This chapter provides an introduction to various forms of corrosion, namely uniform corrosion, localized corrosion, mechanically assisted degradation, environmentally induced cracking, microbiologically influenced corrosion, and metallurgically influenced corrosion.

This chapter first covers some basic principles of electrochemical corrosion and then some of the various types of corrosion. Some of the more common types of corrosion discussed include uniform corrosion, galvanic corrosion, pitting, crevice corrosion, erosion-corrosion, cavitation, fretting corrosion, intergranular corrosion, exfoliation, dealloying corrosion, stress-corrosion cracking, and corrosion fatigue. The chapter discusses the processes involved in corrosion control by retarding either the anodic or cathodic reactions. The rate of corrosion is reduced by conditioning of the metal, by conditioning the environment, and by electrochemical control. Finally, the chapter deals with high-temperature oxidation that usually occurs in the absence of moisture.

This chapter explores the behavior of stainless steel in media that promote corrosion. The forms of corrosion covered are uniform corrosion, atmospheric corrosion, localized corrosion, pitting corrosion, crevice corrosion, and grain boundary corrosion. The chapter discusses the influence of material and environmental variables on stress-corrosion cracking (SCC) and the mechanisms proposed for SCC in stainless steel, comparing the mechanism of SCC with hydrogen embrittlement. In addition, it provides information on biocorrosion and microbiologically induced corrosion in ambient aqueous environments.

The design process is the first and most important step in corrosion control. Major savings in operating costs are possible by anticipating corrosion problems so as to provide proper design for equipment before assembly or construction begins. This chapter describes the role of the design team in producing a successful final design, general considerations in corrosion-control design, and design details that accelerate corrosion. The details that must be considered when attempting to control corrosion by design include plant/site location, plant environment, component/assembly shape, fluid movement, surface preparation and coating procedures, and compatibility, insulation, and stress considerations. Design solutions for specific forms of corrosion, namely crevice corrosion, galvanic corrosion, erosion-corrosion, and stress-corrosion cracking, are then considered. A brief section is devoted to the discussion on corrosion allowance used for steel parts subject to uniform corrosion. Finally, the chapter describes the design considerations for using weathering steels.

This chapter outlines the major types of corrosion, their interactions, their complicating effects on fracture and wear, and some possible prevention methods. The types of corrosion considered in the chapter are galvanic corrosion, uniform corrosion, pitting corrosion, crevice corrosion, microbiologically influenced corrosion, stress-corrosion cracking, and corrosion fatigue.

This chapter discusses common forms of corrosion, including uniform corrosion, galvanic corrosion, pitting, crevice corrosion, dealloying corrosion, intergranular corrosion, and exfoliation. It describes the factors that contribute to stress-corrosion cracking, hydrogen embrittlement, and corrosion fatigue and compares and contrasts their effects on mechanical properties, performance, and operating life. It also includes information on high-temperature oxidation and corrosion prevention techniques.

This chapter outlines the step-by-step processes by which materials are selected in order to prevent or control corrosion and includes information on materials that are resistant to the various forms of corrosion. The various forms of corrosion covered are general (uniform) corrosion, localized corrosion, galvanic corrosion, intergranular corrosion, stress-corrosion cracking, hydrogen damage, and erosion-corrosion. In addition, the economic importance of cost-effective materials selection is also considered.

This chapter familiarizes readers with the basic concepts of corrosion, discussing chemical reactions, ion transfer mechanisms, electrochemical processes and variables, and the formation of solid corrosion products. It presents a simple but effective teaching tool, the elementary electrochemical corrosion circuit, using it to explain how electric potential differences drive the corrosion process and how corrosion rates vary in proportion to current density. The chapter concludes with a discussion on the importance of corrosion products, such as oxides and hydroxides, and how their formation can be a major factor in controlling corrosion.

Corrosion problems can be divided into eight categories based on the appearance of the corrosion damage or the mechanism of attack: uniform or general corrosion; pitting corrosion; crevice corrosion, including corrosion under tubercles or deposits, filiform corrosion, and poultice corrosion; galvanic corrosion; erosion-corrosion, including cavitation erosion and fretting corrosion; intergranular corrosion, including sensitization and exfoliation; dealloying; environmentally assisted cracking, including stress-corrosion cracking, corrosion fatigue, and hydrogen damage (including hydrogen embrittlement, hydrogen-induced blistering, high-temperature hydrogen attack, and hydride formation). All these forms are addressed in this chapter in the context of aqueous corrosion. For each form, a general description is provided along with information on the causes and the list of metals that can be affected, with particular emphasis on the recognition and prevention measures.