This chapter presents the history of stainless steel and provides an overview of the key concepts discussed in this book. This book covers a broad spectrum of historical events, many of which have not been touched upon in other works on stainless steel. It includes the discoveries of the various metallic elements that are used in the various alloys of stainless steel and discusses numerous experiments conducted during the 19th century with iron-base alloys containing chromium and carbon.

This chapter describes important requirements for ferrous and nonferrous alloys used for gears. Wrought surface-hardening and through-hardening carbon and alloy steels are the most widely used of all gear materials and are emphasized in this chapter. The processing characteristics of gear steels and the bending fatigue strength and properties of carburized steels are reviewed. In addition to wrought steels, the chapter provides information on the other iron-base alloys that are used for gears, namely cast carbon and alloy steels, gray and ductile cast irons, powder metallurgy irons and steels, stainless steels, and tool steels. In terms of nonferrous alloys, the chapter addresses copper-base alloys, die cast aluminum alloys, zinc alloys, and magnesium alloys.

This chapter discusses the phase transformations of peritectic alloy systems. It describes the processes involved with equilibrium and nonequilibrium freezing, the mechanisms of peritectic formation, and the resulting microstructures. It also discusses the formation of peritectic structures in iron-base alloys and multicomponent systems.

This chapter discusses the processes involved in heat treating of stainless steels, providing information on the classification, chemical compositions, and corrosion resistance of stainless steels and the effect of specific elements on the characteristics of iron-base alloys. Five groups of stainless steels are discussed: austenitic, ferritic, martensitic, precipitation-hardening, and duplex grades. The chapter also describes the heat treatment conditions that should be maintained for processing of stainless steels.

Austenitic stainless steels are iron-base alloys containing more than 50% Fe, 15 to 26% Cr, and less than 45% Ni. This chapter provides a discussion on the types, compositions, microstructures, processing, deformation mechanism, mechanical properties, formability, and special attributes of austenitic stainless steels.

This chapter discusses the engineering significance of steel and briefly describes its chemical composition, crystal structure, Fe-C phases, and associated characterization techniques.

Amorphous alloys, because of their lack of crystallographic slip planes, are assumed to be insensitive to the selective corrosion attack that causes stress-corrosion cracking (SCC) in crystalline alloys. However, under certain conditions, melt-spun amorphous alloys have proven vulnerable to SCC due to hydrogen embrittlement. This chapter presents findings from several studies on this phenomenon, describing test conditions as well as cracking and fracture behaviors. It also discusses the effect of deformation on corrosion behavior, particularly for alloys without strongly passivating elements.

This chapter provides a brief overview of nickel-iron-base, cobalt-base, and nickel-base superalloys, discussing their basic metallurgy and defining characteristics.