This chapter discusses the crystal structures of steel and cast iron, the iron-iron carbide equilibrium diagram, microconstituents or phases in the iron-iron carbide phase diagram, the iron-carbon carbide-silicon equilibrium diagram of cast irons, and the influence on microstructure by base elements and alloying elements. Graphitization, cooling rates, and heat treatment effects are covered. There also is discussion on inoculation benefits, flake graphite types and typical applications, evolution of cast iron types, ASTM specification A247 for graphite shapes, and selection of the best molding process. A large table lists typical material choices for various applications.

The design stresses for most pressure-containing structural application, which are based upon minimum mechanical properties designated in the specifications published by the American Society for Testing and Materials (ASTM). This chapter reviews metallurgical characteristics and their influence on the properties and performance of structural carbon and low alloy steels and contains a summary of the relevant features of the ASTM product specifications.

This chapter introduces the metallographer to the various types of steels and cast irons and explains how they are classified and defined. Classification and designation details are provided for plain carbon steels, alloy steels, and gray, white, ductile, and malleable cast irons.

In 1924, the American Society for Testing and Materials (ASTM) organized the symposium "Corrosion and Heat Resisting Alloys, and Electrical Resistance Alloys." It was the beginning of a major role that ASTM played in the history of stainless steel. This chapter provides information on the papers presented at the 1924 symposium. It also describes the role of ASTM in stainless steel standardization after the 1924 symposium.

This chapter discusses the role of standards and specifications for steel castings. It defines specifications and discusses how certification, testing, examination, methods, practices, procedures, compositions, properties, facilities, statistical process control, and documentation relate to codes and standards. The chapter describes processes involved in the selection of specifications for steel castings. Further, it provides information on the cost of specifications.

This chapter presents the Unified Numbering System (UNS) for metals and alloys.

This chapter addresses some of the challenges involved in materials selection, providing context for much of the information presented in the book. It describes a typical four-step design scenario, noting material-related considerations and information needs. It explains how design decisions are complicated by the interconnected nature of material properties, design geometry, and manufacturing requirements and effects. The chapter also assesses the design impact of several materials and discusses codes, standards, and specifications.

This chapter provides a detailed discussion on microstructure, properties, and applications of two classes of stainless steel: duplex stainless steel and precipitation-hardening steel.

This chapter focuses on engineering drawings for casting production, providing information on machining and casting drawings and machining and tooling references.

This appendix is a timeline of events related to the discovery, development, and commercialization of stainless steels.

Fastening screws used in fuel-injection pumps failed during assembly and were examined to determine the cause. Based on observations and the result SEM fractography and hardness measurements, the screws failed by brittle intergranular fracture due to hydrogen embrittlement associated with plating procedures. The report includes recommendations for improving the quality of the screws.

This article discusses the effect of alloying on high-strength low-alloy (HSLA) steels. It explains where HSLA steels fit in the continuum of commercial steels and describes the six general categories into which they are divided. It provides composition data for standard types or grades of HSLA steel along with information on available mill forms, key characteristics, and intended uses. The article explains how small amounts of alloying elements, particularly vanadium, niobium, and titanium, control not only the properties of HSLA steels, but also their manufacturability.

ASTM and other standards organizations have developed a number of tests for evaluating stress-corrosion cracking (SCC) under various conditions. This appendix lists many of the SCC tests that have been approved for specific materials and operating environments.

This chapter defines low-temperature and cryogenic steels and describes their alloy classifications and their ambient and low-temperature properties. These steels include ferritic carbon and low alloy steels, martensitic low alloy steels, martensitic high alloy steels, and austenitic high alloy steels.

This chapter covers the basics of weldability of cast steels such as carbon and low alloy steels, corrosion-resistant high alloy steels, nickel-base alloys, heat-resistant high alloy steels, and wear-resistant high austenitic manganese steels. It provides an overview of weld overlay and hard facing; cast-weld construction; and plasma arc cutting and plasma arc welding. The chapter discusses different types of welding processes. These include shielded metal-arc welding, air carbon arc cutting process, gas tungsten-arc welding, gas metal-arc welding process, flux-cored arc welding, submerged arc welding, and electroslag and electro-gas welding.

This chapter presents the early classes of stainless steel. These include martensitic alloys, austenitic alloys, and ferritic alloys. It also presents stainless steel trade names. The chapter describes standardized designation for type 304 stainless steel by various specification organizations.