A brittle fracture occurs at stresses below the material's yield strength (i.e., in the elastic range of the stress-strain diagram). This chapter focuses on brittle fracture in metals and, more specifically, ferrous alloys. It lists the factors that must all be present simultaneously in order to cause brittle fracture in a normally ductile steel. The chapter then discusses the macroscale characteristics and microstructural aspects of brittle fracture. A summary of the types of embrittlement experienced by ferrous alloys is presented. The chapter concludes with a brief section providing information on mixed fracture morphology.

This article presents a general overview of outdoor weather aging factors, their effects on plastic materials, and the accelerated test methods that can be used to estimate the reaction of a plastic component during actual use. Weather and radiation factors that contribute to degradation in plastics include temperature variations, moisture, sunlight, oxidation, microbiologic attack, and other environmental elements. The article also describes the tests used to predict the behavior of a plastic material to outdoor exposure, discussing the use of xenon arc lamp for the weatherometer and fadeometer and the use of fluorescent sunlamp in test devices.

Although zirconium resists stress-corrosion cracking (SCC) where many alloys fail, it is susceptible in Fe3+- and Cu2+-containing solutions, concentrated HNO3, halogen vapors, mercury, cesium, and CH3OH + halides. This chapter explains how composition, texture, stress levels, and strain rate affect the SCC behavior of zirconium and its alloys. It describes environments known to induce SCC, including aqueous solutions, organic liquids, hot and fused salts, and liquid metals. It also discusses cracking mechanisms and SCC prevention and control techniques.

Irradiation-assisted stress-corrosion cracking (IASCC) has been a topic of engineering interest since it was first reported in the 1960s, having been observed in stainless steel cladding on light water reactor fuel elements. This chapter summarizes the results of decades of investigation, showing that IASCC can essentially be defined as the intergranular cracking of austenitic alloys in high-temperature water, where both the material and its environment have been altered by radiation. Of the many interactions that can occur when metals and water are exposed to radiation, the international consensus is that the three with the greatest impact on crack growth rates are the formation of material defects, radiation-induced segregation, and chemical reactions that increase the corrosion potential of water. The chapter discusses each of these in great detail, and includes information on predictive modeling as well.

The toughness of a material is its ability to absorb energy in the form of plastic deformation without fracturing. It is thus a measure of both strength and ductility. This chapter describes the fracture and toughness characteristics of metals and their effect on component lifetime and failure. It begins with a review of the ductile-to-brittle transition behavior of steel and the different ways to measure transition temperature. It then explains how to predict fracture loads using linear-elastic fracture mechanics and how toughness is affected by temperature and strain rate as well as grain size, inclusion content, and impurities. It also presents the theory and use of elastic-plastic fracture mechanics and discusses the causes, effects, and control of temper embrittlement in various types of steel.

This chapter takes a practical approach to the problem of stress-corrosion cracking (SCC) in stainless steels, explaining how different application environments affect different grades of stainless steel. It describes the causes of stress-corrosion cracking in chloride, caustic, polythionic acid, and high-temperature environments and the correlating effects on austenitic, ferritic, duplex, martensitic, and precipitation hardening stainless steels and nickel-base alloys. It also discusses the contributing effects of sensitization and hydrogen embrittlement and the role of composition, microstructure, and thermal history. Sensitization is particularly detrimental to austenitic stainless steels, and in many cases, eliminating it will eliminate the susceptibility to SCC. The chapter includes an extensive amount of data and illustrations.

This chapter discusses the causes and effects of ductile and brittle fracture and their key differences. It describes the characteristics of ductile fracture, explaining how microvoids develop and coalesce into larger cavities that are rapidly pulled apart, leaving bowl-shaped voids or dimples on each side of the fracture surface. It includes SEM images showing how the cavities form, how they progress to final failure, and how dimples vary in shape based on loading conditions. The chapter, likewise, describes the characteristics of brittle fracture, explaining why it occurs and how it appears under various levels of magnification. It also discusses the ductile-to-brittle transition observed in steel, the characteristics of intergranular fracture, and the causes of embrittlement.

Fracture is the separation of a solid body into two or more pieces under the action of stress. Fracture can be classified into two broad categories: ductile fracture and brittle fracture. Beginning with a comparison of these two categories, this chapter discusses the nature and causes of these failure modes. Some body-centered cubic and hexagonal close-packed metals, and steels in particular, exhibit a ductile-to-brittle transition when loaded under impact and the chapter describes the use of notched bar impact testing to determine the temperature at which a normally ductile failure transitions to a brittle failure. The discussion then covers the Griffith theory of brittle fracture and the formulation of fracture mechanics. Procedures for determination of the plane-strain fracture toughness are subsequently covered. Finally, the chapter describes the effects of microstructural variables on fracture toughness of steels, aluminum alloys, and titanium alloys.

