This chapter describes the basic steps in the steelmaking process. It explains how iron is reduced from ore in the liquid state through the classic blast furnace process and in the solid state by direct reduction. It discusses the conversion of iron to steel and the technological advancements that led from open hearth steelmaking to basic oxygen processes and ultimately the electric arc furnace (EAF). It describes the versatility, efficiency, and scalability of the EAF process and its impact on recycling and sustainability. It explains how EAF refining and deoxidation practices have changed over time, and describes secondary refining processes such as degassing, homogenization, rinsing, and remelting.

This chapter traces the history of steelmaking over three millennia, from the discovery of martensite in a mining tool dating from the twelfth century B.C. to the nineteenth century development of the Bessemer and Siemens processes. It also describes the work of early metallographers who discovered many phases and microstructures associated with steel and gave them their now familiar names. The chapter concludes with a brief discussion on the emergence of continuous casting and the subsequent development of strip casting production techniques.

High-strength steels are susceptible to stress-corrosion cracking (SCC) even in moist air. This chapter identifies such steels and the applications where they are typically found. It provides information on crack growth kinetics and crack propagation models in which hydrogen embrittlement is the predominant mechanism. It explains how different application variables affect SCC, including loading mode, state of stress, type of steel, temperature, electrochemical potential, heat treatment, and deformation processes. It also compares SCC characteristics in different high-strength steels and discusses the influence of composition, steelmaking practice, and application environment.

This chapter focuses on the evolution of steel production from 1870 to 1900. It begins with a review of the life of the inventor of the air-boiling process, William Kelly. This is followed by a discussion on how Bessemer's air-blowing process entered the steel production industry and the development of the Kelly-Bessemer process by Alexander Holley. The chapter then discusses how Andrew Carnegie lowered the cost to produce steel, how he entered the iron and steelmaking industry, and how Captain Billy Jones joined Carnegie to expand Carnegie steel. The chapter further provides information on the great strike of 1892 at Homestead and the rapid growth in steel markets. It ends with a discussion about the factors that led Carnegie to sell his steel empire.

This chapter provides a detailed account of the development of tool steel technology. It begins with a record of steelmaking in ancient and medieval times. The crucible melting process involved in making steel is then discussed. This is followed by a description of the increasing use of alloys for tool steels. The chapter provides information on the research investigations into the metallurgy of high-speed tool steels at MIT, Union Carbide, and Carbon Laboratories. The major research effort involved in substituting molybdenum for tungsten in high-speed tool steels is discussed. The chapter also describes the role of the Cleveland Twist Drill Company as the first adopter of molybdenum high-speed steel. It ends with a discussion on the advanced work on high-speed steels by Swedish researchers.

This chapter provides a brief overview of iron and steel manufacturing and the major equipment involved in the process as well as identifying where casting fits into the overall process. In addition, it provides an overview of cast iron manufacturing, including the processes involved in converting pig iron into cast iron and steel.

This chapter discusses the formation and growth of various integrated steel companies from 1901 to 1959, namely the United States Steel Corporation, Bethlehem Steel Corporation, and a few of the notable smaller steel companies. The chapter discusses labor unrest and the growth of organized labor in the steel industry in the twentieth century.

This chapter is an account of the various events that led to the decline of the integrated steel industry during the 1950s. These include the steel strike of 1959, the improvements in technology and increase in imports since 1950s, widespread closures of steel companies, the decline of the minimill industry, and the rapid growth of Mittal Steel.

Inclusions and chemical segregation are factors in many process-induced failures involving steel parts. Inclusions are nonmetallic compounds introduced during production; segregation is a type of chemical partitioning that occurs during solidification. This chapter discusses the origins of segregation and inclusions and their effect on the mechanical properties and microstructure of steel. It explains how to identify various types of inclusions and characteristic segregation patterns, such as banding. It also describes the effect of hot work processing on solidification structure and the chemical variations produced by interdendritic segregation.

This chapter presents a brief description of the three-step process: melting, decarburizing, and alloying. It also discusses the following processes: wild process, rustless process, and Linde Argon-Oxygen decarburization process.

This chapter discusses the rise of steel minimills in the late 1960s through the leadership of F. Kenneth Iverson and Gerald Heffernan. The discussion covers the development of processes for flat products, flanged beams, and railroad rails. The chapter also covers the growth of the minimill industry along with the consolidation of the industry into large corporations. The chapter ends by providing information on novel processes developed for making iron.