This chapter discusses the conditions and sequence of events that lead to stress-corrosion cracking (SCC) and the mechanisms by which it progresses. It explains that the stresses involved in SCC are relatively small and, in most cases, work in combination with the development of a surface film. It describes bulk and surface reactions that contribute to SCC, including dissolution, mass transport, absorption, diffusion, and embrittlement, and their role in crack nucleation and growth. It also discusses crack tip chemistry, grain-boundary interactions, and the effect of stress-intensity on crack propagation rates, and describes several mechanical fracture models, including corrosion tunnel, film-induced cleavage, and tarnish rupture models.

High-strength steels are susceptible to stress-corrosion cracking (SCC) even in moist air. This chapter identifies such steels and the applications where they are typically found. It provides information on crack growth kinetics and crack propagation models in which hydrogen embrittlement is the predominant mechanism. It explains how different application variables affect SCC, including loading mode, state of stress, type of steel, temperature, electrochemical potential, heat treatment, and deformation processes. It also compares SCC characteristics in different high-strength steels and discusses the influence of composition, steelmaking practice, and application environment.

Environmentally assisted cracking is a generic term that includes various cracking phenomena such as stress-corrosion cracking (SCC), corrosion fatigue cracking, and liquid-metal embrittlement. This chapter describes these cracking mechanisms beginning with SCC and the factors that influence its formation. It covers alloy selection and mitigation techniques and includes examples of SCC in aircraft components. The chapter also addresses corrosion fatigue, explaining how different environments and operating conditions affect crack propagation, fatigue strength, and fatigue life. It includes information on liquid-metal embrittlement as well.

Fatigue failures occur due to the application of fluctuating stresses that are much lower than the stress required to cause failure during a single application of stress. This chapter describes three basic factors that cause fatigue: a maximum tensile stress of sufficiently high value, a large enough variation or fluctuation in the applied stress, and a sufficiently large number of cycles of the applied stress. The discussion covers high-cycle fatigue, low-cycle fatigue, and fatigue crack propagation. The chapter then discusses the stages where fatigue crack nucleation and growth occurs. It describes the most effective methods of improving fatigue life. The chapter also explains the effect of geometrical stress concentrations on fatigue. In addition, it explores the environmental effects of corrosion fatigue, low-temperature fatigue, high-temperature fatigue, and thermal fatigue. Finally, the chapter discusses a number of design philosophies or methodologies to deal with design against fatigue failures.

This article is a detailed account of the mechanisms of fatigue failure of polymers, namely thermal fatigue failure and mechanical fatigue failure. The mechanical fatigue failure is discussed in terms of fatigue crack initiation and fatigue crack propagation.

This article introduces the subject of fractography and how it is used in failure analysis. The discussion covers the structure of and fracture and crack-propagation behavior of polymeric materials, the distinction between the ductile and brittle fracture modes on the basis of macroscopic appearance, and the examination and interpretation of the features of fracture surfaces. In addition, the article considers several cases of field failure in various polymers to illustrate the applicability of available analytical tools in conjunction with an understanding of failure mechanisms.

This chapter discusses the factors that play a role in fatigue failures and how they affect the service life of metals and structures. It describes the stresses associated with high-cycle and low-cycle fatigue and how they differ from the loading profiles typically used to generate fatigue data. It compares the Gerber, Goodman, and Soderberg methods for predicting the effect of mean stress from bending data, describes the statistical nature of fatigue measurements, and explains how plastic strain causes cyclic hardening and softening. It discusses the work of Wohler, Basquin, and others and how it led to the development of a strain-based approach to fatigue and the use of fatigue strength and ductility coefficients. It reviews the three stages of fatigue, beginning with crack initiation followed by crack growth and final fracture. It explains how fracture mechanics can be applied to crack propagation and how stress concentrations affect fatigue life. It also discusses fatigue life improvement methods and design approaches.

This chapter summarizes the progress that has been made in the study of high-entropy alloy (HEA) systems and the process-structure-property relationships that define them. It describes the various ways HEAs can be strengthened and explains how alloying elements influence tensile and yield strength, fracture toughness, and fracture strength. It discusses the stages of plastic deformation in HEAs and the role of dislocations and twinning in the evolution of microstructure. It reviews some of the work that has been done on fatigue behaviors and the methods developed to assess fatigue performance. It discusses the influence of defects on fatigue life, the effect of temperature and grain size on fatigue-crack propagation, and the role of nanotwinning in crack-growth retardation. It describes the methods used to produce HEAs in bulk and powder form and to apply them as protective coatings and films. It also identifies potential applications based on properties such as strength, hardness, density, wear resistance, high-temperature stability, and biocompatibility.

This chapter focuses on stress-corrosion cracking (SCC) of metals and their alloys. It is intended to familiarize the reader with the phenomenological and mechanistic aspects of stress corrosion. The phenomenological description of crack initiation and propagation describes well-established experimental evidence and observations of stress corrosion, while the discussions on mechanisms describe the physical process involved in crack initiation and propagation. Several parameters that are known to influence the rate of crack growth in aqueous solutions are presented, along with important fracture features.

This appendix presents an analytical model that estimates damage rates for both crack initiation and propagation mechanisms. The model provides a nonarbitrary definition of fatigue crack initiation length, which serves as an analytical link between initiation and propagation analyses and appears to have considerable merit in estimating the total fatigue life of notched and cracked structures.

