This chapter discusses the effects of metallurgical factors on the corrosion resistance of magnesium alloys. The factors are chemical composition, heat treating, grain size, and cold-work effects. The chapter describes the causes of corrosion failures in magnesium alloys, namely heavy-metal contamination, blast residues, flux inclusions, and galvanic attack.

Superalloys are susceptible to damage from a variety of surface contaminants. They may also require special surface finishes for subsequent processing steps such as coating applications. This chapter describes some of the cleaning and finishing procedures that have been developed for superalloys and how they work. It discusses the effect of metallic contaminants, tarnish, oxide, and scale and how they can be detected and removed. It also discusses chemical and mechanical surface finishing techniques and where they are used, and presents several application examples.

Magnesium, by volume, is two-thirds the weight of aluminum and one-quarter the weight of steel. It also has good damping capacity, giving it an edge over other metals in high-vibration environments. This chapter discusses the basic metallurgy, alloy designations, compositions, and mechanical properties of cast and wrought magnesium alloys. It also describes the processes used to produce magnesium parts, the causes and effects of corrosion, and the use of protective coatings and treatments.

This chapter discusses the various methods used to join titanium alloy assemblies, focusing on welding processes and procedures. It explains how welding alters the structure and properties of titanium and how it is influenced by composition, surface qualities, and other factors. It describes several welding processes, including arc welding, resistance welding, and friction stir welding, and addresses related issues such as welding defects, quality control, and stress relieving. The chapter also covers mechanical fastening techniques along with adhesive bonding and brazing.

This article discusses the weldability and fusion weld properties of refractory metal alloys. The alloys discussed include tantalum, niobium, rhenium, molybdenum, and tungsten.

This article examines the composition and properties of magnesium and its alloys. It discusses alloy and temper designations, applications and product forms, and commercial alloy systems, and explains how alloying elements affect physical and mechanical properties, processing characteristics, and corrosion behaviors.

This chapter covers the welding characteristics of titanium along with the factors that determine which welding method is most appropriate for a given application. It discusses the joinability of titanium alloys, the effect of heat on microstructure, the cause of various defects, and the need for contaminant-free surfaces and atmospheres. It describes common forms of fusion, arc, and solid-state welding along with the use of filler metals, shielding gases, and stress-relief treatments. It also discusses the practice of titanium brazing and the role of filler metals.

This chapter discusses three related corrosion mechanisms, galvanic, deposition, and stray-current corrosion, explaining why they occur and how they affect the corrosion process. It includes information on testing and prevention methods along with examples of the type of damage associated with these corrosion mechanisms.

This chapter describes various units and process streams that are often susceptible corrosion inhibitors in crude oil refineries, discusses the types and applications of corrosion inhibitors, and provides some information on corrosion monitoring techniques used at refineries.

Cleaning procedures serve to remove scale, tarnish films, and other contaminants that form or are otherwise deposited on the surface of titanium during processing operations such as hot working and heat treatment. This chapter explains what makes titanium susceptible to the formation of scale and how it can be removed via belt grinding, abrasive blasting, and molten salt descaling baths. It also discusses the role of acid pickling, barrel finishing, polishing, and buffing as well as the use of chemical conversion coatings and protective platings.

This chapter covers regulatory requirements, safe handling practices, hazard analysis and control, dismantling and decommissioning, and waste disposal. It also includes references for additional information on government regulations.

Most integrated titanium mills have primary working equipment designed specifically for titanium. This chapter describes the forging, rolling, and extruding equipment used to produce titanium mill products and sheds light on the corresponding process, structure, property relationships.

In forgings of both ferrous and nonferrous metals, the flaws that most often occur are caused by conditions that exist in the ingot, by subsequent hot working of the ingot or the billet, and by hot or cold working during forging. The inspection methods most commonly used to detect these flaws include visual, magnetic particle, liquid penetrant, ultrasonic, eddy current, and radiographic inspection. This chapter provides a detailed discussion on the characteristics, process steps, applications, advantages, and limitations of these methods. It also describes the flaws caused by the forging operation and the principal factors that influence the selection of a nondestructive inspection method for forgings.

Arc welding applies to a large and diversified group of welding processes that use an electric arc as the source of heat to melt and join metals. This chapter provides a detailed overview of specific arc welding methods: shielded metal arc welding, flux cored arc welding, submerged arc welding, gas metal arc welding, gas tungsten arc welding, plasma arc welding, plasma-GMAW welding, electroslag welding, and electrogas welding. The basic characteristics of gases used for shielding during arc welding are briefly discussed.

The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. These metals are considered refractory because of their high melting points, high-temperature mechanical stability, and resistance to softening at elevated temperatures. This article discusses the composition, properties, fabrication procedures, advantages and disadvantages, and applications of these refractory metals and their alloys. A comparison of some of the properties of the refractory metals with those of iron, copper, and aluminum is given in a table. The article concludes with a brief section on refractory metal protective coatings.

This chapter covers a wide range of finishing and coating operations, including cleaning, honing, polishing and buffing, and lapping. It discusses the use of rust-preventative compounds, conversion coatings, and plating metals as well as weld overlay, thermal spray, and ceramic coatings and various pack cementation and deposition processes. It also discusses the selection and use of industrial paints and paint application methods.

Aluminum products are used extensively in natural atmospheres and in and around water. They are also widely used in building materials and as containers for chemicals and food and beverage products. This chapter discusses the corrosion mechanisms associated with these environments and the influence of various factors and prevention methods. It also includes an extensive amount of data of corrosion rates, corrosion resistance, and changes in mechanical properties.

Fossil fuels produce many byproducts that, if not fully combusted, put boiler tubes at risk. Fuel ash, chemical residues, and process heat pose the greatest threat and are the primary contributors to fireside corrosion. This chapter covers various types of fireside corrosion such as waterwall, fuel ash, and hot corrosion, acid dew-point or cold-end corrosion, and polythionic acid corrosion. It also addresses stress corrosion cracking and includes relevant case studies.

This chapter deals with the technology of stainless steel as it pertains to its proper use in architecture, art, and construction. It begins with an overview of the corrosion resistance of stainless steel, providing guidelines for balancing corrosion resistance, processing characteristics, and economy. This is followed by sections describing the influence of surface finish on corrosion resistance of stainless steel and reviewing some of the factors pertinent to balancing service environment, design requirements, and maintenance considerations. The chapter then discusses the various factors pertinent to important considerations in buildings, namely surface finish aesthetics, flatness, maintenance, repair, fabrication, and service considerations. It ends with a section providing information on concrete reinforcing bar.