This chapter discusses the construction, interpretation, and use of ternary phase diagrams. It begins by examining a hypothetical phase space diagram and several corresponding two-dimensional plots. It then describes one of the most basic tools of metallurgy, the Gibbs triangle, and explains how to construct tie lines to analyze intermediate compositions and phases. It also discusses the use of three-dimensional temperature-composition diagrams, three- and four-phase equilibrium phase diagrams, and binary and ternary phase diagrams associated with the iron-chromium-nickel alloy system.

Isothermal and continuous cooling transformation (CT) diagrams help users map out diffusion-controlled phase transformations of austenite to various mixtures of ferrite and cementite. This chapter discusses the application as well as limitations of these engineering tools in the context of heat treating eutectoid, hypoeutectoid, and proeutectoid steels. It also provides references to large collections of transformation diagrams and includes several diagrams that plot quenching and hardening transformations as a function of bar diameter.

Gas-metal reactions can have a significant impact on metals and alloys, affecting their properties (during processing) and accelerating service failures, particularly in hot, corrosive environments. This chapter discusses the kinetics of gas-metal reactions and how they are driven by Gibbs energy changes. It plots the energy of formation for many important metal oxides and explains how to construct isothermal stability diagrams to analyze complex reactions involving metals, alloys, and gases containing more than one reactive component.

This appendix discusses the general characteristics, composition, phase transformations, and properties of commercial stainless steels used for making high-quality knives.

Stainless steels derive their name from their corrosion-resisting properties first observed in 1912. Two groups, working independently, concurrently discovered what came to be known as austenitic and ferritic stainless steels. Martensitic and precipitation-hardened stainless steels would be developed later. This chapter discusses each of these four major types of stainless steel and their respective compositions, properties, and uses. It explains how alloying, heat treating, and various hardening processes affect corrosion performance, and includes a detailed discussion on the optimization of martensitic stainless steels for cutlery applications.

This chapter explains why it is sometimes necessary to separate inelastic from elastic strains and how to do it using one of two methods. It first discusses the direct calculation of strain-range components from experimental data associated with large strains. It then explains how the method can be extended to the treatment of very low inelastic strains by adjusting tensile and compressive hold periods and continuous cycling frequencies. The chapter then begins the presentation of the second approach, called the total strain-range method, so named because it combines elastic and inelastic strain into a total strain range. The discussion covers important features, procedures, and correlations as well as the use of models and the steps involved in predicting thermomechanical fatigue (TMF) life. It also includes information on isothermal fatigue, bithermal creep-fatigue testing, and the predictability of the method for TMF cycling.

This chapter addresses the concept of hardenability by first describing the basic hardening process for steel, starting with austenitization followed by quenching and tempering. The context also serves to clarify the difference between hardenability and hardness, which are often confused. Most of the information in the chapter is of a practical nature, covering application-oriented topics such as isothermal transformation (IT) and continuous transformation (CT) diagrams which are used to predict and control the rate of formation of ferrite, pearlite, and bainite. The chapter also discusses the effect of grain size and alloying elements and explains how Jominy end quench testing is used to evaluate the hardenability of steel.

This chapter provides an overview of the thermodynamics of extrusion. It begins by presenting a thermodynamic model of the extrusion process expressed in the form of finite difference equations. It then explains how the model accounts for multiple sources of heat generation, the influence of principal variables on temperature rise, and different types of temperature measurements. It also discusses the benefits of isothermal extrusion and how it achieves consistent mechanical properties in extruded components.

This chapter compares and contrasts the high-temperature behaviors of metals and composites. It describes the use of creep curves and stress-rupture testing along with the underlying mechanisms in creep deformation and elevated-temperature fracture. It also discusses creep-life prediction and related design methods and some of the factors involved in high-temperature fatigue, including creep-fatigue interaction and thermomechanical damage.

This chapter discusses some of the methods and measurements used to construct phase diagrams. It explains how cooling curves were widely used to determine phase boundaries, and how equilibrated alloys examined under controlled heating and cooling provide information for constructing isothermal and vertical sections as well as liquid projections. It also explains how diffusion couples provide a window into local equilibria and identifies typical phase diagram construction errors along with problems stemming from phase-boundary curvatures and congruent transformations.

This chapter focuses on short-term tensile testing at high temperatures. It emphasizes one of the most important reasons for conducting hot tensile tests: the determination of the hot working characteristics of metallic materials. Two types of hot tensile tests are discussed in this chapter, namely, the Gleeble test and the conventional isothermal hot-tensile test. The discussion covers equipment used and testing procedures for the Gleeble test along with information on hot ductility and strength data from this test. The chapter describes the stress-strain curves, material coefficients, and flow behavior determined in the isothermal hot tensile test. It also describes three often-overlapping stages of cavitation during tensile deformation, namely, cavity nucleation, growth of individual cavities, and cavity coalescence.

This chapter examines the isothermal phase transformations of the iron-carbide system. The discussion includes the formation of ferritic, eutectoid, hypoeutectoid, hypereutectoid, bainitic, and martensitic microstructures as well as their properties, composition, and metallurgy. The use of time-temperature-transformation (TTT) diagrams in understanding the phase transformations and the changes in the isothermal transformation curves due to the addition of carbon and other alloying elements are also discussed.

Annealing, a heat treatment process, is used to soften metals that have been hardened by cold working. This chapter discusses the following three distinct processes that can occur during annealing: recovery, recrystallization, and grain growth. The types of processes that occur during recovery are the annihilation of excess point defects, the rearrangement of dislocations into lower-energy configurations, and the formation of subgrains that grow and interlock into sub-boundaries. The article also discusses the main factors that affect recrystallization. They are temperature and time; degree of cold work; purity of the metal; original grain size; and temperature of deformation. The types of grain growth discussed include normal or continuous grain growth and abnormal or discontinuous grain growth.

This chapter examines two important strengthening mechanisms, martensitic and bainitic transformations, both of which occur under nonequilibrium cooling conditions. It explains how time-temperature-transformation diagrams are constructed and how they are used to understand and control the formation of martensite and bainite in steel and other alloys. It describes the morphology of both types of structures, the factors that influence their formation, how they respond to tempering processes, and their effect on mechanical properties and behaviors. It also discusses the role of transformation hysteresis in shape memory alloys.

This appendix provides a brief introduction to Thermo-Calc, explains what it is, and lists its uses. Instructions for accessing a demonstration version of the software are also provided.