From a fundamental standpoint, there are only two modes, or ways, in which metals can fracture under single, or monotonic, loads: shear and cleavage. There are fracture modes other than shear and cleavage. These include intergranular and quasi-cleavage fracture modes for single-load applications, and fatigue for multiple-load applications. Each of these fracture modes are discussed in this chapter. The factors affecting the ductile brittle relationship are also covered.

This article introduces the subject of fractography and how it is used in failure analysis. The discussion covers the structure of and fracture and crack-propagation behavior of polymeric materials, the distinction between the ductile and brittle fracture modes on the basis of macroscopic appearance, and the examination and interpretation of the features of fracture surfaces. In addition, the article considers several cases of field failure in various polymers to illustrate the applicability of available analytical tools in conjunction with an understanding of failure mechanisms.

Ductile fracture results from the application of an excessive stress to a metal that has the ability to deform permanently, or plastically, prior to fracture. Careful examination and knowledge of the metal, its thermal history, and its hardness are important in determining the correct nature of the fracture features. This chapter is a detailed account of the general characteristics and microstructural aspects of ductile fracture with suitable illustrations. It describes some of the complicating factors extraneous to the fracture itself.