This chapter examines boiler tube failures attributed to operation-related causes. It discusses failures due to rapid start-ups, excessive load swing, excessive heat inputs, poor water chemistry control, and water-treatment methods.

This article reviews the fundamental and specific factors that control the properties of steel weldments in both the weld metal and heat-affected zone (HAZ). The influence of welding processes, welding consumables, and welding parameters on the weldment properties is emphasized. The service properties of weldments in corrosive environments are considered and subjected to cyclic loading. The article summarizes the effects of major alloying elements in carbon and low-alloy steels on HAZ microstructure and toughness. It discusses the processes involved in controlling toughness in the HAZ and the selection of the proper filler metal. The article provides a comparison between single-pass and multipass welding and describes the effect of welding procedures on weldment properties and the effects of residual stresses on the service behavior of welded structures. It also describes the fatigue strength and fracture toughness of welded structures. The article reviews various types of corrosion of weldments.

Duplex stainless steels are two-phase alloys based on the iron-chromium-nickel system. Duplex stainless steels offer corrosion resistance and cost advantages over the common austenitic stainless steels. Although there are some problems with welding duplex alloys, considerable progress has been made in defining the correct parameters and chemistry modifications for achieving sound welds. This chapter provides a basic understanding of the development, grade designations, microstructure, properties, and general welding considerations of duplex stainless steel. It also discusses the influence of ferrite-austenite balance on corrosion resistance and the influence of different welding conditions on various material properties of alloy 2205 (UNS S31803).

This article describes the weldability tests that are used to evaluate the effects of welding on such properties and characteristics as base-metal and weld-metal cracking; base-metal and weld-metal ductility; weld penetration; and weld pool shape and fluid flow. It also describes several weldability tests for evaluating cracking susceptibility, classified as self-restraint or externally loaded tests. The article discusses the processes, advantages, and disadvantages of the weld pool shape tests, the weld penetration tests, and the Gleeble test.

This article discusses the weldability and fusion weld properties of refractory metal alloys. The alloys discussed include tantalum, niobium, rhenium, molybdenum, and tungsten.

This chapter discusses various factors that affect corrosion of stainless steel weldments. It begins by providing an overview of the metallurgical factors associated with welding. This is followed by a discussion on preferential attack associated with weld metal precipitates in austenitic stainless steels as well as several forms of corrosion associated with welding. The effects of gas-tungsten arc weld shielding gas composition and heat-tint oxides on corrosion resistance are then covered. Microbiological corrosion of butt welds in water tanks is also illustrated. In addition, the chapter provides information on corrosion of ferritic and duplex stainless steel weldments.

This chapter provides a basis for understanding the influence of stainless steel alloy composition and metallurgy on the welding process, which involves complex dynamics associated with melting, refining, and thermal processing. It begins with an overview of the welding characteristics of the categories of stainless steels, namely austenitic, duplex, ferritic, martensitic, and precipitation-hardening stainless steels. This is followed by a discussion of the selection criteria for materials to be welded. Various welding processes used with stainless steel are then described. The chapter ends with a section on some of the practices to ensure safety and weld quality.

This appendix provides reference tables listing weldability of cast irons, steels, and nonferrous metals. A process selection table for arc welding carbon steels is included, and recommended preheat and interpass temperature tables are also presented. This appendix includes information on qualification codes and standards.