This chapter discusses common forms of corrosion, including uniform corrosion, galvanic corrosion, pitting, crevice corrosion, dealloying corrosion, intergranular corrosion, and exfoliation. It describes the factors that contribute to stress-corrosion cracking, hydrogen embrittlement, and corrosion fatigue and compares and contrasts their effects on mechanical properties, performance, and operating life. It also includes information on high-temperature oxidation and corrosion prevention techniques.

Elevated-temperature failures are the most complex type of failure because all of the modes of failures can occur at elevated temperatures (with the obvious exception of low-temperature brittle fracture). Elevated-temperature problems are real concerns in industrial applications. The principal types of elevated-temperature failure mechanisms discussed in this chapter are creep, stress rupture, overheating failure, elevated-temperature fatigue, thermal fatigue, metallurgical instabilities, and environmentally induced failure. The causes, features, and effects of these failures are discussed. The cooling techniques for preventing elevated-temperature failures are also covered.

This chapter targets areas that determine if a change occurred and if the change induced the failure: change or what's different analysis. It describes the different sources of changes that induce process deficiencies: design, process, test and inspection, environmental, supplier lot, aging, and supplier changes. The chapter presents an example of a cluster bomb failure to explain how the failure analysis team found and corrected the failure cause.

This chapter covers special fault-tree analysis topics, including the use of transfer symbols, INHIBIT gates, sequential AND gates, state-of-the-part versus state-of-the-system considerations, and the fault tree to identify redundancy-defeating failures.

The susceptibility of plastics to environmental failure, when exposed to organic chemicals, limits their use in many applications. Environmental factors can be classified into two categories: chemical and physical effects. This article discusses the effects of these environmental factors on the mechanical properties of plastics.

This article discusses the molecular mechanism, environmental criteria, and material optimization of environmental stress crazing (ESC) in glassy thermoplastics, polyethylenes, and nylons. In addition, it provides information on various tests used to determine relative susceptibility to ESC, namely constant tensile load testing and constant-strain testing.

This chapter provides an introduction to various forms of corrosion, namely uniform corrosion, localized corrosion, mechanically assisted degradation, environmentally induced cracking, microbiologically influenced corrosion, and metallurgically influenced corrosion.

This chapter focuses on stress-corrosion cracking (SCC) of metals and their alloys. It is intended to familiarize the reader with the phenomenological and mechanistic aspects of stress corrosion. The phenomenological description of crack initiation and propagation describes well-established experimental evidence and observations of stress corrosion, while the discussions on mechanisms describe the physical process involved in crack initiation and propagation. Several parameters that are known to influence the rate of crack growth in aqueous solutions are presented, along with important fracture features.

Irradiation-assisted stress-corrosion cracking (IASCC) has been a topic of engineering interest since it was first reported in the 1960s, having been observed in stainless steel cladding on light water reactor fuel elements. This chapter summarizes the results of decades of investigation, showing that IASCC can essentially be defined as the intergranular cracking of austenitic alloys in high-temperature water, where both the material and its environment have been altered by radiation. Of the many interactions that can occur when metals and water are exposed to radiation, the international consensus is that the three with the greatest impact on crack growth rates are the formation of material defects, radiation-induced segregation, and chemical reactions that increase the corrosion potential of water. The chapter discusses each of these in great detail, and includes information on predictive modeling as well.

Leaks can occur as the result of several failure causes. This chapter reviews the causes, features, and impact of various types of leaks, namely gasket leaks, O-ring leaks, bond-joint leaks, weld leaks, polyvinyl chloride leaks, valve leaks, and structural leaks.

This chapter discusses the conditions and sequence of events that lead to stress-corrosion cracking (SCC) and the mechanisms by which it progresses. It explains that the stresses involved in SCC are relatively small and, in most cases, work in combination with the development of a surface film. It describes bulk and surface reactions that contribute to SCC, including dissolution, mass transport, absorption, diffusion, and embrittlement, and their role in crack nucleation and growth. It also discusses crack tip chemistry, grain-boundary interactions, and the effect of stress-intensity on crack propagation rates, and describes several mechanical fracture models, including corrosion tunnel, film-induced cleavage, and tarnish rupture models.

