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Published: 01 December 2003
Fig. 16 Relationships among glass transition temperature ( T g ), melt temperature ( T m ), molecular weight, and polymer properties. Source: Ref 13
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Published: 01 November 2010
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Published: 01 December 2003
Fig. 17 Variation of glass transition temperature ( T g ) with cure time and temperature. Source: Ref 23
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Book Chapter
Thermal Analysis and Thermal Properties
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2003
DOI: 10.31399/asm.tb.cfap.t69780115
EISBN: 978-1-62708-281-5
... analysis, thermomechanical analysis, and rheological analysis. The basic thermal properties covered include thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass-transition temperatures. The article further describes various factors influencing...
Abstract
This article covers the thermal analysis and thermal properties of engineering plastics with respect to chemical composition, chain configuration, and/or conformation of the base polymers. The thermal analysis techniques covered are differential scanning calorimetry, thermogravimetric analysis, thermomechanical analysis, and rheological analysis. The basic thermal properties covered include thermal conductivity, temperature resistance, thermal expansion, specific heat, and the determination of glass-transition temperatures. The article further describes various factors influencing the determination of service temperature of a material. Representative examples of different types of engineering thermoplastics are discussed in terms of structure and thermal properties. The article also discusses the thermal and related properties of thermoset resin systems.
Book Chapter
Polymers
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 August 2013
DOI: 10.31399/asm.tb.ems.t53730099
EISBN: 978-1-62708-283-9
... glass at a glass transition temperature. The relative positions of molecules are frozen so the amorphous glass is not a liquid. The change of specific volume on cooling is schematically illustrated in Fig. 9.11 . Fig. 9.11 Change of the specific volume of polyethylene with temperature...
Abstract
This chapter discusses the structural classifications, molecular configuration, degradation, properties, and uses of polymers. It describes thermoplastic and thermosetting polymers, degree of polymerization, branching, cross-linking, and copolymers. It also discusses glass transition temperatures, additives, and the effect of stretching on thermoplastics.
Book Chapter
Moisture-Related Failure
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 December 2003
DOI: 10.31399/asm.tb.cfap.t69780314
EISBN: 978-1-62708-281-5
... Abstract This article describes the mechanisms of moisture-induced damage in polymeric materials, covering the characteristics of important structural plastics; the effects of moisture on glass transition temperature, modulus, creep, and stress relaxation of plastic materials; and moisture...
Abstract
This article describes the mechanisms of moisture-induced damage in polymeric materials, covering the characteristics of important structural plastics; the effects of moisture on glass transition temperature, modulus, creep, and stress relaxation of plastic materials; and moisture-induced fatigue failure in composites. The effect of moisture on the mechanical properties of thermoset resins and thermoplastics are also discussed.
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Tensile engineering stress-strain behavior as a function of temperature. (a...
Available to PurchasePublished: 01 November 2012
, higher temperature (approaching glass transition), necking and cold drawing; 4, above glass transition temperature, homogeneous deformation (quasi-rubberlike behavior). (b) Variation of the stress-strain behavior of polymethyl methacrylate with test temperature. Source: Ref 21
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Tensile engineering stress-strain behavior as a function of temperature. (a...
Available to Purchase
in Mechanical Behavior of Nonmetallic Materials
> Mechanics and Mechanisms of Fracture: An Introduction
Published: 01 August 2005
, higher temperature (approaching glass transition), necking and cold drawing; 4, above glass transition temperature, homogeneous deformation (quasi-rubber-like behavior). Source: Ref 7.10 . (b) Variation of the stress-strain behavior of PMMA with test temperature. Source: Ref 7.19
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Temperature dependence of viscosity for several glasses. The “working range...
Available to PurchasePublished: 01 August 2013
Fig. 8.4 Temperature dependence of viscosity for several glasses. The “working range” is the temperature range in which glasses can be economically shaped. The straight lines on the semi-log plot do not extend below the glass transition temperature.