This chapter focuses on stress-corrosion cracking (SCC) of metals and their alloys. It is intended to familiarize the reader with the phenomenological and mechanistic aspects of stress corrosion. The phenomenological description of crack initiation and propagation describes well-established experimental evidence and observations of stress corrosion, while the discussions on mechanisms describe the physical process involved in crack initiation and propagation. Several parameters that are known to influence the rate of crack growth in aqueous solutions are presented, along with important fracture features.

Nickel and nickel-base alloys are specified for many applications, such as oil and gas production, power generation, and chemical processing, because of their resistance to stress-corrosion cracking (SCC). Under certain conditions, however, SCC can be a concern. This chapter describes the types of environments and stress loads where nickel-base alloys are most susceptible to SCC. It begins with a review of the physical metallurgy of nickel alloys, focusing on the role of carbides and intermetallic phases. It then explains how SCC occurs in the presence of halides (such as chlorides, bromides, iodides, and fluorides), sulfur-bearing compounds (such as H2S and sulfur-oxyanions), high-temperature and supercritical water, and caustics (such as NaOH), while accounting for temperature, composition, microstructure, properties, environmental contaminants, and other factors. The chapter also discusses the effects of hydrogen embrittlement and provides information on test methods.

This chapter discusses the conditions and sequence of events that lead to stress-corrosion cracking (SCC) and the mechanisms by which it progresses. It explains that the stresses involved in SCC are relatively small and, in most cases, work in combination with the development of a surface film. It describes bulk and surface reactions that contribute to SCC, including dissolution, mass transport, absorption, diffusion, and embrittlement, and their role in crack nucleation and growth. It also discusses crack tip chemistry, grain-boundary interactions, and the effect of stress-intensity on crack propagation rates, and describes several mechanical fracture models, including corrosion tunnel, film-induced cleavage, and tarnish rupture models.

Composite systems for cryogenic applications are discussed in this chapter. This chapter emphasizes filamentary-reinforced composites because they are the most widely used composite materials. It begins with a discussion on the approach to designing and fabricating with low-pressure laminate composites. This is followed by a section providing an overview of the materials in modern cryogenic technology. Then, the chapter describes the effect of cryogenic temperatures on materials properties; it also introduces the various joining techniques developed for composite materials. The effects of radiation on the properties of the materials are covered as well as the processes involved in testing laminates at cryogenic temperatures. Finally, the chapter provides information available on concrete aggregate composites.

This chapter covers the fatigue and fracture behaviors of ceramics and polymers. It discusses the benefits of transformation toughening, the use of ceramic-matrix composites, fracture mechanisms, and the relationship between fatigue and subcritical crack growth. In regard to polymers, it covers general characteristics, viscoelastic properties, and static strength. It also discusses fatigue life, impact strength, fracture toughness, and stress-rupture behaviors as well as environmental effects such as plasticization, solvation, swelling, stress cracking, degradation, and surface embrittlement.

This chapter presents definitions of terms related to the metallurgy and metallographic study of irons and steels.

This chapter presents topics pertaining to resistance at cryogenic temperatures: measurement, the resistive mechanisms, and available data. The chapter also presents brief descriptions of the various mechanisms that are operative in producing resistance at low temperatures. The alloys discussed are the nondilute mixtures of metals. An introduction to low-temperature electrical properties of specific metals and alloys is included.

This appendix contains tables that list the composition and capabilities of etchants that reveal the microstructure of metals and alloys, including aluminum, chromium, cobalt, copper, lead, magnesium, molybdenum, nickel, niobium, palladium, platinum, radioactive metals, rare earth metals, rhenium, rhodium, selenium, tellurium, silicon, silver, tantalum, tin, titanium, tungsten, vanadium, and zinc, as well as carbides, oxides, and nitrides.

Fracture mechanics is the science of predicting the load-carrying capabilities of cracked structures based on a mathematical description of the stress field surrounding the crack. The fundamental ideas stem from the work of Griffith, who demonstrated that the strain energy released upon crack extension is the driving force for fracture in a cracked material under load. This chapter provides a summary of Griffith’s work and the subsequent development of linear elastic and elastic-plastic fracture mechanics. It includes detailed illustrations and examples, familiarizing readers with the steps involved in determining strain energy release rates, stress intensity factors, J-integrals, R-curves, and crack tip opening displacement parameters. It also covers fracture toughness testing methods and the effect of measurement variables.