This chapter focuses on common failure characteristics exhibited by mechanical and electrical components. The topic is considered from two perspectives: one possibility is that the system failed because parts were nonconforming to drawing requirements and another possibility is that the system failed even though all parts in the system met their drawing requirements. The common failures discussed in this chapter include those associated with metallic components, composite materials, plastic components, ceramic components, and electrical and electronic components.

Glasses and ceramics are susceptible to stress-corrosion cracking (SCC), as are metals, but the underlying mechanisms differ in many ways. One of the major differences stems from the lack of active dislocation motion that, in metals, serves to arrest cracks by reducing stress concentrations at flaw tips. As a result, even relatively small flaws (20 to 50 μm in radius) can cause glasses and ceramics to fail. This chapter examines the propensity of flaws to grow in glass and ceramic materials exposed to different environments, especially water, at stresses well below those that would produce immediate failure. It describes crack growth mechanisms, explains how to measure crack growth rates and predict time to failure, and provides crack growth data for a number of materials and environments.

Uranium alloys are used in applications requiring dense metals, but they have little resistance to oxidation and corrosion and are susceptible to environmentally assisted cracking, particularly when processed to high strength levels. This chapter describes the conditions under which uranium alloys are most prone to cracking. It discusses testing and characterization methods, cracking phenomenology, material properties, and microstructure. It also provides suggestions for avoiding and overcoming environmentally assisted cracking problems.

After the fault-tree, a failure-cause identification method has identified potential failure causes and the failure analysis team has prepared a failure mode assessment and assignment (FMA&A). The team knows specifically what to search for when examining components and subassemblies from the failed system. There are numerous techniques and technologies available for examining and analyzing components and subassemblies, which are categorized as follows: optical approaches, dimensional inspection and related approaches, nondestructive test approaches, mechanical and environmental approaches, and chemical and composition analysis for assessing material characteristics. This chapter is a detailed account of the working principle and the steps involved in these techniques and technologies.

In some cases, the failure analysis team finds that all components meet their requirements, the system was properly assembled, and it was not operated or tested in an out-of-specification manner, yet it still failed. When this occurs, the only conclusion the failure analysis team can reach is that it missed something in its analysis or that the design is defective. This chapter focuses on the latter possibility by discussing the various factors that a failure analysis team should consider to identify the causes of defects in system design. These include requirements identification and verification, circuit performance, mechanical failures, materials compatibility, and environmental factors. Examples that illustrate the value of design analysis are also presented.

Fiber-reinforced metal-matrix composites have carved out a niche in applications requiring high strength to weight ratios, but they are susceptible to failure when exposed to high temperatures and cyclic loads. This chapter discusses the obstacles that must be overcome to improve the creep-fatigue behavior of these otherwise promising materials. It addresses six areas that have been the focus of intense research, including thermal-expansion and elastic-viscoplastic mismatch, thermally induced biaxiality and interply stresses, creep and cyclic relaxation of residual stresses, and enhanced interfaces for oxidation.

This article discusses the chemical susceptibility of a polymeric material. The discussion covers significant absorption and transportation of an environmental reagent by the polymer; the chemical susceptibility of additives; and thermal degradation, thermal oxidative degradation, photo-oxidative degradation, environmental corrosion, and chemical corrosion of polymers. It also includes some of the techniques used to detect changes in structure during polymer exposure to hostile environments. In addition, the article describes the effects of environment on polymer performance, namely plasticization, solvation, swelling, environmental stress cracking, polymer degradation, surface embrittlement, and temperature effects.

This chapter describes nondestructive evaluation (NDE) test methods and their relative effectiveness for diagnosing the cause of stress-corrosion cracking (SCC) service failures. It discusses procedures for analyzing various types of damage in carbon and low-alloy steels, high-strength low-alloy steels, hardenable stainless steels, austenitic stainless steels, copper-base alloys, titanium and titanium alloys, aluminum and aluminum alloys, and nickel and nickel alloys. It identifies material-environment combinations where SCC is known to occur, provides guidelines on how to characterize cracking and fracture damage, and explains what to look for during macroscopic and microscopic examinations as well as chemical and metallographic analyses. It also includes nearly a dozen case studies investigating SCC failures in various materials.

This chapter briefly outlines some of the basic aspects of failure analysis, describing some of the basic steps and major concerns in conducting a failure analysis. A brief review of failure types from fracture, distortion, wear-assisted failure, and environmentally assisted failure (corrosion) is also provided.