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Published: 01 December 2003
Fig. 1 Log relaxation modulus, E ( t ), as a function of log time, t (or temperature), for a glassy thermoplastic material. 1, glassy plateau; 2, transition region; 3, rubbery plateau; 4, flow region. T g , glass transition temperature
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Schematic diagrams showing the effects of temperature on the modulus of (a)...
Available to PurchasePublished: 01 October 2012
Fig. 12.9 Schematic diagrams showing the effects of temperature on the modulus of (a) amorphous and (b) semicrystalline thermoplastics. T g , glass transition temperature; T m , melting temperature
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Change of the specific volume of polyethylene with temperature. If it does ...
Available to PurchasePublished: 01 August 2013
Fig. 9.11 Change of the specific volume of polyethylene with temperature. If it does not crystallize at the melting temperature, polyethylene will remain a supercooled liquid until it reaches its glass transition temperature. Source: Ref 9.1
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Published: 01 December 2003
Fig. 18 Differential scanning calorimetry of nylon gears. MW, molecular weight; T g , glass transition temperature; T m , melt temperature
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Amorphous or dual-resin bonding. PEEK, polyetheretherketone; PEI, polyether...
Available to PurchasePublished: 01 October 2012
Fig. 8.53 Amorphous or dual-resin bonding. PEEK, polyetheretherketone; PEI, polyetherimide; T g , glass transition temperature; T m , melt temperature. Source: Ref 8.1
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Book Chapter
Mechanical Behavior of Nonmetallic Materials
Available to PurchaseSeries: ASM Technical Books
Publisher: ASM International
Published: 01 August 2005
DOI: 10.31399/asm.tb.mmfi.t69540297
EISBN: 978-1-62708-309-6
... than melt by heat as thermoplastics do. They are used at temperatures below the glass transition temperature. Thermoplastics have a linear structure (i.e., not cross-linked). They usually contain various stabilizers, fillers, or toughening agents; therefore, a wide range of properties are possible. Due...
Abstract
Structural and fracture mechanics-based tools for metals are believed to be applicable to nonmetals, as long as they are homogeneous and isotropic. This chapter discusses the essential aspects of the fatigue and fracture behaviors of nonmetallic materials with an emphasis on how they compare with metals. It begins by describing the fracture characteristics of ceramics and glasses along with typical properties and subcritical crack growth mechanisms. It then discusses the properties of engineering plastics and the factors affecting crack formation and growth, fracture toughness, fatigue life, and stress rupture failures.
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Published: 01 December 2003
Fig. 1 Residual stress distributions for various values of the Biot number, m , for the case that the initial temperature, T 0 , lies far above the glass transition temperature, T g . T ∝ , final temperature below T g ; L , sample thickness. Source: Ref 4
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Contrasting cooling curves for amorphous and crystalline polymers. A crysta...
Available to PurchasePublished: 30 April 2020
Fig. 3.4 Contrasting cooling curves for amorphous and crystalline polymers. A crystalline polymer has a volume change at the melting temperature, T M , during slow cooling, but an amorphous polymer reaches a brittle condition below the glass transition temperature, T g .
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A 1000 h creep modulus of several polymers as a function of temperature. PB...
Available to PurchasePublished: 01 December 2003
Fig. 5 A 1000 h creep modulus of several polymers as a function of temperature. PBT, polybutylene terephthalate; PC, polycarbonate; PPO, polyphenylene oxide; PVC, polyvinyl chloride; PP, polypropylene; HDPE, high-density polyethylene; T g , glass transition temperature
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Mer chemical structure of representative hydrocarbon thermo-plastic polymer...
Available to PurchasePublished: 01 December 2003
Fig. 13 Mer chemical structure of representative hydrocarbon thermo-plastic polymers (see Table 6 for glass-transition temperatures)
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Change in behavior of a polymeric material with increasing strain rate and/...
Available to PurchasePublished: 01 December 2003
Fig. 1 Change in behavior of a polymeric material with increasing strain rate and/or decreasing temperature. (a) Brittle behavior. (b) Limited ductility behavior. (c) Cold drawing behavior. (d) Rubbery behavior. Curve (a) could represent testing below the glass transition temperature. Source
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