This chapter describes some of the processes used to concentrate beryllium-rich minerals from ores. It discusses the flotation of bertrandite and phenacite from calcite, mica, fluorspar, and quartz-containing ores, the flotation of beryl from pegmatitic gangues and low-grade deposits, and the use of chemical activators and conditioning agents. It also explains that hand sorting is still very common because of processing challenges and inefficiencies.

Beryllium is the 44th most abundant element on Earth, with an estimated concentration of six parts per million in the Earth’s crust. It is found in various forms in more than 100 minerals, two of which, beryl and bertrandite, account for most of the beryllium produced throughout the world. This chapter describes where and how beryllium is obtained and provides facts, figures, and insights on global supply and demand.

This article discusses the composition and morphology of compacted graphite (CG) iron relative to that of gray and ductile iron. It explains that the graphite in CG iron is intermediate in shape between the spheroidal graphite found in ductile iron and the flake graphite in gray iron, giving it distinct advantages in a number of applications. The article also discusses the role of melt treatment elements and explains how alloying and heat treatment affect tensile strength, hardness, toughness, and ductility.

This chapter begins with a brief review of the different types of surface treatments and coatings used in industry and their effect on properties and performance. It then discusses the importance of corrosion and wear treatments and the consequences of failing to properly implement them in critical industries such as mining, energy production, transportation, and mineral and chemical processing. The chapter also describes basic approaches to dealing with corrosion and wear in steel.

Nickel and nickel alloys have an excellent combination of corrosion, oxidation, and heat resistance, combined with good mechanical properties. Nickel alloys can be divided into alloys that combine corrosion and heat resistance, superalloys for high-temperature applications, and special nickel alloys. Corrosion- and heat-resistant nickel alloys include commercially pure and low-alloy nickels, nickel-copper alloys, nickel-molybdenum and nickel-silicon alloys, nickel-chromium-iron alloys, nickel-chromium-molybdenum alloys, and nickel-chromium-iron-molybdenum-copper alloys. Special nickel alloys include electrical-resistance alloys, low-expansion alloys, magnetically soft alloys, and shape memory alloys. This chapter discusses the metallurgy, nominal composition, properties, applications, advantages, and disadvantages of these alloys. It also provides information on cobalt wear-resistant alloys and cobalt corrosion-resistant alloys.

This chapter explains how to measure the shape, size, microstructure, and composition of powders as well as their flowability and crystallization behavior. It presents detailed workflows and calculations based on SEM, TEM, FESEM, and STEM imaging, x-ray diffraction, differential scanning calorimetry, EDS and EELS spectroscopy, and powder sieving. It also discusses the measurement of crystallite size, lattice mismatch, and crystallinity and the relationship between surface area and flowability.

This chapter describes some of the chemical processes that have been developed to extract beryllium from different types of ore. It covers the Kjellgren-Sawyer sulfate method, the Degussa method, Copaux-Kawecki fluoride extraction, solvent extraction, and leaching and settling. It also provides information on electrolytic extraction and the use of electrorefining.

This article discusses the metallurgy and properties of ductile cast iron. It begins with an overview of ductile or spheroidal-graphite iron, describing the specifications, applications, and compositions. It then discusses the importance of composition control and explains how various alloying elements affect the properties, behaviors, and processing characteristics of ductile iron. The article describes the benefits of nickel and silicon additions in particular detail, explaining how they make ductile iron more resistant to corrosion, heat, and wear.

This chapter covers mechanical properties, microstructures, chemical compositions, manufacturing processes, and engineering of gating practices for several applications of gray, white, and alloyed cast irons. It begins with a description of material standards, followed by a section providing information on the practice of stress relieving. Next, the chapter details various ways of eliminating slag entrainment while designing gating and venting systems. Several factors related to the establishment of the optimum pouring rate and time are then covered. Further, the chapter discusses the technology of unalloyed or low-alloyed gray iron castings and white iron and high-alloyed cast irons. Finally, it describes the casting defects that are associated with cast iron and the processes involved in solving these defects. The article includes a number of figures illustrating the topics discussed.

