Bonding in solids may be classified as either primary or secondary bonding. Methods of primary bonding include the metallic, ionic, and covalent bonds. This chapter discusses and provides a comparison of the properties of these bonds. This is followed by a discussion on crystalline structure, providing information on space lattices and crystal systems, hexagonal close-packed systems, and face-centered and body-centered cubic systems. The chapter then covers slip systems and closes with a brief section on allotropic transformations that occur at a constant temperature during either heating or cooling.

This chapter discusses the application of investment casting to nickel- and cobalt-base superalloys. It describes the production of polycrystalline and single crystal castings, the materials normally used, and the part dimensions and tolerances typically achieved. It explains how patterns, molds, and shells are produced, discusses the practice of directional solidification, and examines an assortment of turbine components cast from nickel- and cobalt-base alloys. The chapter also addresses casting problems such as inclusions, porosity, distortion, core shift, and leaching and explains how to avoid them.

This chapter explains the basic terminology and principles of metallurgy as they apply to extrusion. It begins with an overview of crystal structure in metals and alloys, including crystal defects and orientation. This is followed by sections discussing the development of the continuous cast microstructure of aluminum and copper alloys. The discussion provides information on billet and grain segregation and defects in continuous casting. The chapter then discusses the processes involved in the deformation of pure metals and alloys at room temperature. Next, it describes the characteristics of pure metals and alloys at higher temperatures. The processes involved in extrusion are then covered. The chapter provides details on how the toughness and fracture characteristics of metals and alloys affect the extrusion process. The weld seams in hollow profiles, the production of composite profiles, and the processing of composite materials, as well as the extrusion of metal powders, are discussed. The chapter ends with a discussion on the factors that define the extrudability of metallic materials and how these attributes are characterized.

This appendix provides a detailed overview of the crystal structure of metals. It describes primary bonding mechanisms, space lattices and crystal systems, unit cell parameters, slip systems, and crystallographic planes and directions as well as plastic deformation mechanisms, crystalline imperfections, and the formation of surface or planar defects. It also discusses the use of X-ray diffraction for determining crystal structure.

This chapter discusses the foundational principles of materials science. It begins with a review of the periodic table and the fundamental particles, including atoms, ions, and molecules, that constitute matter. It also reviews the types of bonds that form between atoms and the relative levels of force they produce. It describes the difference between crystalline and noncrystalline or amorphous materials and discusses common crystal structures, including face-centered cubic, body-centered cubic, hexagonal close packed, and diamond cubic. It also describes the structure of sodium chloride and includes a list of structurally similar compounds.

This chapter introduces many of the key concepts on which metallurgy is based. It begins with an overview of the atomic nature of matter and the forces that link atoms together in crystal lattice structures. It discusses the types of imperfections (or defects) that occur in the crystal structure of metals and their role in mechanical deformation, annealing, precipitation, and diffusion. It describes the concept of solid solutions and the effect of temperature on solubility and phase transformations. The chapter also discusses the formation of solidification structures, the use of equilibrium phase diagrams, the role of enthalpy and Gibb’s free energy in chemical reactions, and a method for determining phase compositions along the solidus and liquidus lines.

Porosity in aluminum is caused by the precipitation of hydrogen from liquid solution or by shrinkage during solidification, and more usually by a combination of these effects. Nonmetallic inclusions entrained before solidification influence porosity formation and mechanical properties. This chapter describes the causes and control of porosity and inclusions in aluminum castings as well as the combined effects of hydrogen, shrinkage, and inclusions on the properties of aluminum alloys. In addition, it discusses the applications of radiography to reveal internal discontinuities in aluminum.

This chapter discusses two damage mechanisms in which stress plays a major role. In the one case, stress causes cracks in the oxide scale on metals, leading to preferential corrosion attack. An example from industry of this type of failure is the circumferential cracking that occurs on the waterwall tubes of supercritical coal-fired boilers fired under low NOx combustion conditions, conducive to the production of sulfidizing environments. In the other case, stress contributes to brittle fracture in the form of intergranular cracking. The phenomenon, which is known by various names, typically occurs at the lower end of the intermediate temperature range and has been observed in ferritic steels, stainless steels, Fe-Ni-Cr alloys, and nickel-base alloys, as described in the chapter.

Almost all metals and alloys are produced from liquids by solidification. For both castings and wrought products, the solidification process has a major influence on both the microstructure and mechanical properties of the final product. This chapter discusses the three zones that a metal cast into a mold can have: a chill zone, a zone containing columnar grains, and a center-equiaxed grain zone. Since the way in which alloys partition on freezing, it follows that all castings are segregated to different categories. The different types of segregation discussed include normal, gravity, micro, and inverse. The chapter also provides information on grain refinement and secondary dendrite arm spacing and porosity and shrinkage in castings. It concludes with a brief overview of six of the most important casting processes in industries: sand casting, plaster mold casting, evaporative pattern casting, investment casting, permanent mold casting, and die casting.

