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Book Chapter
Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 October 2011
DOI: 10.31399/asm.tb.mnm2.t53060247
EISBN: 978-1-62708-261-7
... C) P Mottled Solidification Malleable iron Temper graphite. Irregularly shaped nodules of graphite F, P Silver-gray Heat treatment Austempered ductile iron Spheroidal graphite B, AF Silver-gray Heat treatment (a) F, ferrite; P, pearlite; A, austenite; M, martensite; B...
Abstract
The commercial relevance of cast irons is best understood in the context of the iron-carbon phase diagram, where their composition places them near the eutectic point, which sheds light on why they melt at lower temperatures than steel and why they can be cast into more intricate shapes. This chapter examines these unique properties and how they are derived. It begins by describing the basic metallurgy of cast iron, focusing on the eutectic reaction. It explains how to control the reaction and thus properties of cast iron by overcooling and inoculation. The chapter also discusses composition, microstructure, heat treatments, and the classification and casting characteristics of white, gray, ductile, malleable, compacted graphite, and special cast irons.
Book Chapter
Engineering of Malleable Iron Castings
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 January 2022
DOI: 10.31399/asm.tb.isceg.t59320157
EISBN: 978-1-62708-332-4
... Alloyed iron, liquid quench → Martensitic microstructure Alloyed iron, salt quench → Bainitic microstructure Fig. 8.2 Graphite clusters. Source: Ref 2 Fig. 8.3 Malleable iron process schematic. Source: Ref 1 Other controls are: The increase in manganese...
Abstract
Malleable iron has unique properties that justify its application in the metal working industry. This chapter discusses the advantages, limitations, and mechanical properties of malleable iron; provides a description of the malleabilization process; and presents manufacturing guidelines for malleable iron castings.
Book Chapter
Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 June 2008
DOI: 10.31399/asm.tb.emea.t52240453
EISBN: 978-1-62708-251-8
... diffusion and carbide decomposition. Stage 2—Cooling Austenite is transformed into ferrite, pearlite, or martensite, depending on the cooling cycle after graphitization. Ferritic Malleable Iron After the first-stage graphitization treatment, the casting is fast cooled to between 730 and 760 °C...
Abstract
The properties of cast iron are determined primarily by the form of carbon they contain, which in turn, is controlled by modifying compositions and cooling rates during casting. Certain alloys (such as Si, Al, Ni, Co, and Cu) promote graphite formation, while others (such as S, V, Cr, Sn, Mo, and Mn) promote the formation of cementite. This chapter examines the relative potencies of these alloys and their effect on microstructure. It covers the five most common commercial cast irons, including white, gray, ductile, malleable, and compacted graphite, describing their compositional ranges, distinguishing features, advantages, limitations, and applications.
Book Chapter
Malleable Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2001
DOI: 10.31399/asm.tb.aub.t61170100
EISBN: 978-1-62708-297-6
... malleable cast iron. Subsequent variations in post-annealing heat treatments can produce malleable irons with ferritic, pearlitic, or martensitic microstructures. Fig. 1 Microstructure of a typical malleable cast iron showing graphite in the form of temper carbon. 4% picral etch. 250× Annealing...
Abstract
This article explains how malleable iron is produced and how its microstructure and properties differ from those of gray and ductile iron. Malleable iron is first cast as white iron then annealed to convert the iron carbide into irregularly shaped graphite particles called temper carbon. Although malleable iron has largely been replaced by ductile iron, the article explains that it is still sometimes preferred for thin-section castings that require maximum machinability and wear resistance. The article also discusses the annealing and alloying processes by which these properties are achieved.
Book Chapter
Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 August 2018
DOI: 10.31399/asm.tb.msisep.t59220583
EISBN: 978-1-62708-259-4
..., and examines the growth mechanisms and structural details that set them apart. It also discusses the formation of compacted (vermicular) graphite and malleable iron, and compares and contrasts the composition, properties, and heat treatment of whiteheart and blackheart malleable types. chilled cast iron...
Abstract
This chapter discusses the effect of composition and cooling rate on the microstructure and properties of cast irons and explains how they differ from steel. It describes the conditions under which white, gray, mottled (chilled), and nodular (ductile) cast irons are produced, and examines the growth mechanisms and structural details that set them apart. It also discusses the formation of compacted (vermicular) graphite and malleable iron, and compares and contrasts the composition, properties, and heat treatment of whiteheart and blackheart malleable types.
Book Chapter
Introduction to Steels and Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 March 2002
DOI: 10.31399/asm.tb.mgppis.t60400001
EISBN: 978-1-62708-258-7
... Abstract This chapter introduces the metallographer to the various types of steels and cast irons and explains how they are classified and defined. Classification and designation details are provided for plain carbon steels, alloy steels, and gray, white, ductile, and malleable cast irons...
