This chapter discusses corrosion prevention methods used with aluminum and its alloys. The methods range from relatively straightforward measures, such as proper handling and storage, to advanced early warning corrosion monitoring systems for military aircraft. The chapter summarizes the basic factors that influence design for corrosion resistance and discusses the use of conversion coatings, organic coatings, porcelain enameling, and electroplating. It also discusses corrosion monitoring methods used in chemical processing and refining industries.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 July 2009
DOI: 10.31399/asm.tb.bcp.t52230107
EISBN: 978-1-62708-298-3
... laboratory experience shows that fusion with sodium fluoride or fritting with sodium peroxide are the best methods for dissolving beryllium minerals. Potassium hydroxide fusions are best for beryllium oxide and similar products based on it, which have been heated to a high temperature (>1550 °C, or 2820...
Series: ASM Technical Books
Publisher: ASM International
Published: 01 July 2009
DOI: 10.31399/asm.tb.bcp.t52230071
EISBN: 978-1-62708-298-3
... into solution. The addition of the metal oxide is postulated to convert the complex [Si 6 O 18 ] 12– anions into orthosilicate forms through: (Eq 7.1) ( Si 6 O 18 ) 12 − = n SiO 2 + ( 6 − n ) SiO 4 4...
Abstract
This chapter describes some of the chemical processes that have been developed to extract beryllium from different types of ore. It covers the Kjellgren-Sawyer sulfate method, the Degussa method, Copaux-Kawecki fluoride extraction, solvent extraction, and leaching and settling. It also provides information on electrolytic extraction and the use of electrorefining.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2001
DOI: 10.31399/asm.tb.aub.t61170540
EISBN: 978-1-62708-297-6
... Powder, metal Magnets 8.5 Metal, powder Cemented carbides and diamond tooling 15.2 Powder Catalysts 8.0 Salts (carbonate, sulfate, nitrate, acetate), metal Colorizers (a) 11.6 Oxide plus some sulfate, hydroxide, and carbonate Feedstuff, anodizing, magnetic recording, electrolysis...
Abstract
This article discusses the properties, behaviors, and uses of cobalt and its alloys. It explains how cobalt alloys are categorized and describes the commercial designations and grades that are available. It also provides composition information and explains how alloying elements and carbides affect toughness, hardness, ductility, and strength as well as resistance to heat, corrosion, and wear.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 February 2005
DOI: 10.31399/asm.tb.chffa.t51040257
EISBN: 978-1-62708-300-3
..., it is possible to use nickel-base superalloys as bolster materials, whereas the remainder of the die assembly can be made from tool steels and stainless steels. The use of insulators, such as metallic sheets coated with ceramics such as zirconium oxide, and water cooling reduces heat losses and prevents damage...
Abstract
This chapter discusses the processes of isothermal and hot-die forging and their use in producing aerospace components. It explains how isothermal forging was developed to provide a near-net shape component geometry and well-controlled microstructures and properties with accurate control of the working temperature and strain rate. It describes the materials typically used as well as equipment and tooling, die heating procedures, part separation techniques, and postforging heat treatment.
Book: Principles of Soldering
Series: ASM Technical Books
Publisher: ASM International
Published: 01 April 2004
DOI: 10.31399/asm.tb.ps.t62440145
EISBN: 978-1-62708-352-2
... in preventing oxidation of an underlying base metal comes from the beneficial exploitation of their use to grow oxide films of controlled thickness in the manufacture of solar cells. In particular, 5 μm (200 μin.) of silver, applied by thermal evaporation, to a clean copper surface permits the growth of Cu 2 O...
Abstract
This chapter considers the materials and processing aspects of soldering and the manner in which these interrelate in the development of joining processes. It discusses the processes involved in eliminating or suppressing metallurgical and mechanical constraints as well as constraints imposed by the components.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 July 2009
DOI: 10.31399/asm.tb.bcp.t52230117
EISBN: 978-1-62708-298-3
... is crushed and pulverized to a fine powder and used to make more pure beryllium carbide shapes by hot pressing at temperatures up to 2000 °C (3630 °F). Early efforts to make beryllium metal by reduction of beryllium oxide with carbon resulted in Be 2 C on firing the mixture at 1950 to 2100 °C (3540 to 3810...
Abstract
This chapter discusses the synthesis of important beryllium compounds, including beryllium borides, beryllium carbide, beryllium carbonates, beryllium carboxylates, beryllium halides, beryllium hydride, beryllium hydroxide, beryllium nitrate, beryllium nitride, beryllium oxalate, beryllium oxide, beryllium oxide carboxylates, beryllium perchlorate, beryllium phosphates, beryllium sulfate, and beryllium sulfide.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 November 2019
DOI: 10.31399/asm.tb.mfadr7.t91110563
EISBN: 978-1-62708-247-1
... for MEMS is [6] , and a classic reference is [7] .) A few wafer bonding methods are most common for MEMS: glass frit, metal-metal thermocompression bonding [8] , and fusion bonding. Glass paste can be screen printed onto the wafer or applied as a stencil. The wafers are aligned and compressed at 350...