This article reviews fatigue test methodologies, provides an overview of general fatigue behavior (crack initiation and propagation) in engineering plastics, and discusses some of the factors affecting the fatigue performance of polymers. In addition, it provides information on fractography that provides useful insight into the nature of fracture processes.

This chapter provides a quantitative treatment of the cracking mechanisms associated with fatigue, drawing on the principles of fracture mechanics. It explains that although fracture mechanics originated with the aim of understanding sudden and catastrophic crack extension, the main premise of a stress field in the vicinity of the crack also applies to the study of cycle-by-cycle stable crack growth. A detailed review is given of the many developments and discoveries that helped shape the theory and methods collectively defined as crack mechanics, which the authors then employ to analyze the crack growth behavior of various materials, including steels and nonferrous alloys, under constant-amplitude loading. The authors then deal with the effects of complex loading using crack retardation and crack closure models to show how load fluctuations can slow crack growth rates and even cause total crack arrest. They also present the results of a study on crack initiation, propagation, and fracture in circular (rather than rectangular) specimens and a fatigue study on ductile and quasi-brittle materials.

This chapter focuses on the processes and mechanisms involved in fatigue. It begins with a review of some of the early theories of fatigue and the tools subsequently used to obtain a better understanding of the fatigue process. It then explains how plasticity plays a major role in creating dislocations, breaking up grains into subgrains, and causing microscopic imperfections to coalesce into larger flaws. It also discusses the factors that contribute to the development and propagation of fatigue cracks, including surface deterioration, volumetric and environmental effects, foreign particles, and stresses generated by rolling contact.

The aluminum alloy skin on the main rotor blade of a helicopter tore off in flight, and an investigation was subsequently conducted to find the cause. Visual examination and SEM fractography revealed that a fatigue crack originated on the underside of a rivet hole at the trailing edge of the blade. The crack then propagated through the outer skin toward the leading edge of the blade. Once the fatigue crack reached critical length, the sheet metal fractured catastrophically, tearing away from the blade.

This chapter describes an investigation following an aircraft accident in which the main undercarriage struts had failed. Visual examination revealed that the starboard strut fractured about 13 cm from the end nearest the underside of the wing. A close-up view of the fracture surface indicated that cracking initiated at the outer periphery of the strut and propagated inward until overload fracture occurred. SEM imaging revealed fatigue striations along the outer periphery and dimples elsewhere, indicative of tensile overload. Based on these observations, investigators concluded that the starboard strut failed by fatigue, which overloaded the port side strut as evidenced by its slant type fracture pattern.

This chapter addresses the challenge of selecting an appropriate stress-corrosion cracking (SCC) test to evaluate the serviceability of a material for a given application. It begins by establishing a generic model in which SCC is depicted in two stages, initiation and propagation, that further subdivide into several zones plus a transition region. It then discusses SCC test standards before describing basic test objectives and selection criteria. The chapter explains how to achieve the required loading conditions for different tests and how to prepare test specimens to determine elastic strain, plastic strain, and residual stress responses. It also describes the difference between smooth and precracked specimens and how they are used, provides information on slow-strain-rate testing and how to assess the results, and discusses various test environments and procedures, including tests for weldments. The chapter concludes with a section on how to interpret time to failure, threshold stress, percent survival, stress intensity, and propagation rate data, and assess the precision of the associated tests.

A low-pressure turbine rotor blade failed in service, causing extensive engine damage. A section of the blade broke off around 25 mm from the root platform, producing a flat fracture surface that appeared smooth on one end and grainy elsewhere. Based on their examination, investigators concluded that the nickel-base superalloy blade was exposed to high temperatures and stresses, initiating a crack that propagated under cyclic loading. This chapter provides a summary of the investigation and the insights acquired using scanning electron fractography, metallography, and hardness measurements.

This chapter addresses the issue of stress-corrosion cracking (SCC) in carbon and low-alloy steels. It discusses crack initiation, propagation, and fracture in aqueous chloride, hydrogen sulfide, sulfuric acid, hydroxide, ammonia, nitrate, ethanol, methanol, and hydrogen gas environments. It explains how composition and microstructure influence SCC, as do mechanical properties such as strength and fracture toughness and processes such as welding and cold work. It also discusses the role of materials selection and best practices for welding.

Fracture mechanics is a well-developed quantitative approach to the study of failures. This chapter discusses fracture toughness and fracture mechanics, linear-elastic fracture mechanics, and modes of loading. The discussion also covers plane strain and stress and crack growth kinetics. The chapter presents a case history that illustrates the use of fracture mechanics in failure analysis. An appendix provides a more detailed discussion of fracture mechanics concepts.

Stress-corrosion cracking (SCC) in magnesium alloys was first reported in the 1930s and, within ten years, became the focus of intense study. This chapter provides a summary of all known work published since then on the nature of SCC in magnesium alloys and how it is related to composition, microstructure, and heat treatment. It describes the types of environments where magnesium alloys are most susceptible to SCC and the effect of contributing factors such as temperature, strain rate, and applied and residual stresses. The chapter also discusses crack morphology and what it reveals, provides information on proposed cracking mechanisms, and presents a practical approach for preventing SCC.