Abstract
This chapter introduces the metallographer to the various types of steels and cast irons and explains how they are classified and defined. Classification and designation details are provided for plain carbon steels, alloy steels, and gray, white, ductile, and malleable cast irons.
Image
Two possible heat treatment cycles to produce blackheart malleable iron hav...
Available to PurchasePublished: 01 August 2018
Fig. 17.112 Two possible heat treatment cycles to produce blackheart malleable iron having either pearlite or pearlite + martensite structures. After graphitization, controlled cooling takes the austenite to approximately 870 °C (1600 °F). (a) Still or forced air cooling, or (b) homogenization
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Book Chapter
Alteration of Microstructure
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 March 2002
DOI: 10.31399/asm.tb.mgppis.t60400049
EISBN: 978-1-62708-258-7
...-pearlite, that is, the bull’s-eye microstructure, or a martensitic-pearlitic matrix (produced by quenching after the first-stage anneal). The metallographer must be able to disinguish malleable iron by the appearance of the graphite. The graphite is easily distinguished from the graphite flakes formed...
Abstract
Microstructures can be altered intentionally or unintentionally. In some cases, metallographers must diagnose what may have happened to the steel or cast iron based on the microstructural details. This chapter discusses how microstructure in steels and cast irons can be intentionally altered during heat treatment, solidification, and deformation (hot and cold working). Some specific examples are then shown to illustrate what can go wrong through unintentional changes in microstructure, for example, the loss of carbon from the surface of the steel by the process known as decarburization or the buildup of brittle carbides on the grain boundaries of an austenitic stainless steel by the process known as sensitization.
Book Chapter
Tribological Properties of Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 30 April 2021
DOI: 10.31399/asm.tb.tpsfwea.t59300179
EISBN: 978-1-62708-323-2
..., the situation is even more complex, in that, in addition to the basic types (gray, ductile, white, ADT, and malleable), each can have different graphite concentrations and morphologies; each can have different matrices—ferrite, pearlite, martensite; each type of cast iron is available in different strengths...
Abstract
This chapter covers the friction and wear behaviors of cast irons. It describes the microstructure and metallurgy of gray, white, malleable, and ductile cast irons, their respective tensile properties, and their suitability for applications involving friction, various types of erosion, and adhesive and abrasive wear.
Book Chapter
Origin of Microstructure
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 March 2002
DOI: 10.31399/asm.tb.mgppis.t60400023
EISBN: 978-1-62708-258-7
... is martensite. 2% nital etch. 500× Cementite Cementite is iron carbide, that is, a compound of iron and carbon, Fe 3 C. The name cementite comes from cementation steel, which was an early process used to produce high-carbon steel through carburization, by which carbon is absorbed into the steel...
Abstract
This chapter introduces the basic ferrous physical metallurgy principles that need to be understood by the metallographer. The discussion focuses on the variations in microstructures that are generated as a result of the phase transformations that occur during both heat treatment (as in steels) and solidification (as in cast irons). The chapter describes how the development of the iron-carbon phase diagram, coupled with the understanding of the kinetics of phase transformations through the use of isothermal transformation diagram, were breakthroughs in the advancement of ferrous physical metallurgy. Several examples of the morphological features of microstructural constituents in steels are also presented.
Book Chapter
Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 November 2007
DOI: 10.31399/asm.tb.smnm.t52140175
EISBN: 978-1-62708-264-8
... Abstract This chapter discusses the composition, properties, microstructure, grain formation, and fracture behavior of gray, white, ductile, and malleable cast iron and how these critical factors are affected when iron is heated to different temperatures prior to or during solidification...
Abstract
This chapter discusses the composition, properties, microstructure, grain formation, and fracture behavior of gray, white, ductile, and malleable cast iron and how these critical factors are affected when iron is heated to different temperatures prior to or during solidification.
Book Chapter
Influence of Microstructure on Mechanical Properties and Performance
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 January 2022
DOI: 10.31399/asm.tb.isceg.t59320031
EISBN: 978-1-62708-332-4
... properties is indicated in the lower part of the diagram. Chapter 8 , “ Engineering of Malleable Iron Castings ,” in this book details the process, microstructure, and applications. Fig. 4.8 Process variables that influence graphite shape and microstructure. Source: Ref 7 4.10.1 Carbon...
Abstract
This chapter discusses the crystal structures of steel and cast iron, the iron-iron carbide equilibrium diagram, microconstituents or phases in the iron-iron carbide phase diagram, the iron-carbon carbide-silicon equilibrium diagram of cast irons, and the influence on microstructure by base elements and alloying elements. Graphitization, cooling rates, and heat treatment effects are covered. There also is discussion on inoculation benefits, flake graphite types and typical applications, evolution of cast iron types, ASTM specification A247 for graphite shapes, and selection of the best molding process. A large table lists typical material choices for various applications.