Abstract
This chapter discusses the various failure analysis techniques for microelectromechanical systems (MEMS), focusing on conventional semiconductor manufacturing processes and materials. The discussion begins with a section describing the advances in integration and packaging technologies that have helped drive the further proliferation of MEMS devices in the marketplace. It then shows some examples of the top MEMS applications and quickly discusses the fundamentals of their workings. The next section describes common failure mechanisms along with techniques and challenges in identifying them. The chapter also provides information on the testing of MEMS devices. It covers the two common challenges in sample preparation for MEMS: decapping, or opening up the package, without disturbing the MEMS elements; and removing MEMS elements for analysis. Finally, the chapter discusses the aspects of failure analysis techniques that are of particular interest to MEMS.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 July 2000
DOI: 10.31399/asm.tb.fec.t65940233
EISBN: 978-1-62708-302-7
... to I ox,M (normally 50 to 100 mV): (Eq 6.2) I ex , a = I ox , M and I ex,a becomes a direct measure of the oxidation rate, I ox,M , of the metal in this potential range. This linear portion of an experimental curve reveals the Tafel curve of the anodic metal...
Abstract
This chapter discusses the principles and procedures of electrochemical measurements used to investigate corrosion behaviors. It begins by presenting a diagram of a basic potentiostatic circuit, which consists of a working electrode and an auxiliary or counter electrode suspended in an electrolytic solution. It describes how corrosion potentials and current densities are measured and explains how to deal with various sources of error. It also explains how electrochemical impedance measurements are used and describes the underlying theory and procedures in some detail.
Book: Principles of Brazing
Series: ASM Technical Books
Publisher: ASM International
Published: 01 August 2005
DOI: 10.31399/asm.tb.pb.t51230143
EISBN: 978-1-62708-351-5
... in its manifestation. As an example, the degree of surface oxidation of stainless steels at the instant that the filler metal melts can vary from one brazing operation to another, owing to small differences in component preparation, heating rate, and furnace atmosphere. The problem may be avoided...
Abstract
This chapter considers the role of materials in brazing operations and the manner in which they impact on the choice of processing conditions and their optimization. The concepts covered are metallurgical and mechanical constraints, and constraints imposed by the components and their solutions as well as service environment considerations.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240349
EISBN: 978-1-62708-251-8
... expensive coke to be used. The carbon monoxide gas flows up through the blast furnace, removing oxygen from the iron ore and leaving iron. The iron in the ore reduces to metallic iron from iron because the free energies of CO and CO 2 are both lower than that of iron oxide. This greatly increases...
Abstract
This chapter discusses various processes involved in the production of steel from raw materials to finished mill products. The processes include hot rolling, cold rolling, forging, extruding, or drawing. The chapter provides a detailed description of two main furnaces used for making steel: the electric arc furnace and the basic oxygen furnace. It also provides information on the classification and specifications for various steels, namely, plain carbon steels, low-carbon steels, medium-carbon plain carbon steels, and high-carbon plain carbon steels. The chapter concludes with a general overview of the factors influencing corrosion in iron and steel and a brief discussion of corrosion-resistant coatings.
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 June 1988
DOI: 10.31399/asm.tb.eihdca.t65220241
EISBN: 978-1-62708-341-6
..., the laminations should be on the order of 0.38 mm (0.015 in.) each. At 10 kHz, a thickness of 0.20 mm (0.008 in.) is used. The laminations have a highly oxidized or phosphated surface which acts as insulation between the layers, thereby electrically isolating each for maximum efficiency. At RF frequencies...
Abstract
To a large extent, the induction coil and its coupling to the workpiece determine the precise heating pattern that is developed. However, it is often desirable to modify this pattern in order to produce a special heating distribution or to increase energy efficiency. At other times, the high heating rates of induction are needed for processing nonconductors. This chapter describes broad methods of accomplishing such objectives: modification of the field of magnetic induction, use of devices to prevent auxiliary equipment or certain portions of a workpiece from being heated, and techniques to apply heating to electrically nonconductive materials. These methods make use of devices such as flux concentrators, shields, and susceptors. The chapter provides a description of the materials for these devices and guidelines for their application.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 December 2001
DOI: 10.31399/asm.tb.aub.9781627082976
EISBN: 978-1-62708-297-6
Series: ASM Technical Books
Publisher: ASM International
Published: 01 February 2005
DOI: 10.31399/asm.tb.chffa.9781627083003
EISBN: 978-1-62708-300-3
Book Chapter
Series: ASM Technical Books
Publisher: ASM International
Published: 01 August 1999
DOI: 10.31399/asm.tb.lmcs.t66560039
EISBN: 978-1-62708-291-4
.... The world production of apparently simple steels of these types far exceeds that of any other metallic material. This production is overwhelmingly in the form of sheet and strip, and while much is used in apparently simple purposes, some of it is used in very demanding applications, automobile outer panels...
Abstract
This chapter discusses the composition and structure of low-carbon irons and steels, particularly those used in the production of hot-rolled strip. It describes the manufacturing process from the production of ingots to coiling, and it explains how finishing and coiling temperatures affect ferritic grain size and the distribution of cementite particles. It also discusses subsequent processing, including cold rolling and annealing, and the parameters with the greatest impact on grain size and microstructure. In addition, it describes the production of enameling irons, the benefits of high-temperature heat treatments, and the effects of quench and strain aging.