Boilers are engineered systems designed to convert the chemical energy in fuel into heat to generate hot water or steam. This chapter describes boiler applications and types, including firetube boilers, watertube boilers, electric boilers, packaged boilers, fluidized bed combustion boilers, oil- and gas-fired boilers, waste heat boilers, and black liquor recovery boilers. It also describes the operation and working principle of utility or power plant boilers, covering conventional subcritical and advanced supercritical types.

This chapter describes the metallurgy, composition, and properties of steels and other alloys. It provides information on the atomic structure of metals, the nature of alloy phases, and the mechanisms involved in phase transformations, including time-temperature effects and the role of diffusion, nucleation, and growth. It also discusses alloying, heat treating, and defect formation and briefly covers condenser tube materials.

Boilers are often classified based on the maximum operating temperature and pressure for which they are designed. Classifications, in ascending order, are subcritical, supercritical, ultra-supercritical, and to advanced ultra-supercritical. At each higher operating point comes greater efficiency, as well as greater demand on construction materials. This chapter discusses the primary requirements for boiler tube materials, including oxidation and corrosion resistance, fatigue strength, thermal conductivity, and the ability to resist creep and rupture. It also provides information on various steels and alloys, covering cost, engineering specifications, and ease of use.

This chapter describes some of the most effective tools for investigating boiler tube failures, including scanning electron microscopy, optical emission spectroscopy, atomic absorption spectroscopy, x-ray fluorescence spectroscopy, x-ray diffraction, and x-ray photoelectron spectroscopy. It explains how the tools work and what they reveal. It also covers the topic of image analysis and its application in the measurement of grain size, phase/volume fraction, delta ferrite and retained austenite, inclusion rating, depth of carburization/decarburization, scale thickness, pearlite banding, microhardness, and hardness profiles. The chapter concludes with a brief discussion on the effect of scaling and deposition and how to measure it.

Water chemistry is a factor in nearly all boiler tube failures. It contributes to the formation of scale, biofilms, and sludge, determines deposition rates, and drives the corrosion process. This chapter explains how water chemistry is managed in boilers and describes the effect of impurities and feedwater parameters on high-pressure boiler components. It discusses deposition and scaling, types of corrosion, and carryover, a condition that occurs when steam becomes contaminated with droplets of boiler water. The chapter also covers water treatment procedures, including filtration, chlorination, ion exchange, demineralization, reverse osmosis, caustic and chelant treatment, oxygen scavenging, and colloidal, carbonate, phosphate, and sodium aluminate conditioning.

The power generating industry has become proficient at predicting how long a component will last under a given set of operating conditions. This chapter explains how such predictions are made in the case of boiler tubes. It identifies critical damage mechanisms, progressive failure pathways, and relevant test and measurement procedures. It describes life assessment methods based on hardness, wall thickness, scale formation, microstructure, and creep. It also includes a case study on the determination of the residual life of a secondary superheater tube.

This chapter covers the failure modes and mechanisms associated with boiler components and the tools and techniques used to assess damages and predict remaining component life. It begins with a review of the design and operation of a utility boiler and the materials used in construction. It then describes the various causes of failure in boiler tubes, headers, and steam pipes, explaining how and why they occur, how they are diagnosed, and how to mitigate their effects. The final and by far largest section in the chapter is a tutorial on damage and life assessment techniques for boiler components and assemblies. It demonstrates the use of various methods, including analytical techniques that estimate life expenditure based on operating history, component geometry, and material properties; predictive methods based on the extrapolation of failure statistics; methods that predict life based on dimensional measurements; methods based on metallographic studies; methods based on temperature estimates; and a method for estimating remaining life under creep conditions based on stress-rupture testing of service-exposed material samples. The chapter also discusses the use of fracture mechanics and presents a number of cases in which life assessments are made based on the integration of several methods.