Book Chapter
Heat Treating of Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 March 2006
DOI: 10.31399/asm.tb.pht2.t51440207
EISBN: 978-1-62708-262-4
... relieving, annealing, normalizing, surface hardening, quenching, martempering, austempering, and flame and induction hardening. annealing austempering carbon equivalent ductile cast iron flame hardening gray cast iron induction hardening malleable cast iron martempering normalizing quenching...
Abstract
This chapter is a detailed account of heat treating techniques for cast irons (gray and ductile), providing the reader with a basic understanding of the differences among various types of cast irons and the concept of carbon equivalent. The types of heat treatments discussed are stress relieving, annealing, normalizing, surface hardening, quenching, martempering, austempering, and flame and induction hardening.
Book Chapter
Reference Tables
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2004
DOI: 10.31399/asm.tb.tt2.t51060273
EISBN: 978-1-62708-355-3
... steels, standard austenitic grades; wrought 200 29 193 28 Stainless steels, standard ferritic grades; wrought 200 29 . . . . . . Stainless steels, standard martensitic grades; wrought 200 29 . . . . . . Boron-aluminum composites 193 28 . . . . . . Malleable irons, pearlitic...
Abstract
This chapter contains tables listing room-temperature tensile yield strength comparisons of metals and plastics and room-temperature tensile modulus of elasticity comparisons of various materials.
Book Chapter
Glossary of Practical Heat Treating Terms
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 30 April 2024
DOI: 10.31399/asm.tb.phtpp.t59380235
EISBN: 978-1-62708-456-7
... cool the surface, leaving a shallow martensitic layer. latent heat Thermal energy absorbed or released when a substance undergoes a phase change. ledeburite The eutectic of the iron-carbon system, the constituents being austenite and cementite. The austenite decomposes into ferrite and cementite...
Abstract
The appendix provides a glossary of practical heat treating terms.
Series: ASM Technical Books
Publisher: ASM International
Published: 30 April 2024
DOI: 10.31399/asm.tb.phtpp.9781627084567
EISBN: 978-1-62708-456-7
Book Chapter
Heat Treatment of Cast Irons
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 31 December 2020
DOI: 10.31399/asm.tb.phtbp.t59310331
EISBN: 978-1-62708-326-3
... microstructural and mechanical properties requires heat treatment in addition to the as-cast thermal cycle. Some types of iron castings also are routinely heat treated as a regular part of their production process. For example, malleable iron castings are subjected to a malleablizing treatment; the highest...
Abstract
Cast irons, like steels, are iron-carbon alloys but with higher carbon levels than steels to take advantage of eutectic solidification in the binary iron-carbon system. Like steel, heat treatment of cast iron includes stress relieving, annealing, normalizing, through hardening, and surface hardening. This chapter introduces solid-state heat treatment of iron castings, covering general considerations for heat treatment and discussing the processes, advantages, and disadvantages of heat treatment of cast iron.
Book Chapter
Tribological Properties of Steels
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 30 April 2021
DOI: 10.31399/asm.tb.tpsfwea.t59300199
EISBN: 978-1-62708-323-2
... forms 8.1 Introduction Steel, as we know it, did not appear in commercial use until the invention of the Bessemer furnace in 1850 (or thereabouts). Cast irons existed, but they did not have the malleability of steel. Steel is an iron carbon alloy with carbon content generally below 2%; cast...
Abstract
This chapter covers the friction and wear behaviors of carbon, alloy, and tool steels. It begins a review of commercially available shapes and forms. It then describes the metallurgy and microstructure of various designations and grades of each type of steel and explains how it affects their performance in adhesive and abrasive wear applications and in environments where they are subjected to solid particle, droplet, slurry, and cavitation erosion and fretting damage.
Book Chapter
Heat Treating Basics
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 August 2015
DOI: 10.31399/asm.tb.piht2.t55050093
EISBN: 978-1-62708-311-9
... Malleable iron contains compact nodules of graphite flakes in the form known as temper carbon. As opposed to the spheroidal nodules found in ductile cast iron, these nodules are somewhat irregular aggregates. Numbers such as 40010, as shown in Table 5.3 , classify the pearlitic and martensitic ASTM grades...
Abstract
This chapter covers the fundamentals of heat treating. It begins with a review of the composition, classification, and properties of iron and steel, the phases of the iron-carbon system, and the basic types of heat treatments. It then discusses the topics of hardness and hardenability, the role of carbon in the hardening of steels, the process of austenitization, and the influence of cooling rate on subsequent transformations. The chapter also explains how induction heating affects residual stress, distortion, and grain size.
Series: ASM Technical Books
Publisher: ASM International
Published: 01 January 2022
DOI: 10.31399/asm.tb.isceg.9781627083324
EISBN: 978-1-62708-332-4
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