This appendix contains tables listing the physical and mechanical properties of stainless steel engineering alloys. The physical properties covered are density, modulus of elasticity, coefficient of thermal expansion, thermal conductivity, specific heat, and electrical resistivity. The mechanical properties listed include yield strength, tensile strength, elongation and hardness.

Martensitic stainless steels are essentially iron-chromium-carbon alloys that possess a body-centered tetragonal crystal structure (martensitic) in the hardened condition. Martensitic stainless steels are similar to plain carbon or low-alloy steels that are austenitized, hardened by quenching, and then tempered for increased ductility and toughness. This chapter provides a basic understanding of grade designations, properties, corrosion resistance, and general welding considerations of martensitic stainless steels. It also discusses the causes for hydrogen-induced cracking in martensitic stainless steels and describes sulfide stress corrosion resistance of type 410 weldments.

This chapter provides a detailed discussion on microstructure, properties, and applications of two classes of stainless steel: duplex stainless steel and precipitation-hardening steel.

This chapter discusses various factors pertinent to the prevention of corrosion in alloys for petroleum applications and reviews the selection of stainless steels for petroleum applications, including oil country tubular goods, line pipe, offshore platforms, liquefied natural gas vessels, and refinery equipment.

This chapter discusses the processes involved in heat treating of stainless steels, providing information on the classification, chemical compositions, and corrosion resistance of stainless steels and the effect of specific elements on the characteristics of iron-base alloys. Five groups of stainless steels are discussed: austenitic, ferritic, martensitic, precipitation-hardening, and duplex grades. The chapter also describes the heat treatment conditions that should be maintained for processing of stainless steels.

This chapter discusses the metallurgy, phase structure, thermal processing, and applications of martensitic stainless steels. The phenomenon of martensite formation is explained. A table listing the compositions of martensitic stainless steels is also presented.

This article covers the metallurgy and properties of stainless steels. It provides composition information on all types of ferritic, austenitic, martensitic, duplex, and precipitation-hardening stainless steels, including proprietary and nonstandard grades, along with corresponding property and performance data. It also discusses the effect of various alloying elements on pitting, crevice corrosion, sensitization, stress-corrosion cracking, and oxidation resistance.

Stainless steels and nickel-base alloys are recognized for their resistance to general corrosion and other categories of corrosion. This chapter examines the effects of specific alloying elements, metallurgical structure, and mechanical conditioning on the corrosion resistance of these alloys. Some categories of corrosion covered are pitting, crevice, intergranular, stress-corrosion cracking, general, and high-temperature corrosion.

Steels that resist corrosive attack from normal atmospheric exposure and contain a minimum of 10.5% Cr and 50% Fe are generally classified as stainless steels. Their special qualities lie in a chromium-rich oxide surface film that quickly regrows when damaged. This chapter discusses the classification, composition, properties, treatments, and applications of austenitic, ferritic, martensitic, duplex, precipitation-hardening, powder metallurgy, and cast stainless steels. It also reviews the history of stainless steels and provides information on alloy designation systems.

This appendix contains tables listing the composition of austenitic, ferrite, martensitic, precipitation-hardenable, and duplex stainless steels and of Alloy Casting Institute heat- and corrosion-resisting casting alloys.

This appendix is a collection of tables listing the chemical compositions of wrought ferritic steels; wrought stainless steels; cast corrosion- and heat-resistant alloys; wrought iron-, nickel-, and cobalt-base alloys; cast nickel- and cobalt-base alloys; oxide-dispersion-strengthened alloys; and iron-, nickel- and cobalt-base filler metals.

This chapter discusses the composition and classification of stainless steels and focuses on the processes involved in heat treatment and applications of these steels. The wrought and the cast stainless steels covered are ferritic, austenitic, duplex (ferritic-austenitic), martensitic, and precipitation-hardening. In addition, information on special considerations for stainless steel castings is also provided. The heat treatment processes explained in the chapter are preheating, annealing, stress relieving, hardening, tempering, austenite conditioning, heat aging, and nitride surface hardening. Finally, some special considerations for stainless steel castings are discussed.

This appendix provides tables listing alloy compositions and standard designations and common unit and hardness conversion factors.

This chapter describes the metallurgy, composition, and properties of steels and other alloys. It provides information on the atomic structure of metals, the nature of alloy phases, and the mechanisms involved in phase transformations, including time-temperature effects and the role of diffusion, nucleation, and growth. It also discusses alloying, heat treating, and defect formation and briefly covers condenser tube materials.

All materials are susceptible to corrosion or some form of environmental degradation. Although no single material is suitable for all applications, usually there are a variety of materials that will perform satisfactorily in a given environment. The intent of this chapter is to review the corrosion behavior of the major classes of metals and alloys as well as some nonmetallic materials, describe typical corrosion applications, and present some unique weaknesses of various types of materials. It also aims to point out some unique material characteristics that may be important in material selection, and discuss, where appropriate, the characteristic forms of corrosion that attack specific materials. The materials addressed in this chapter include carbon steels, weathering steels, and alloy steels; nickel, copper, aluminum, titanium, lead, magnesium, tin, zirconium, tantalum, niobium, and cobalt and their alloys; polymers; and other nonmetallic materials, including rubber, carbon and graphite, and woods.

This chapter presents the primary considerations and mechanisms for corrosion and how they are involved in the selection of materials for process equipment in petroleum refineries and petrochemical plants. In addition, specific information on mechanical properties, corrosion, sulfide stress cracking, hydrogen-induced cracking, stress-oriented hydrogen-induced cracking, hydrogen embrittlement cracking, stress-corrosion cracking, velocity-accelerated corrosion, erosion-corrosion, and corrosion control is provided.

Many metallic components, such as retorts in heat treat furnaces, furnace heater tubes and coils in chemical and petrochemical plants, waterwalls and reheater tubes in boilers, and combustors and transition ducts in gas turbines, are subject to oxidation. This chapter explains how oxidation affects a wide range of engineering alloys from carbon and Cr-Mo steels to superalloys. It discusses the kinetics and thermodynamics involved in the formation of oxides and the effect of surface and bulk chemistry. It provides oxidation data for numerous alloys and intermetallics in terms of weight gain, metal loss, depth of attack, and oxidation rate. It also discusses the effect of metallurgical and environmental factors such as oxygen concentration, high-velocity combustion gas streams, chromium depletion and breakaway, component thickness, and water vapor.