This appendix provides composition data and application-related information on a wide range of superalloys in both wrought and cast form.

Many companies conduct only metallurgical evaluations in the wake of failures, discovering nothing more than the physical mechanism by which the failure occurred. The origin of failures, however, is often complex, involving not only physical mechanisms, but also human behavior and latent factors. Failures may also involve multiple parts, entire machines, or processes of any size and shape. The chapter examines the unique aspects of many failures and explains how they can sometimes be traced to systemic issues. It also covers the reasons why products fail, including improper service or operation, improper maintenance, improper testing, assembly errors, fabrication or manufacturing errors, and design errors. The case of the Tacoma Narrows Bridge collapse is presented to illustrate the consequence of overlooked factors, in this case, wind dynamics, and the importance of identifying root causes to prevent repeat failures.

This chapter discusses the compatibility problems that arise from chemical or physical interactions between liquefied gases and the common materials used in their production, storage, transportation, distribution, and use. The discussion covers the compatibility of materials with liquid oxygen and liquid fluorine. Hydrogen-environment embrittlement is unique to low-temperature hydrogen systems and is also discussed.

This chapter describes the nine steps of a failure investigation. The steps add detail to the problem-solving process introduced in Chapter 3. The first five steps are (1) understanding and negotiating the investigation goals, (2) obtaining an understanding of the failure, (3) objectively and clearly identifying all possible root causes, (4) evaluating the likelihood of each root cause, and (5) converging on the most likely root cause(s). Many failure investigations stop at this point, but significant value is provided in the next four steps, which are (6) identifying all possible corrective actions, (7) evaluating each corrective action, (8) selecting the optimal corrective action(s), and (9) evaluating the effectiveness of each corrective action. Each step is discussed in detail with examples along with information on the procedures to be followed and resources needed for the investigation.

Ceramic-matrix composites possess many of the desirable qualities of monolithic ceramics, but are much tougher because of the reinforcements. This chapter explains how reinforcements are used in ceramic-matrix composites and how they alter energy-dissipating mechanisms and load-carrying behaviors. It compares the stress-strain curves for monolithic ceramics and ceramic-matrix composites, noting improvements afforded by the addition of reinforcements. It then goes on to discuss the key attributes, properties, and applications of discontinuously reinforced ceramic composites, continuous fiber ceramic composites, and carbon-carbon composites. It also describes a number of ceramic-matrix composite processing methods, including cold pressing and sintering, hot pressing, reaction bonding, directed metal oxidation, and liquid, vapor, and polymer infiltration.

The necessity of developing the lightest-weight structures with sufficient strength was the driving factor for the development of filament-wound composite pressure vessels. This chapter presents a brief history of the development of rocket motor cases (RMCs), followed by a comparison of the advantages of composites over metals for RMCs. A discussion on a typical design, analysis, and manufacturing operation follows. The chapter introduces the basic design approach and shows some sizing techniques along with example calculations. It discusses the processes involved in the testing of the composite pressure vessel.

This chapter provides a brief introduction to superalloys and their high-temperature capabilities. It explains how and why they were developed and highlights some of their unique properties, behaviors, and characteristics. It discusses their basic metallurgy, how they are processed, and where they are typically used. It also includes nominal composition data for more than 120 superalloys and a concise overview of the major topics in the book.

The objective of mechanical testing of an engineered material is to provide data necessary for the analysis, design, and fabrication of structural components using the material. The testing of filament-wound composite materials offers unique challenges because of the special characteristics of composites. This chapter describes suitable static mechanical test techniques for characterizing laminated composite materials. The approach is to provide recommended techniques, based on consensus opinions of fabricators and users of filament-wound composites, and to survey available techniques that have been used successfully in the field. The chapter describes the effects of various factors on the properties of composite constituents, including fibers, resins, and unidirectional plies. Some aspects of specimen selection are also described. The chapter provides information on pressure bottles and tubular parts that have been developed as standard test specimens for combined load testing of composites.

This chapter identifies the primary causes of service failures and discusses the types of defects from which they stem. It presents more than a dozen examples of failures attributed to such causes as design defects, material defects, and manufacturing or processing defects as well as assembly errors, abnormal operating conditions, and inadequate maintenance. It also describes the precise usage of terms such as defect, flaw, imperfection, and discontinuity.

