Steels for hot-work applications, designated as group H steels in the AISI classification system, have the capacity to resist softening during long or repeated exposures to high temperatures needed to hot work or die cast other materials. These steels are subdivided into three classes according to the alloying approach: chromium hot-work steels, tungsten hot-work steels, and molybdenum hot-work steels. This chapter discusses the composition, characteristics, applications, advantages, and disadvantages of each of these steels.

There is a fairly wide variety of different tool steels for different applications. The American Iron and Steel Institute (AISI) classification of tool steels includes seven major categories: water-hardening tool steels, shock-resisting tool steels, cold work tool steels, hot work tool steels, low-alloy special-purpose tool steels, mold tool steels, high-speed tool steels, and powder metallurgy tool steels. This chapter provides discusses the manufacturing process, composition, properties, types, and applications of these tool steels and other cutting tool materials, such as cemented carbides. It also describes the methods of applying coatings to cutting tools to improve tool life.

This chapter focuses on the failure aspects of tool steels. The discussion covers the classification, chemical composition, main characteristics, and several failures of tool steels and their relation to heat treatment. The tool steels covered are hot work, cold work, plastic mold, and high-speed tool steels.

Tool steels represent a small, but very important, segment of the total production of steel. Their principal use is for tools and dies that are used in the manufacture of commodities. For the most part, the processes used for heat treating carbon and alloy steels are also used for heat treating tool steels, that is, annealing, austenitizing, tempering, and so forth. This chapter focuses on these heat treating processes of tool steels. Classification and approximate compositions and heating treating practices of some principal types of tool steels are provided. The steel types discussed include water-hardening; shock-resisting; oil-hardening cold-work; air-hardening, medium-alloy cold-work; high-carbon, high-chromium cold-work; low-alloy, special-purpose; mold; hot-work; and high-speed tool steels.

Tools steels are defined by their wear resistance, hardness, and durability which, in large part, is achieve by the presence of carbide-forming alloys such as chromium, molybdenum, tungsten, and vanadium. This chapter describes the alloying principles employed in various tool steels, including high-speed, water-hardening, shock-resistant, and hot and cold work tool steels. It discusses the influence of alloy design on the evolution of microstructure and properties during solidification, heat treating, and hardening operations. It also describes critical phase transformations and the effects of partitioning, precipitation, segregation, and retained austenite.

The several specific grades or compositions of tool steels have evolved over time and have been organized into useful groupings. This chapter presents the AISI classification system for tool steels, which categorizes tool steels by their alloying, applications, or heat treatment, and briefly describes the characteristics of each major group. It discusses selection criteria for tool steels, along with examples.

The possible classification for tool steels is their division into four groups according to their final application: hot-worked, cold-worked, plastic mold, and high-speed tool steels. This chapter mainly follows such division by application, but the grade nomenclatures used here are primarily from AISI. It presents the classification of tool steels and discusses the principles and processes of tool steel heat treating, namely normalizing, annealing, hardening, and tempering. Various factors associated with distortion in several tool steels are also covered. The chapter discusses the composition, classification, and properties of unalloyed and low-alloy cold-worked tool steels; medium and high-alloy cold-worked tool steels; and 18% nickel maraging steels.