Ductile iron has far superior mechanical properties compared to gray iron as well as significantly improved castability and attractive cost savings compared to cast steel. This chapter begins with information on graphite morphology and matrix type. It then discusses the advantages and applications of ductile iron. Next, the effects of various factors on the grades, chemistry, matrix, and mechanical properties of ductile iron are covered. This is followed by a section detailing the ductile iron treatment methods and the quality control methods used. Guidelines for gating and feeder design are then provided. Further, the chapter addresses the technology of ductile iron castings, including the performance and geometric attributes, molding and core-making processes used, material grades, mechanical properties, and chemical compositions of a few applications. Finally, it describes ductile iron casting defects and presents practical cases of problem-solving.

Aluminum is the second most widely used metal in the world. It is readily available, offers a wide range of properties, and can be shaped, coated, and joined using a variety of methods. This chapter discusses some of the key attributes of wrought and cast aluminum alloys and the classifications, designations, and grades of available product forms. It also explains how aluminum alloys are used in aerospace, automotive, rail, and marine applications as well as in building and construction, electrical products, manufacturing equipment, packaging, and consumer durables such as appliances and furniture.

The machinery and equipment required for rod and tube extrusion is determined by the specific extrusion process. This chapter provides a detailed description of the design requirements and principles of machinery and equipment for direct and indirect hot extrusion. It then covers the presses and auxiliary equipment for tube extrusion, induction furnaces for billet processing, handling systems for copper and aluminum alloy products, extrusion cooling systems, and age-hardening ovens. Next, the chapter describes the principles and applications of equipment for the production of aluminum and copper billets. Then, it focuses on process control in both direct and indirect hot extrusion of aluminum alloys without lubrication. The chapter describes the technology of electrical and electronic controls in the extrusion process. It ends with a discussion on the factors that influence the productivity and quality of the products in the extrusion process and methods for process optimization.

This chapter discusses the melting and conversion of superalloys and the solidification challenges they present. Superalloys have high solute content which can lead to untreatable defects if they solidify too slowly. These defects, called freckles, are highly detrimental to fatigue life. The chapter explains how and why freckles form as well as how they can be prevented. It describes the criteria for selecting the proper melting method for specific alloys based on melt segregation and chemistry requirements. It compares standard processes, including electric arc furnace/argon oxygen decarburization melting, vacuum induction melting, vacuum arc remelting, and electroslag remelting. It also addresses related issues such as consumable remelt quality, control anomalies, melt pool characteristics, and melt-related defects, and includes a section that discusses the processes involved in converting cast ingots into mill products.

This article describes in more detail the fundamental building-block level, atomic, then expands to a discussion of molecular considerations, intermolecular structures, and finally supermolecular issues. An explanation of important thermal, mechanical, and physical properties of engineering plastics and commodity plastics follows, and the final section briefly outlines the most common plastics manufacturing processes.

Ceramics normally have high melting temperatures, excellent chemical stability and, due to the absence of conduction electrons, tend to be good electrical and thermal insulators. They are also inherently hard and brittle, and when loaded in tension, have almost no tolerance for flaws. This chapter describes the applications, properties, and behaviors of some of the more widely used structural ceramics, including alumina, aluminum titanate, silicon carbide, silicon nitride, zirconia, zirconia-toughened alumina (ZTA), magnesia-partially stabilized zirconia (Mg-PSZ), and yttria-tetragonal zirconia polycrystalline (Y-TZP). It also provides information on materials selection, design optimization, and joining methods, and covers every step of the ceramic production process.

This chapter describes the molecular structures and chemical reactions associated with the production of thermoset and thermoplastic components. It compares and contrasts the mechanical properties of engineering plastics with those of metals, and explains how fillers and reinforcements affect impact and tensile strength, shrinkage, thermal expansion, and thermal conductivity. It examines the relationship between tensile modulus and temperature, provides thermal property data for selected plastics, and discusses the effect of chemical exposure, operating temperature, and residual stress. The chapter also includes a section on the uses of thermoplastic and thermosetting resins and provides information on fabrication processes and fastening and joining methods.

This chapter familiarizes readers with the many and varied thermoset composite fabrication processes and the types of applications for which they were developed. It describes wet lay-up, prepreg lay-up, and low-temperature vacuum bag curing prepreg processes, which are best suited for low-volume, medium-sized and larger parts. It also discusses filament winding and preforming processes (including weaving, knitting, stitching, and braiding) in addition to resin-transfer molding, resin film infusion, and pultrusion.