This chapter provides an overview of beryllium casting practices and the challenges involved. It discusses the stages of solidification, the effect of cooling rate, the difficulty of heat removal, and the potential for hot cracking. It describes common melting techniques, including vacuum induction melting, vacuum arc melting, and electron beam melting, and some of the ways they have been used to cast beryllium alloys. The chapter also includes information on metal purification and grain refinement procedures.

This appendix defines abbreviations, acronyms, and symbols presented within this book.

This article discusses the role of alloying in the production and use of common refractory metals, including molybdenum, tungsten, niobium, tantalum, and rhenium. It provides an overview of each metal and its alloys, describing the compositions, properties, and processing characteristics as well as the effect of alloying elements. It also discusses strengthening mechanisms and, where appropriate, corrosion behavior.

Casting is the most economical processing route for producing titanium parts, and unlike most metals, the properties of cast titanium are on par with those of wrought. This chapter covers titanium melting and casting practices -- including vacuum arc remelting, consumable electrode arc melting, electron beam hearth melting, rammed graphite mold casting, sand casting, investment casting, hot isostatic pressing, weld repair, and heat treatment -- along with related equipment, process challenges, and achievable properties and microstructures. It also explains how titanium parts are produced from powders and how the different methods compare with each other and with conventional production techniques. The methods covered include powder injection molding, spray forming, additive manufacturing, blended elemental processing, and rapid solidification.

This appendix contains recipes of the electrolytic solutions in which various metals are polished in preparation for metallographic examination.

This chapter describes surface modification processes that go beyond conventional heat treatments, including plasma nitriding, plasma carburizing, low-pressure carburizing, ion implantation, physical and chemical vapor deposition, salt bath coating, and transformation hardening via high-energy laser and electron beams. The chapter compares methods and includes several example applications.

This article discusses the fusion welding processes that are most widely used for joining titanium, namely, gas-tungsten arc welding, gas-metal arc welding, plasma arc welding, laser-beam welding, and electron-beam welding. It describes several important and interrelated aspects of welding phenomena that contribute to the overall understanding of titanium alloy welding metallurgy. These factors include alloy types, weldability, melting and solidification effects on weld microstructure, postweld heat treatment effects, structure/mechanical property/fracture relationships, and welding process application.

This chapter gives a brief review of the development of additive manufacturing (AM) and the appeal of different of different AM methods.

This chapter discusses surface engineering treatments, including flame hardening, induction hardening, high-energy beam hardening, laser melting, and shot peening. It describes the basic implementation of each method, the materials for which they are suited, and their effect on surface metallurgy.

Adhesive bonding is a widely used industrial joining process in which a polymeric material is used to join two separate pieces (the adherends or substrates). This chapter begins with a discussion on the advantages and disadvantages of adhesive bonding, followed by a section providing information on the theory of adhesion. The chapter then describes the considerations for designing adhesively bonded joints and for testing or characterizing adhesive materials. The following section covers the characteristics of the most important synthetic adhesive systems and five groups of adhesives, namely structural, hot melt, pressure sensitive, water based, and ultraviolet and electron beam cured. The chapter ends with a discussion on some general guidelines for adhesive bonding and the basic steps in the adhesive bonding process.

This chapter discusses the fusion welding processes, namely oxyfuel gas welding, oxyacetylene braze welding, stud welding (stud arc welding and capacitor discharge stud welding), high-frequency welding, electron beam welding, laser beam welding, hybrid laser arc welding, and thermit welding.

This chapter discusses coating technologies that are applicable to beryllium, including physical and chemical vapor deposition, thermal evaporation, electroplating, sputtering, ion plating, and plasma arc spraying. It describes the advantages and disadvantages of each method and the effect of temperature, pressure, and other process variables on the microstructures and properties developed.

This chapter reviews some of the differences between powder metallurgy and additive manufacturing and explains how they influence the microstructure and properties of various alloys and the formation of defects in manufactured parts.

Surface modification technologies improve the performance of tool steels. This chapter discusses the processes involved in oxide coatings, nitriding, ion implantation, chemical and physical vapor deposition processing, salt bath coating, laser and electron beam surface modification, and boride coatings that improve the performance of hot-work and high-speed tool steels.

The refractory metals include niobium, tantalum, molybdenum, tungsten, and rhenium. These metals are considered refractory because of their high melting points, high-temperature mechanical stability, and resistance to softening at elevated temperatures. This article discusses the composition, properties, fabrication procedures, advantages and disadvantages, and applications of these refractory metals and their alloys. A comparison of some of the properties of the refractory metals with those of iron, copper, and aluminum is given in a table. The article concludes with a brief section on refractory metal protective coatings.