This chapter discusses the compositions, properties, and applications of nonferrous metals, including zirconium, hafnium, beryllium, lead, tin, gold, silver, and platinum group metals. It also addresses fusible alloys and provides melting temperatures for several compositions.

This article discusses the compositions, properties, and uses of silver, gold, and platinum group metals, including platinum, rhodium, iridium, ruthenium, and osmium. It describes the role of various alloying elements and explains how they affect physical, mechanical, and electrical properties as well as corrosion resistance.

This chapter explains how the authors assessed the potential risks of creep-fatigue in several aerospace applications using the tools and techniques presented in earlier chapters. It begins by identifying the fatigue regimes encountered in the main engines of the Space Shuttle. It then describes the types of damage observed in engine components and the methods used to mitigate problems. It also discusses the results of analyses that led to changes in design or approach and examines fatigue-related issues in turbine engines used in commercial aircraft.

This chapter provides an overview of a computational method, called CALPHAD, used for the study of phase equilibria in multicomponent systems. It describes the thermodynamic models and calculation techniques employed in the software and explains how it applies to complex alloys used in industry. It also provides examples showing how CALPHAD has been used to determine the formability of metallic glass, calculate the dilation of stainless steel during phase transformation, and predict the beta transus and approach curves of commercial titanium alloys.

This chapter describes some common pitfalls encountered in failure investigations and provides guidance to help engineers recognize processes and “quick fixes” that companies often try to substitute for failure analysis. It discusses three important skills and characteristics that a professional engineer must improve to conduct an effective and successful failure investigation, namely technical skills, communication skills, and technical integrity. The chapter also provides information on the additional basic tools available for failure investigation and root cause determination: the Kepner-Tregoe structured problem-solving method, PROACT software for root cause analysis developed by the Reliability Center, Inc., and other processes and methods developed by the Failsafe Network, Inc., and Shainin LLC.

This chapter discusses the failure mechanisms associated with fiber-reinforced composites. It begins with a review of fiber-matrix systems and the stress-strain response of unidirectional lamina and both notched and unnotched composite laminate specimens. It then explains how cyclic loading can lead to delamination, the primary failure mode of most composites, and describes some of the methods that have been developed to improve delamination resistance, assess damage tolerance, determine residual strength, and predict failure modes.

This chapter is dedicated mostly to the metallurgical effects on the corrosion behavior of corrosion-resistant alloys. It begins with a section describing the importance of alloying elements on the corrosion behavior of nickel alloys. The chapter considers the metallurgical effects of alloy composition for heat-resistant alloys, nickel corrosion-resistant alloys, and nickel-base alloys. This chapter also discusses the corrosion implications of changing the alloy microstructure via solid-state transformation, second-phase precipitation, or cold work. It concludes with a comparison of corrosion behavior between cast and wrought product forms.

Most filament winding machines now have computer controls and at least three axes. Winding with four axes is increasingly common because the shapes of the products have evolved to include more complexity. The automation used on the winding machine and ancillary components does not eliminate the need for proper fiber handling. This chapter is a primer on modern filament winding equipment and its use, starting with an overview of machine control and then discussing the design and structural analysis of filament wound components such as pressure vessels, pipes, grid structures, deep sea oil platform drill risers, high-speed rotors, and filament-wound preforms.

This chapter discusses the ways in which the evolution of filament winding software systems has capitalized on the inherent flexibility of computer numerical controlled winding machines and enhanced their productivity. It provides a detailed discussion on different types of geometries that can be wound, from the simple to the highly complex, with insight into the limitations, advantages, and challenges of each. Components covered include classic axisymmetric parts (rings, pipes, driveshafts, pipe reducers, tapered shafts, closed-end pressure vessels, and storage tanks), nonround sections (aeromasts, airfoils, box sections, and fuselage sections), curved-axis parts (elbows, ducts), and special applications (tees). Basic winding concepts, such as band pattern, are discussed and explained, and some simple predictive formulae are introduced. The chapter also provides examples of programming various geometries using advanced software tools and discusses how various materials, such as rovings, tow-preg, prepreg tape, and woven materials, affect winding program generation.

Superalloys, although not strictly defined, are generally regarded as high-performance alloys based on group VIII elements (nickel, cobalt, or iron, with a high percentage of nickel) to which a multiplicity of alloying elements have been added. The defining feature of a superalloy is its combination of relatively high mechanical strength and surface stability at high operating temperatures. This chapter provides a brief history of the development of superalloys and discusses their use in the gas turbine engines.