This chapter describes the classification of steels and the various compositional categories of commercial steel products. It explains how different alloying elements affect the properties of carbon and low-alloys steels and discusses strength, toughness, and corrosion resistance and how to improve them.

This article discusses the role of alloying in the production and use of carbon and low-alloy steels. It explains how steels are defined and selected based on alloy content and provides composition and property data for a wide range of designations and grades. It describes the effect of alloying on structure and composition and explains how alloy content can be controlled to optimize properties and behaviors such as ductility, strength, toughness, fatigue and fracture resistance, and resistance to corrosion, wear, and high-temperature creep. It also examines the effect of alloying on processing characteristics such as hardenability, formability, weldability, machinability, and temper embrittlement. In addition, the article provides an extensive amount of engineering data with relevance in materials selection.

This chapter discusses the properties and compositions of steels used in pressure vessels, piping, boilers, rebar, and other structural applications. It covers fine-grained steels, quenched and tempered steels, and controlled rolled (thermomechanical treatment) steels. It also compares and contrasts steels used for concrete reinforcement and in various types of pressure vessels, and presents a metallographic study of the effects of welding on the micro and macrostructure of steel.

Carbon and low-alloy steels are the most frequently welded metallic materials, and much of the welding metallurgy research has focused on this class of materials. Key metallurgical factors of interest include an understanding of the solidification of welds, microstructure of the weld and heat-affected zone (HAZ), solid-state phase transformations during welding, control of toughness in the HAZ, the effects of preheating and postweld heat treatment, and weld discontinuities. This chapter provides information on the classification of steels and the welding characteristics of each class. It describes the issues related to corrosion of carbon steel weldments and remedial measures that have proven successful in specific cases. The major forms of environmentally assisted cracking affecting weldment corrosion are covered. The chapter concludes with a discussion of the effects of welding practice on weldment corrosion.

This chapter covers mechanical properties, microstructures, chemical compositions, manufacturing processes, and engineering of gating practices for several applications of gray, white, and alloyed cast irons. It begins with a description of material standards, followed by a section providing information on the practice of stress relieving. Next, the chapter details various ways of eliminating slag entrainment while designing gating and venting systems. Several factors related to the establishment of the optimum pouring rate and time are then covered. Further, the chapter discusses the technology of unalloyed or low-alloyed gray iron castings and white iron and high-alloyed cast irons. Finally, it describes the casting defects that are associated with cast iron and the processes involved in solving these defects. The article includes a number of figures illustrating the topics discussed.

This chapter describes the metallurgy, composition, and properties of steels and other alloys. It provides information on the atomic structure of metals, the nature of alloy phases, and the mechanisms involved in phase transformations, including time-temperature effects and the role of diffusion, nucleation, and growth. It also discusses alloying, heat treating, and defect formation and briefly covers condenser tube materials.

This chapter discusses the forming characteristics of dual-phase (DP) and transformation-induced plasticity (TRIP) steels. It begins with a review of the mechanical behavior of advanced high-strength steels (AHSS) and how they respond to stress-strain conditions associated with deformation processes such as stretching, bending, flanging, deep drawing, and blanking. It then describes the complex tribology of AHSS forming operations, the role of lubrication, the effect of tool steels and coatings, and the force and energy requirements of various forming presses. It also discusses the cause of springback and explains how to predict and compensating for its effects.

Heat treatment is the most common way of altering the mechanical, physical, and even chemical properties of steels. This chapter describes the changes that occur in carbon and low-alloy steels during conventional heat treatments. It explains how austenite decomposition largely defines the final microstructure, and how the associated phase transformations are driven by nucleation and growth processes. It describes diffusionless and diffusive growth mechanisms and provides detailed information on the properties, structure, and behaviors of the transformation products produced, namely martensite and bainite. It also discusses the formation of austenite, the control and measurement of austenitic grain size, the characteristics of ferritic microstructures, and the methods used to classify ferrite morphology.

This chapter provides a quantitative treatment of the cracking mechanisms associated with fatigue, drawing on the principles of fracture mechanics. It explains that although fracture mechanics originated with the aim of understanding sudden and catastrophic crack extension, the main premise of a stress field in the vicinity of the crack also applies to the study of cycle-by-cycle stable crack growth. A detailed review is given of the many developments and discoveries that helped shape the theory and methods collectively defined as crack mechanics, which the authors then employ to analyze the crack growth behavior of various materials, including steels and nonferrous alloys, under constant-amplitude loading. The authors then deal with the effects of complex loading using crack retardation and crack closure models to show how load fluctuations can slow crack growth rates and even cause total crack arrest. They also present the results of a study on crack initiation, propagation, and fracture in circular (rather than rectangular) specimens and a fatigue study on ductile and quasi-brittle materials.

This chapter is a study of the microstructure of case-hardened steels. It explains what can be learned by examining grain size, microcracking, nonmetallic inclusions, and the effects of microsegregation. It identifies information-rich features, describing their ideal characteristics, the likely cause of variations observed, and their effect on mechanical properties and behaviors. The discussions throughout the chapter are aided by the use of images, diagrams, data plots, and tables.

This chapter describes the attributes of aluminum products that are critical for key structural applications. It covers the selection criteria and evaluations performed by the aluminum supplier or customer: physical attributes, mechanical properties (tensile, fracture, and fatigue), and corrosion.

This chapter describes a sheet metal forming method, called hydroforming, that uses pressurized liquid and a shaped punch or die. It discusses the advantages and disadvantages of the two approaches, the effect of process variations, and tooling modifications intended to reduce sheet bulging. It identifies the factors that influence part quality and explains how finite-element analysis can be used to optimize hydroforming operations. It also discusses the economics of sheet hydroforming and presents several application examples.

This chapter presents definitions of terms related to the metallurgy and metallographic study of irons and steels.

This chapter covers the mechanics and tribology of sheet metalworking processes, including shearing, bending, spinning, stretching, deep drawing, ironing, and hydroforming. It explains how to determine friction, wear, and lubrication needs based on process forces, temperatures, and strains and the effects of strain hardening on workpiece materials. It presents test methods for evaluating process tribology, describes lubrication and wear control approaches, and discusses the factors, such as surface roughness, lubricant breakdown, and adhesion, that can lead to galling and other forms of wear. It also provides best practices for selecting, evaluating, and applying lubricants for specific materials, including steels, stainless steels, and aluminum and magnesium alloys.