This chapter defines steel castings, explains when to use steel castings, gives an overview of casting processes, and gives examples of suitable applications for cast steel parts.

This chapter opens with a discussion of the classification of rod and tube extrusion processes. The standard processes involve hot working (extrusion at temperatures above room temperature), but some specialized cold working processes are also used for rod and tube extrusion. The next section reviews principles, variations, thermal conditions, axial load calculation, material flow, and applications of direct extrusion and indirect extrusion, with examples provided for extrusion of aluminum and copper alloys. Next, the chapter focuses on the process principles, advantages, and applications of conventional hydrostatic extrusion and thick film processes. This is followed by sections providing information on the special extrusion processes, namely conform process and cable sheathing. The chapter ends with a discussion on direct and indirect tube extrusion.

Compared with other deformation processes used to produce semifinished products, the hot-working extrusion process has the advantage of applying pure compressive forces in all three force directions, enhancing workability. The available variations in the extrusion process enable a wide spectrum of materials to be extruded. This chapter focuses on the processes involved in the extrusion of semifinished products in various metals and their alloys, namely tin, lead, lead-base soft solders, tin-base soft solders, zinc, magnesium, aluminum, copper, titanium, zirconium, iron, nickel, and powder metals. It discusses their properties and applications as well as suitable equipment for extrusion. It further discusses the processes involved in the extrusion of semifinished products in exotic alloys and extrusion of semifinished products from metallic composite materials.

This chapter provides a concise, design-oriented summary of more than 30 sheet forming processes within the categories of bending and flanging, stretch forming, deep drawing, blank preparation, and incremental and hybrid forming. Each summary includes a description and diagram of the process and a bullet-point list identifying relevant equipment, materials, variations, and applications. The chapter also discusses critical process variables, interactions, and components and the classification of sheet metal parts based on geometry.

The second-generation composite materials were added to increase the strain to failure of the primary phase and/or create a dispersed second phase, thereby enhancing the fracture toughness of the thermosetting matrix. These matrices offered novel design capabilities for composites in a variety of aircraft applications. To improve the damage tolerance of composite materials even further, an engineering approach to toughening was used to modify the highly stressed interlayer with either a tougher material or through the use of preformed particles, leading to the third generation of composite materials. This chapter discusses the development, processes, application, advantages, and disadvantages of dispersed-phase toughening of thermoset matrices. Information on the processes of particle interlayer toughening of composite materials is also included.

Many of the structural characteristics of steel products are a result of changes that occur during solidification, particularly volume contractions and solute redistribution. This chapter discusses the solidification process and how it affects the quality and behaviors of steel. It explains how steel shrinks as it solidifies, causing issues such as pipe and voids, and how differences in the solubility of solid and liquid steel lead to compositional heterogeneities or segregation. It describes the dendritic nature of solidification, peritectic and eutectic reactions, microporosity, macro- and microsegregation, and hot cracking, as well as the effects of solidification and remelting on castings, ingots, and continuous cast products. It explains how to determine where defects originate in continuous casters and how to control alumina, sulfide, and nitride inclusions.

When a metal is alloyed with another metal, either substitutional or interstitial solid solutions are usually formed. This chapter discusses the general characteristics of these solutions and the effects of several alloying elements on the yield strength of pure metals. It presents four rules that give a qualitative estimate of the ability of two metals to form substitutional solid solutions: relative size factor, chemical affinity factor, relative valency factor, and lattice type factor. The chapter provides information on alloys that form an ordered structure during heating. It describes the intermediate phases that are formed during solidification between the two extremes of substitutional solid solution on the one hand and intermetallic compound on the other. The chapter concludes with a section on strain aging in low-carbon steels that allows the interstitial atoms to diffuse to the dislocations and again form atmospheres that pin dislocation movement.

This chapter begins with information on the historical development of aluminum alloy castings. It then covers the basic factors involved in the selection of a casting process. This is followed by sections describing the various categories of casting processes and their variants: expendable mold gravity-feed casting, nonexpendable (permanent) mold gravity feed casting, and pressure die casting. Next, the chapter describes the technologies used to produce premium engineered castings and when such castings may be relevant. The chapter concludes with descriptions of other process technologies used with castings, including metallurgical bonding, metal-matrix composites, and hot isostatic pressing.

This chapter describes various aspects of the billet making process and how they affect the quality of aluminum extrusions. It begins with an overview of the direct-chill continuous casting technique and its advantages over other methods, particularly for hard aluminum alloys. It then discusses the influence of casting variables, including pouring temperature and cooling rate, and operating considerations such as the make-up of charge materials, fluxing and degassing procedures, and grain refining. The chapter also provides information on vertical and horizontal casting systems, billet homogenization, and the cause of casting defects, including cracking and splitting, segregation, porosity, and grain growth.