The commercial relevance of cast irons is best understood in the context of the iron-carbon phase diagram, where their composition places them near the eutectic point, which sheds light on why they melt at lower temperatures than steel and why they can be cast into more intricate shapes. This chapter examines these unique properties and how they are derived. It begins by describing the basic metallurgy of cast iron, focusing on the eutectic reaction. It explains how to control the reaction and thus properties of cast iron by overcooling and inoculation. The chapter also discusses composition, microstructure, heat treatments, and the classification and casting characteristics of white, gray, ductile, malleable, compacted graphite, and special cast irons.

This chapter provides perspective on the physical dimensions associated with the microstructure of steel and the instruments that reveal grain size, morphology, phase distributions, crystal defects, and chemical composition, from which properties and behaviors derive. The chapter also reviews the definitions and classifications used to identify and differentiate commercial steels, including the AISI/SAE and UNS designation systems.

This chapter introduces the principal heat treating processes, namely normalizing, annealing, stress relieving, surface hardening, quenching, and tempering. An overview of four of the more popular surface hardening treatments, namely carburizing, carbonitriding, nitriding, and nitrocarburizing, is provided.

This chapter provides a brief overview of nickel-iron-base, cobalt-base, and nickel-base superalloys, discussing their basic metallurgy and defining characteristics.

This chapter discusses the context in which metallography is used and some of the challenges of analyzing three-dimensional structures from a two-dimensional perspective. It describes the hierarchical nature of metals, the formation of grain boundaries, and the notable characteristics of microstructure. It explains how microstructure can be represented qualitatively by points, lines, surfaces, and volumes associated to a large extent with grain contact, and how qualitative features (including grains) can be quantified based on cross-sectional area, volume fraction, density, distribution, and other such metrics.

The testing of plastics includes a wide variety of chemical, thermal, and mechanical tests. This chapter reviews the tensile testing of plastics, which has been standardized in ASTM D 638, "Standard Test Method for Tensile Properties of Plastics," and other comparable standards. It describes the fundamental factors that affect data from tensile tests, examines the stipulations in standardized tensile testing, and discusses the utilization of data from tensile tests.

This chapter presents the theory and practice associated with the application of thin films. The first half of the chapter describes physical deposition processes in which functional coatings are deposited on component surfaces using mechanical, electromechanical, or thermodynamic techniques. Physical vapor deposition (PVD) techniques include sputtering, e-beam evaporation, arc-PVD, and ion plating and are best suited for elements and compounds with moderate melting points or when a high-purity film is required. The remainder of the chapter covers chemical vapor deposition (CVD) processes, including atomic layer deposition, plasma-enhanced and plasma-assisted CVD, and various forms of vapor-phase epitaxy, which are commonly used for compound films or when deposit purity is less critical. A brief application overview is also presented.

Dual-phase (DP) steels have the widest usage in automotive industry because of their excellent combination of strength and ductility. This chapter provides an overview of the composition, microstructure, processing, deformation mechanism, mechanical properties, formability, and special attributes of DP steels.

The existence of austenite and ferrite, along with carbon alloying, is fundamental in the heat treatment of steel. In view of the importance of structure and its formation to heat treatment, this chapter describes the various microstructures that form in steels, the various factors that determine the formation of microstructures during heat treatment processing of steel, and some of the characteristic properties of each of the microstructures. The discussion also covers the constitution of iron during heat treatment and the phases of heat-treated steel with elaborated information on iron phase transformation, hysteresis in heating and cooling, ferrite and austenite as two crystal structures of solid iron, and the diffusion coefficient of carbon.

This chapter describes the most effective ways to improve the corrosion resistance of sintered stainless steels, including increasing alloy content, optimizing the sintering process, and the use of surface treatments and modifications.

This chapter provides a brief but practical overview of the case carburizing process. It discusses the benefits and challenges of the process and compares and contrasts it with other hardening methods. It explains how design allowables and safety factors compensate for unknowns and familiarizes readers with the steps involved in determining case depth and verifying that case carbon requirements have been met.

This chapter introduces the basic concepts of mechanical design and its general relation with the properties derived from tensile testing. It begins with a description of the basic objective of product design. Next, a simple tie bar is used to illustrate the application of mechanical property data to material selection and design and to highlight the general implications for mechanical testing. Material subjected to the basic stress conditions is considered to establish design approaches and mechanical test methods, first in static loading and then in dynamic loading and aggressive environments. The chapter then briefly describes design criteria for some basic property combinations such as strength, weight, and costs as well as stiffness in tension. Additionally, it describes the processes involved in mechanical testing for stress at failure and elastic modulus. Finally, the chapter examines the correlation between hardness and strength.

This chapter describes the metallurgy of superalloys and the extent to which it can be controlled. It discusses the alloying elements, crystal structures, and processing sequences associated with more than a dozen phases that largely determine the characteristics of superalloys, including their properties, behaviors, and microstructure. It examines the role of more than 20 alloying elements, including phosphorus (promotes carbide precipitation), boron (improves creep properties), lanthanum (increases hot corrosion resistance), and carbon and tungsten which serve as matrix stabilizers. It explains how precipitates provide strength by impeding deformation under load. It also discusses the factors that influence grain size, shape, and orientation and how they can be controlled to optimize mechanical and physical properties.

This chapter reviews failure aspects of structural ferrous powder metallurgy (PM) parts, which form the bulk of the PM industry. The focus is on conventional PM technology of parts in the density range of 6 to 7.2 g/cc. The chapter briefly introduces the processing steps that are essential to understanding failure analysis of PM parts. This is followed by a section on case hardening of PM parts. The methods used for analyzing the failures are then discussed. Some case studies are given that illustrate different failures and the methods of prevention of these failures.

This chapter summarizes the progress that has been made in the study of high-entropy alloy (HEA) systems and the process-structure-property relationships that define them. It describes the various ways HEAs can be strengthened and explains how alloying elements influence tensile and yield strength, fracture toughness, and fracture strength. It discusses the stages of plastic deformation in HEAs and the role of dislocations and twinning in the evolution of microstructure. It reviews some of the work that has been done on fatigue behaviors and the methods developed to assess fatigue performance. It discusses the influence of defects on fatigue life, the effect of temperature and grain size on fatigue-crack propagation, and the role of nanotwinning in crack-growth retardation. It describes the methods used to produce HEAs in bulk and powder form and to apply them as protective coatings and films. It also identifies potential applications based on properties such as strength, hardness, density, wear resistance, high-temperature stability, and biocompatibility.

Medium-carbon steels are typically hardened for high-strength, high-fatigue-resistant applications by austenitizing, quenching to martensite, and tempering. This chapter explains how microalloying with vanadium, niobium, and/or titanium provides an alternate way to improve the mechanical properties of such steels. It also addresses microalloyed forging steels and explains how nontraditional bainitic microstructures can be produced by direct cooling after forging.

This chapter provides practical information on the forming and forging processes used to manufacture titanium parts, including die forging, precision die forging, hot and cold forming, superplastic forming, and deep drawing. It explains how process variables such as temperature, pressure, and strain rate influence microstructure and properties and provides recommended ranges for commonly formed and forged titanium alloys.

This chapter examines two important strengthening mechanisms, martensitic and bainitic transformations, both of which occur under nonequilibrium cooling conditions. It explains how time-temperature-transformation diagrams are constructed and how they are used to understand and control the formation of martensite and bainite in steel and other alloys. It describes the morphology of both types of structures, the factors that influence their formation, how they respond to tempering processes, and their effect on mechanical properties and behaviors. It also discusses the role of transformation hysteresis in shape memory alloys.

The oil-hardening cold-work tool steels, designated as group O steels in the AISI classification system, derive their high hardness and wear resistance from high carbon and modest alloy contents. This chapter describes the microstructures and hardenability of oil-hardening tool steels and discusses the processes involved in the hardening and tempering of tool steels. It also covers the selection criteria and applications of oil-hardening cold-work tool steels.